Efficient Gating of Organic Electrochemical Transistors with In‐Plane Gate Electrodes

Abstract Organic electrochemical transistors (OECTs) are electrolyte‐gated transistors, employing an electrolyte between their gate and channel instead of an insulating layer. For efficient gating, non‐polarizable electrodes, for example, Ag/AgCl, are typically used but unfortunately, this simple approach limits the options for multiple gate integration. Patterned polarizable Au gates on the other hand, show strongly reduced gating due to a large voltage drop at the gate/electrolyte interface. Here, an alternative, simple yet effective method for efficient OECT gating by scalable in‐plane gate electrodes, is demonstrated. The fact that poly(3,4‐ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) exhibits a volumetric capacitance in an electrolyte is made use of. As a result, the capacitance of PEDOT:PSS‐based gates can be strongly enhanced by increasing their thickness, thereby reducing the voltage loss at the gate/electrolyte interface. By combining spin coating and electrodeposition, planar electrodes of various thicknesses are created on a multi‐gated OECT chip and their effect on the gating efficiency, examined. It is shown that the gating performed by an in‐plane PEDOT:PSS electrode can be tuned to be comparable to the one obtained by a Ag/AgCl electrode. Overall, the realization of efficient gating with in‐plane electrodes paves the way toward integration of OECT‐based biosensors and “organ‐on‐a‐chip” platforms.