Dynamic Stabilization of Metastable States in Triple‐Well Ferroelectric Sn₂P₂S₆

Abstract Polarization dynamics in ferroelectric materials is governed by the effective potential energy landscape of the order parameter. The unique aspect of ferroelectrics compared to many other transitions is the possibility of more than two potential wells, leading to complicated energy landscapes with new fundamental and functional properties. Here, direct dynamic evidence is revealed of a triple‐well potential in the metal thiophosphate Sn₂P₂S₆ compound using multivariate scanning probe microscopy combined with theoretical simulations. The key finding is that the metastable zero polarization state can be accessed through a gradual switching process and is stabilized over a broad range of electric fields. Simulations confirm that the observed zero polarization state originates from a kinetic stabilization of the nonpolar state of the triple‐well, as opposed to domain walls. Dynamically, the triple‐well of Sn₂P₂S₆ becomes equivalent to antiferroelectric hysteresis loops. Therefore, this material combines the robust and well‐defined domain structure of a proper ferroelectric with dynamic hysteresis loops present in antiferroelectrics. Moreover, the triple‐well enhances mem‐capacitive effects in Sn₂P₂S₆, which are forbidden for ideal double‐well ferroelectrics. These findings provide a path to tunable electronic elements for beyond binary high‐density computing devices and neuromorphic circuits based on dynamic properties of the triple‐well.