journal article·2021-12-06

3D Steric Bulky Semiconductor Molecules toward Organic Optoelectronic Nanocrystals

Yin-Xiang Li, Xue-Mei Dong, Meng-Na Yu, He-Shan Zhang, Mustafa Eginligil, Yi-Jie Nie, Ling-Hai Xie, Zong-Qiong Lin, Ju-Qing Liu, Wei Huang

ACS Materials Letters· Volume 3· Issue 12
Publisher page

Abstract

With minimal defects, few grain boundaries, and high-performance optoelectronic characteristics, organic semiconductor nanocrystals (OSNCs) have emerged as promising solutions for miniaturized organic devices and related optoelectronic circuits. To realize this, it is crucial that the OSNCs should possess desired morphologies and unique optoelectronic attributions. After the planar π-conjugated building blocks, the steric bulky molecules with a three-dimensional (3D) framework enable the multiscale self-assembly architectures and superior charge storage properties, as well as high-performance optoelectronic applications, such as organic transistor memory, organic light-emitting diodes, organic lasers and organic photovoltaic cells. However, this type of 3D steric bulky molecule-based OSNCs are not easily to get, and molecular design principles must be developed. In this Review, recent advances in the efficient theories that have arose in building varied nanoarchitectures of 3D steric bulky molecule-based OSNCs, especially the 2D and 3D in morphology, are highlighted. The obtained steric OSNCs exhibited rich optoelectronic properties, including the charge storage, ion transmission, crystallization-enhanced emission, and so on. Further architectural optimization of the steric OSNCs to cater for optoelectronic device based on them is necessary to strive to develop this research direction.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Perovskite Materials and Applications · Luminescence and Fluorescent Materials · Organic Electronics and Photovoltaics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (Nanjing Tech), 30 South Puzhu Road, Nanjing 211816, China

Center for Molecular Systems and Organic Devices (CMSOD), Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China

Frontiers Science Center for Flexible Electronics, Xi’an Institute of Flexible Electronics (IFE) and Xi’an Institute of Biomedical Materials & Engineering, Northwestern Polytechnical University, 127 West Youyi Road, Xi’an 710072, China

Funding

Jiangsu Province Postdoctoral Science Foundation · Ministry of Science and Technology of the People's Republic of China · China Postdoctoral Science Foundation · Nanjing University of Posts and Telecommunications · Ministry of Human Resources and Social Security · National Natural Science Foundation of China

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