journal article·2024-05Open access

Photochemical Shield Enabling Highly Efficient Perovskite Photovoltaics

Run‐Jun Jin, Yan‐Hui Lou, Lei Huang, Kai‐Li Wang, Chun‐Hao Chen, Jing Chen, Fan Hu, Zhao‐Kui Wang

Advanced Materials· Volume 36· Issue 21

Abstract

Abstract Oxygen is difficult to be physically removed. Oxygen will be excited by light to form free radicals which further attack the lattice of perovskite. The stabilization of α‐FAPbI3 against δ‐FAPbI3 is the key to optimize perovskite solar cells. Herein, the simple molecule, benzaldehyde (BAH) is adopted. The photochemical shield will be established in perovskite layer. Moreover, heterogeneous nucleation induced by BAH enhances the crystallization of α‐FAPbI3. Consequently, the stability of device is improved significantly. The target device maintains 95% of original power conversion efficiency after 1500 h under air conditions and light‐emitting diode light. The power conversion efficiency increases from 23.21% of pristine device to 24.82% of target device.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Perovskite Materials and Applications · Conducting polymers and applications · Chalcogenide Semiconductor Thin Films

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Functional Nano & Soft Materials (FUNSOM) Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Jiangsu Key Laboratory for Carbon‐Based Functional Materials & Devices Soochow University Suzhou 215123 China

College of Energy Soochow Institute for Energy and Materials Innovations Soochow University Suzhou 215006 China

Funding

National Natural Science Foundation of China · Natural Science Foundation of Jiangsu Province · Higher Education Discipline Innovation Project

References (67)

Show source-provided references
1. 10.1063/1.494141610.1063/1.4941416 ↗
2. 10.1016/j.optcom.2015.12.04310.1016/j.optcom.2015.12.043 ↗
3. 10.1038/srep3163710.1038/srep31637 ↗
4. 10.1021/acsenergylett.8b0021710.1021/acsenergylett.8b00217 ↗
5. 10.1002/adma.20200342210.1002/adma.202003422 ↗
6. 10.1002/aenm.20220041710.1002/aenm.202200417 ↗
7. 10.1002/aenm.20220053710.1002/aenm.202200537 ↗
8. 10.1002/smll.20230258510.1002/smll.202302585 ↗
9. 10.1002/aenm.20220319010.1002/aenm.202203190 ↗
10. 10.1002/aenm.20220094510.1002/aenm.202200945 ↗
11. 10.1002/aenm.20210367410.1002/aenm.202103674 ↗
12. 10.1002/aenm.20220279910.1002/aenm.202202799 ↗
13. 10.1002/adma.20220409810.1002/adma.202204098 ↗
14. 10.1038/s41586-023-05825-y10.1038/s41586-023-05825-y ↗
15. 10.1016/j.joule.2020.11.00110.1016/j.joule.2020.11.001 ↗
16. 10.1016/j.joule.2022.03.00310.1016/j.joule.2022.03.003 ↗
17. 10.1002/anie.20150315310.1002/anie.201503153 ↗
18. 10.1039/C6EE00409A10.1039/C6EE00409A ↗
19. 10.1039/C8NR03058H10.1039/C8NR03058H ↗
20. 10.1002/anie.20200521110.1002/anie.202005211 ↗
21. 10.1021/acsenergylett.2c0014010.1021/acsenergylett.2c00140 ↗
22. 10.1021/acsami.9b2308610.1021/acsami.9b23086 ↗
23. 10.1039/D1EE02882K10.1039/D1EE02882K ↗
24. 10.1038/s41467-023-37492-y10.1038/s41467-023-37492-y ↗
25. 10.1021/ja01345a01810.1021/ja01345a018 ↗
26. 10.1080/1091581060071661210.1080/10915810600716612 ↗
27. 10.1007/BF0017009710.1007/BF00170097 ↗
28. 10.1002/adma.20220533810.1002/adma.202205338 ↗
29. 10.1038/s41467-021-26541-z10.1038/s41467-021-26541-z ↗
30. 10.1126/sciadv.adc992310.1126/sciadv.adc9923 ↗
31. 10.1016/j.mtener.2021.10090710.1016/j.mtener.2021.100907 ↗
32. 10.1002/adma.20220436610.1002/adma.202204366 ↗
33. 10.1016/j.apsusc.2022.15320610.1016/j.apsusc.2022.153206 ↗
34. 10.1002/admi.20180001010.1002/admi.201800010 ↗
35. 10.1002/adfm.20210963110.1002/adfm.202109631 ↗
36. 10.1002/adom.20170061510.1002/adom.201700615 ↗
37. 10.1016/j.jcrysgro.2019.12525110.1016/j.jcrysgro.2019.125251 ↗
38. 10.1016/j.commatsci.2016.01.02710.1016/j.commatsci.2016.01.027 ↗
39. 10.1016/j.nanoen.2021.10615210.1016/j.nanoen.2021.106152 ↗
40. 10.1126/science.abb898510.1126/science.abb8985 ↗
41. 10.1038/s41586-021-03406-510.1038/s41586-021-03406-5 ↗
42. 10.1016/j.fuel.2017.12.03810.1016/j.fuel.2017.12.038 ↗
43. 10.1002/smtd.20220093310.1002/smtd.202200933 ↗
44. 10.1038/s41467-020-19237-310.1038/s41467-020-19237-3 ↗
45. 10.1063/1.174758810.1063/1.1747588 ↗
46. 10.1002/adma.20150500210.1002/adma.201505002 ↗
47. 10.1021/acsenergylett.9b0234810.1021/acsenergylett.9b02348 ↗
48. 10.1002/adom.20160032710.1002/adom.201600327 ↗
49. 10.1107/S002188980904012610.1107/S0021889809040126 ↗
50. 10.1002/adfm.20221483410.1002/adfm.202214834 ↗
51. 10.1021/jacs.3c0153110.1021/jacs.3c01531 ↗
52. 10.1002/aenm.20180120810.1002/aenm.201801208 ↗
53. 10.1002/adma.20221022310.1002/adma.202210223 ↗
54. 10.1002/solr.20210073110.1002/solr.202100731 ↗
55. 10.1002/adma.20220032010.1002/adma.202200320 ↗
56. 10.1002/aenm.20180071510.1002/aenm.201800715 ↗
57. 10.1002/adma.20221154510.1002/adma.202211545 ↗
58. 10.1039/C7CP01140G10.1039/C7CP01140G ↗
59. 10.1002/solr.20220003810.1002/solr.202200038 ↗
60. 10.1126/science.abc441710.1126/science.abc4417 ↗
61. 10.1126/science.aba089310.1126/science.aba0893 ↗
62. 10.1002/smll.20220269010.1002/smll.202202690 ↗
63. 10.1002/aenm.20190405410.1002/aenm.201904054 ↗
64. 10.1016/j.jpowsour.2015.07.08110.1016/j.jpowsour.2015.07.081 ↗
65. 10.1039/C9TA08314F10.1039/C9TA08314F ↗
66. 10.1002/anie.20231469010.1002/anie.202314690 ↗
67. 10.1002/cjoc.20230012810.1002/cjoc.202300128 ↗