journal article·2025-07

Growth Control of InP/ZnSe Heterostructured Nanocrystals

Doyoon Shin, Hak June Lee, Dongju Jung, Jong Ah Chae, Jeong Woo Park, Jaemin Lim, Seongbin Im, Sejong Min, Euyheon Hwang, Doh C. Lee, Young‐Shin Park, Jun Hyuk Chang, Kyoungwon Park, Junki Kim, Ji‐Sang Park, Wan Ki Bae

Advanced Materials· Volume 37· Issue 26
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Abstract

Abstract The morphology of heterostructured semiconductor nanocrystals ( h ‐NCs) dictates the spatial distribution of charge carriers and their recombination dynamics and/or transport, which are the main performance indicators of photonic applications utilizing h ‐NCs. The inability to control the morphology of heterovalent III‐V/II‐VI h ‐NCs composed of heavy‐metal‐free elements hinders their practical use. As a case study of III‐V/II‐VI h ‐NCs, the growth control of ZnSe epilayers on InP NCs is demonstrated here. The anisotropic morphology in InP/ZnSe h ‐NCs is attributed to the facet‐dependent energy costs for the growth of ZnSe epilayers on different facets of InP NCs, and effective chemical means for controlling the growth rates of ZnSe on different surface planes are demonstrated. Ultimately, this article capitalizes on the controlled morphology of InP/ZnSe h ‐NCs to expand their photophysical characteristics from stable and pure emission to environment‐sensitive one, which will facilitate their use in a variety of photonic applications.
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Research context

OpenAlex topics: Quantum Dots Synthesis And Properties · Chalcogenide Semiconductor Thin Films · Nanowire Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

SKKU Advanced Institute of Nano Technology (SAINT) Sungkyunkwan University (SKKU) Suwon 16419 Republic of Korea

Department of Chemical and Biomolecular Engineering, KAIST Institute for the Nanocentury Korea Advanced Institute of Science and Technology (KAIST) Daejeon 34141 Republic of Korea

Chemistry Division Los Alamos National Laboratory Los Alamos NM 87545 USA

Display Research Center Korea Electronics Technology Institute (KETI) Seongnam 13509 Republic of Korea

Funding

National Research Foundation of Korea · Ministry of Science, ICT and Future Planning · Ministry of Trade, Industry and Energy · Samsung Display

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