Progress and Perspective toward Continuous‐Wave Organic Solid‐State Lasers

Abstract A continuous‐wave (CW) organic solid‐state laser is highly desirable for spectroscopy, sensing, and communications, but is a significant challenge in optoelectronics. The accumulation of long‐lived triplet excitons and relevant excited‐state absorptions, as well as singlet–triplet annihilation, are the main obstacles to CW lasing. Here, progress in singlet‐ and triplet‐state utilizations in organic gain media is reviewed to reveal the issues in working with triplets. Then, exciton behaviors that inhibit light oscillations during long excitation pulses are discussed. Further, recent advances in increasing organic lasing pulse widths from microseconds toward the indication of CW operation are summarized with respect to molecular designs, advanced resonator architectures, triplet scavenging, and potential triplet contribution strategies. Finally, future directions and perspectives are proposed for achieving stable CW organic lasers with significant triplet contribution.