High‐Quality Hybrid Perovskite Thin Films by Post‐Treatment Technologies in Photovoltaic Applications

Abstract Incredible progress in photovoltaic devices based on hybrid perovskite materials has been made in the past few decades, and a record‐certified power conversion efficiency (PCE) of over 26% has been achieved in single‐junction perovskite solar cells (PSCs). In the fabrication of high‐efficiency PSCs, the postprocessing procedures toward perovskites are essential for designing high‐quality perovskite thin films; developing efficient and reliable post‐treatment techniques is very important to promote the progress of PSCs. Here, recent post‐treatment technological reforms toward perovskite thin films are summarized, and the principal functions of the post‐treatment strategies on the design of high‐quality perovskite films have been thoroughly analyzed by dividing into two categories in this review: thermal annealing (TA)‐related technique and TA‐free technique. The latest research progress of the above two types of post‐treatment techniques is summarized and discussed, focusing on the optimization of postprocessing conditions, the regulation of perovskite qualities, and the enhancement of device performance. Finally, an outlook of the prospect trends and future challenges for the fabrication of the perovskite layer and the production of highly efficient PSCs is given.