PO43− Tetrahedron Assisted Chelate Engineering for 10.67%‐Efficient Antimony Selenosulfide Solar Cells
Source abstract
Abstract
Abstract Anisotropic carrier transport and deep‐level defect of antimony selenosulfide (Sb2(S,Se)3) absorber are two vital auses restraining the photovoltaic performance of this emerging thin‐film solar cell. Herein, chelate engineering is proposed to prepare high‐quality Sb2(S,Se)3 film based on hydrothermal deposition approach, which realizes desirable carrier transport and passivated defects by using tetrahedral PO43− ion in dibasic sodium phosphate (Na2HPO4, DSP). The PO43− Lewis structure, on one hand in the form of [(SbO)3(PO4)] chelate, can adsorb on the polar planes of cadmium sulfide (CdS) layer, promoting the heterogeneous nucleation, and on the other hand, the tetrahedral PO43− inhibits horizontal growth of (Sb4S(e)6)n ribbons due to size effects, thus achieving desirable [hk1] orientation. Moreover, the introduction PO43− effectively passivates the antisite defect SbS1. These synergistic effects have effectively improved carrier transport and reduced non‐radiative recombination of the Sb2(S,Se)3 absorber. Consequently, the DSP‐modified Sb2(S,Se)3 device efficiency increases from 8.59% to 10.67%.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Chalcogenide Semiconductor Thin Films · Quantum Dots Synthesis And Properties · Perovskite Materials and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
State Key Laboratory of Featured Metal Materials and Life‐cycle Safety for Composite Structures MOE Key Laboratory of New Processing Technology for Nonferrous Metals and Materials and School of Resources Environment and Materials Guangxi University Nanning 530004 China
Institute of Thin Film Physics and Applications Shenzhen Key Laboratory of Advanced Thin Films and Applications Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province State Key Laboratory of Radio Frequency Heterogeneous Integration College of Physics and Optoelectronic Engineering Shenzhen University Shenzhen 518060 China
National‐Local Joint Engineering Laboratory of New Energy Photoelectric Devices College of Physics Science and Technology Institute of Life Science and Green Development Hebei University Baoding 071002 China
ISCR (Institut des Sciences Chimiques de Rennes)‐CNRS UMR 6226, Universite de Rennes Rennes F‐35000 France
Funding
National Key Research and Development Program of China · National Natural Science Foundation of China
References (84)
Show source-provided references
1. 10.1002/aenm.20230039110.1002/aenm.202300391 ↗
2. 10.1002/adma.20241066910.1002/adma.202410669 ↗
3. 10.1039/D4EE02877E10.1039/D4EE02877E ↗
4. 10.1002/aenm.20210301510.1002/aenm.202103015 ↗
5. 10.1002/adfm.20221165710.1002/adfm.202211657 ↗
6. 10.1002/adma.20220856410.1002/adma.202208564 ↗
7. 10.1002/adfm.20230976410.1002/adfm.202309764 ↗
8. 10.1038/s41467-018-07903-610.1038/s41467-018-07903-6 ↗
9. 10.1002/smll.20231041810.1002/smll.202310418 ↗
10. 10.1038/s41467-018-04634-610.1038/s41467-018-04634-6 ↗
11. 10.1002/adfm.20240297810.1002/adfm.202402978 ↗
12. 10.1002/anie.20231295110.1002/anie.202312951 ↗
13. 10.1088/1674-4926/44/8/08270110.1088/1674-4926/44/8/082701 ↗
14. 10.1063/1.173603410.1063/1.1736034 ↗
15. 10.1021/acsami.8b1833010.1021/acsami.8b18330 ↗
16. 10.1002/smtd.20230072810.1002/smtd.202300728 ↗
17. 10.1002/adma.20230852210.1002/adma.202308522 ↗
18. 10.1016/j.cclet.2023.10946810.1016/j.cclet.2023.109468 ↗
19. 10.20517/energymater.2022.1410.20517/energymater.2022.14 ↗
20. 10.1002/adfm.20221451110.1002/adfm.202214511 ↗
21. 10.1038/s41560-020-0652-310.1038/s41560-020-0652-3 ↗
22. 10.1021/acsami.1c1322310.1021/acsami.1c13223 ↗
23. 10.1016/j.cej.2022.13647410.1016/j.cej.2022.136474 ↗
24. 10.1002/aenm.20200234110.1002/aenm.202002341 ↗
25. 10.1002/adma.20210434610.1002/adma.202104346 ↗
26. 10.1016/j.cej.2022.13534110.1016/j.cej.2022.135341 ↗
27. 10.1007/s40843-022-2066-510.1007/s40843-022-2066-5 ↗
28. 10.1016/j.cej.2022.13740010.1016/j.cej.2022.137400 ↗
29. 10.1002/pip.262710.1002/pip.2627 ↗
30. 10.1021/acsami.0c1425610.1021/acsami.0c14256 ↗
31. 10.1016/j.vacuum.2023.11239310.1016/j.vacuum.2023.112393 ↗
32. 10.1002/adfm.20211003210.1002/adfm.202110032 ↗
33. 10.1021/acsami.0c0918010.1021/acsami.0c09180 ↗
34. 10.1016/j.joule.2024.05.00410.1016/j.joule.2024.05.004 ↗
35. 10.1016/j.nanoen.2018.04.04410.1016/j.nanoen.2018.04.044 ↗
36. 10.1002/aenm.20240335210.1002/aenm.202403352 ↗
37. 10.1002/adma.20210907810.1002/adma.202109078 ↗
38. 10.1002/admi.20220054710.1002/admi.202200547 ↗
39. 10.1002/pip.51810.1002/pip.518 ↗
40. 10.1002/adma.20220624210.1002/adma.202206242 ↗
41. 10.1039/D2EE02261C10.1039/D2EE02261C ↗
42. 10.1002/advs.20210514210.1002/advs.202105142 ↗
43. 10.1002/advs.20230424610.1002/advs.202304246 ↗
44. 10.1002/adma.20230584110.1002/adma.202305841 ↗
45. 10.1039/D3TA00554B10.1039/D3TA00554B ↗
46. 10.1002/adfm.20220840910.1002/adfm.202208409 ↗
47. 10.1016/j.apcatb.2021.12049410.1016/j.apcatb.2021.120494 ↗
48. 10.1007/s10562-019-03084-z10.1007/s10562-019-03084-z ↗
49. 10.1016/j.cej.2023.14672210.1016/j.cej.2023.146722 ↗
50. 10.1557/mrc.2018.9410.1557/mrc.2018.94 ↗
51. 10.3390/nano1007135810.3390/nano10071358 ↗
52. 10.1016/j.jmat.2021.02.00910.1016/j.jmat.2021.02.009 ↗
53. 10.1021/acsaem.9b0219210.1021/acsaem.9b02192 ↗
54. 10.1063/1.514075110.1063/1.5140751 ↗
55. 10.1039/C8TA11783G10.1039/C8TA11783G ↗
56. 10.1002/sus2.4410.1002/sus2.44 ↗
57. 10.1088/1674-4926/44/8/08050110.1088/1674-4926/44/8/080501 ↗
58. 10.1039/D2TA01465C10.1039/D2TA01465C ↗
59. 10.1002/aenm.20190250910.1002/aenm.201902509 ↗
60. 10.1002/ange.20241310810.1002/ange.202413108 ↗
61. 10.1038/s41467-019-09057-510.1038/s41467-019-09057-5 ↗
62. 10.1103/PhysRevB.87.20512510.1103/PhysRevB.87.205125 ↗
63. 10.1016/j.jallcom.2023.17075310.1016/j.jallcom.2023.170753 ↗
64. 10.1002/sus2.16010.1002/sus2.160 ↗
65. 10.1002/inf2.1240010.1002/inf2.12400 ↗
66. 10.1039/D2TA00893A10.1039/D2TA00893A ↗
67. 10.1002/adfm.20231497410.1002/adfm.202314974 ↗
68. 10.1002/sstr.20230033910.1002/sstr.202300339 ↗
69. 10.1016/0143-148X(80)90017-810.1016/0143-148X(80)90017-8 ↗
70. 10.1016/S0012-8252(02)00089-210.1016/S0012-8252(02)00089-2 ↗
71. 10.1016/j.solmat.2021.11104510.1016/j.solmat.2021.111045 ↗
72. 10.1021/acsami.0c0818010.1021/acsami.0c08180 ↗
73. 10.1016/j.ijhydene.2024.01.31110.1016/j.ijhydene.2024.01.311 ↗
74. 10.1021/acsaem.3c0158010.1021/acsaem.3c01580 ↗
75. 10.1002/adfm.20230414110.1002/adfm.202304141 ↗
76. 10.1016/j.jcis.2024.05.05510.1016/j.jcis.2024.05.055 ↗
77. 10.1002/advs.20220235610.1002/advs.202202356 ↗
78. 10.1016/j.nanoen.2024.10944810.1016/j.nanoen.2024.109448 ↗
79. 10.1016/j.solmat.2016.11.03310.1016/j.solmat.2016.11.033 ↗
80. 10.1021/nn403058f10.1021/nn403058f ↗
81. 10.1002/solr.20220111510.1002/solr.202201115 ↗
82. 10.1016/j.surfin.2023.10341110.1016/j.surfin.2023.103411 ↗
83. 10.1016/j.solmat.2018.07.00410.1016/j.solmat.2018.07.004 ↗
84. 10.1021/acsami.9b0122010.1021/acsami.9b01220 ↗