High‐Performance Organic Field‐Effect Transistors Based on Single and Large‐Area Aligned Crystalline Microribbons of 6,13‐Dichloropentacene

Single and large-area aligned crystalline microribbons of 6,13-dichloropentacene (DCP) are prepared. The ribbons display excellent charge transport properties with a mobility of up to 9.0 cm2 V−1 s−1 in ambient conditions, one of the highest values reported for organic semiconductors. The slipped π-π stacking with large intermolecular overlap is responsible for the high mobility of DCP ribbons. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.