Mechanical Durability and Flexibility in Perovskite Photovoltaics: Advancements and Applications

Abstract The remarkable progress in perovskite solar cell (PSC) technology has witnessed a remarkable leap in efficiency within the past decade. As this technology continues to mature, flexible PSCs (F‐PSCs) are emerging as pivotal components for a wide array of applications, spanning from powering portable electronics and wearable devices to integrating seamlessly into electronic textiles and large‐scale industrial roofing. F‐PSCs characterized by their lightweight, mechanical flexibility, and adaptability for cost‐effective roll‐to‐roll manufacturing, hold immense commercial potential. However, the persistent concerns regarding the overall stability and mechanical robustness of these devices loom large. This comprehensive review delves into recent strides made in enhancing the mechanical stability of F‐PSCs. It covers a spectrum of crucial aspects, encompassing perovskite material optimization, precise crystal grain regulation, film quality enhancement, strategic interface engineering, innovational developed flexible transparent electrodes, judicious substrate selection, and the integration of various functional layers. By collating and analyzing these dedicated research endeavors, this review illuminates the current landscape of progress in addressing the challenges surrounding mechanical stability. Furthermore, it provides valuable insights into the persistent obstacles and bottlenecks that demand attention and innovative solutions in the field of F‐PSCs.