journal article·2016-05Open access

A Novel Alkylated Indacenodithieno[3,2‐b]thiophene‐Based Polymer for High‐Performance Field‐Effect Transistors

Weimin Zhang, Yang Han, Xiuxiu Zhu, Zhuping Fei, Yu Feng, Neil D. Treat, Hendrik Faber, Natalie Stingelin, Iain McCulloch, Thomas D. Anthopoulos, Martin Heeney

Advanced Materials· Volume 28· Issue 20

Abstract

A novel rigid donor monomer, indacenodithieno[3,2-b]thiophene (IDTT), containing linear alkyl chains, is reported. Its copolymer with benzothiadiazole is an excellent p-type semiconductor, affording a mobility of 6.6 cm(2) V(-1) s(-1) in top-gated field-effect transistors with pentafluorobenzenethiol-modified Au electrodes. Electrode treatment with solution-deposited copper(I) thiocyanate (CuSCN) has a beneficial hole-injection/electron-blocking effect, further enhancing the mobility to 8.7 cm(2) V(-1) s(-1) .
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Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Semiconductor materials and devices

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Affiliations

College of Chemistry and Chemical Engineering Guangxi University for Nationalities Nanning 530006 P. R. China

Department of Chemistry and Centre for Plastic Electronics Imperial College London London SW7 2AZ UK

Department of Physics and Centre for Plastic Electronics Imperial College London London SW7 2AZ UK

Department of Materials and Centre for Plastic Electronics Imperial College London London SW7 2AZ UK

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