journal article·2015-02

Fast Printing and In Situ Morphology Observation of Organic Photovoltaics Using Slot‐Die Coating

Feng Liu, Sunzida Ferdous, Eric Schaible, Alexander Hexemer, Matthew Church, Xiaodong Ding, Cheng Wang, Thomas P. Russell

Advanced Materials· Volume 27· Issue 5
Publisher page

Abstract

The mini-slot-die coater offers a simple, convenient, materials-efficient route to print bulk-heterojunction (BHJ) organic photovoltaics (OPVs) that show efficiencies similar to spin-coating. Grazing-incidence X-ray diffraction (GIXD) and GI small-angle X-ray scattering (GISAXS) methods are used in real time to characterize the active-layer formation during printing. A polymer-aggregation-phase-separation-crystallization mechanism for the evolution of the morphology describes the observations.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Thin-Film Transistor Technologies · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Polymer Science and Engineering University of Massachusetts Amherst MA 01003 USA

Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA

Advanced Light Source Lawrence Berkeley National Laboratory Berkeley CA 94720 USA

Jema Science Inc Berkeley California 94720 USA

References (27)

Show source-provided references
1. 10.1002/adma.20090369710.1002/adma.200903697 ↗
2. 10.1002/anie.20070250610.1002/anie.200702506 ↗
3. 10.1021/cr050149z10.1021/cr050149z ↗
4. 10.1038/ncomms241110.1038/ncomms2411 ↗
5. 10.1039/c1ee01891d10.1039/c1ee01891d ↗
6. 10.1039/b9nr00430k10.1039/b9nr00430k ↗
7. 10.1016/S1369-7021(12)70019-610.1016/S1369-7021(12)70019-6 ↗
8. 10.1002/polb.2306310.1002/polb.23063 ↗
9. 10.1016/j.progpolymsci.2013.07.01010.1016/j.progpolymsci.2013.07.010 ↗
10. 10.1002/adma.20120090210.1002/adma.201200902 ↗
11. 10.1021/ja408923y10.1021/ja408923y ↗
12. 10.1002/aenm.20120102710.1002/aenm.201201027 ↗
13. 10.1002/aenm.20110072610.1002/aenm.201100726 ↗
14. 10.1021/ja405493j10.1021/ja405493j ↗
15. 10.1021/ja210474710.1021/ja2104747 ↗
16. 10.1021/ja208556410.1021/ja2085564 ↗
17. 10.1021/ja710079w10.1021/ja710079w ↗
18. 10.1021/nl202052610.1021/nl2020526 ↗
19. 10.1021/nn203627910.1021/nn2036279 ↗
20. 10.1002/aenm.20110000710.1002/aenm.201100007 ↗
21. 10.1021/ma200033810.1021/ma2000338 ↗
22. 10.1088/0034-4885/76/2/02250110.1088/0034-4885/76/2/022501 ↗
23. 10.1039/c0sm00343c10.1039/c0sm00343c ↗
24. 10.1002/adma.20070309710.1002/adma.200703097 ↗
25. 10.1002/adma.20130362210.1002/adma.201303622 ↗
26. 10.1107/S002188981001577310.1107/S0021889810015773 ↗
27. 10.1063/1.45300610.1063/1.453006 ↗