Plasmonic Near‐Infrared‐Response S‐Scheme ZnO/CuInS₂ Photocatalyst for H₂O₂ Production Coupled with Glycerin Oxidation

Abstract Solar fuel synthesis is intriguing because solar energy is abundant and this method compensates for its intermittency. However, most photocatalysts can only absorb UV‐to‐visible light, while near‐infrared (NIR) light remains unexploited. Surprisingly, the charge transfer between ZnO and CuInS₂ quantum dots (QDs) can transform a NIR‐inactive ZnO into a NIR‐active composite. This strong response is attributed to the increased concentration of free charge carriers in the p‐type semiconductor at the interface after the charge migration between ZnO and CuInS₂, enhancing the localized surface plasmon resonance (LSPR) effect and the NIR response of CuInS₂. As a paradigm, this ZnO/CuInS₂ heterojunction is used for H₂O₂ production coupled with glycerin oxidation and demonstrates supreme performance, corroborating the importance of NIR response and efficient charge transfer. Mechanistic studies through contact potential difference (CPD), Hall effect test, and finite element method (FEM) calculation allow for the direct correlation between the NIR response and charge transfer. This approach bypasses the general light response issues, thereby stepping forward to the ambitious goal of harnessing the entire solar spectrum.