Ferroic alternation in methylammonium lead triiodide perovskite
Source abstract
Abstract
Abstract Methylammonium lead triiodide (MAPbI3) perovskite has attracted broad interest for solar cells, light‐emitting diodes, and so forth. Experiments have captured that the alternative coexistence of polar and nonpolar domains in MAPbI3 can be switched by photons and phonons. Therefore, it is urgent to clarify the interplay among the crystal space group, polarity, ferroic properties, and switching mechanisms for MAPbI3. Herein, we perform a statistical synthesis on ferroelectric and anti‐ferroelectric features for tetragonal MAPbI3 perovskite. The polar and nonpolar domains are ferroelectric with the I4cm space group and anti‐ferroelectric with the I4/mcm space group, respectively. The domain wall (DW) separating nonpolar and polar regions is charged. Combining the effects of the electric properties of ferroic domains and the charged DWs, novel switching mechanisms are proposed in which photons and phonons drive alternations between ferroelectric and anti‐ferroelectric domains, which provide a reasonable approach to clarify the ambiguous understanding of ferroic behavior for MAPbI3 perovskite. image
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Perovskite Materials and Applications · Solid-state spectroscopy and crystallography · 2D Materials and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Materials Science and Engineering, School of Mechanical Engineering Shijiazhuang Tiedao University Shijiazhuang China
Centre for Advanced Structural Materials City University of Hong Kong Shenzhen Research Institute, Greater Bay Joint Division, Shenyang National Laboratory for Materials Science Shenzhen China
CityU‐Shenzhen Futian Research Institute Shenzhen China
Department of Mechanics Sichuan University Chengdu China
Department of Mechanical Engineering City University of Hong Kong Kowloon, Hong Kong China
Funding
Nanjing University of Aeronautics and Astronautics · National Natural Science Foundation of China · Natural Science Foundation of Hebei Province
References (100+)
Show source-provided references
1. 10.1021/ja809598r10.1021/ja809598r ↗
2. 10.1002/anie.20160278710.1002/anie.201602787 ↗
3. 10.1038/s41563-020-0784-710.1038/s41563-020-0784-7 ↗
4. 10.1038/s41467-019-09794-710.1038/s41467-019-09794-7 ↗
5. 10.1038/s41566-019-0466-710.1038/s41566-019-0466-7 ↗
6. 10.1038/s41566-020-0678-x10.1038/s41566-020-0678-x ↗
7. 10.1002/adma.20200198110.1002/adma.202001981 ↗
8. 10.1038/nature2403210.1038/nature24032 ↗
9. 10.1038/nphoton.2017.9410.1038/nphoton.2017.94 ↗
10. High‐quality cuboid CH3NH3PbI3 single crystals for high performance X‐ray and photon detectors10.1002/adfm.201806984 ↗
11. 10.1002/pssr.20180038010.1002/pssr.201800380 ↗
12. 10.1126/sciadv.aay081510.1126/sciadv.aay0815 ↗
13. Two‐dimensional halide perovskite as beta‐ray scintillator for nuclear radiation monitoring10.1038/s41467-020-17114-7 ↗
14. 10.1038/s41586-020-2285-x10.1038/s41586-020-2285-x ↗
15. 10.1002/adfm.20200250310.1002/adfm.202002503 ↗
16. 10.1021/acsami.0c1085110.1021/acsami.0c10851 ↗
17. 10.1021/acs.nanolett.8b0320910.1021/acs.nanolett.8b03209 ↗
18. 10.1016/j.scib.2019.12.01510.1016/j.scib.2019.12.015 ↗
19. 10.1002/aisy.20200012210.1002/aisy.202000122 ↗
20. 10.1021/acsami.9b1292410.1021/acsami.9b12924 ↗
21. Health hazards of methylammonium lead iodide based perovskites: cytotoxicity studies10.1039/C5TX00303B ↗
22. 10.1039/C9NR03647D10.1039/C9NR03647D ↗
23. 10.1021/acsami.9b1653310.1021/acsami.9b16533 ↗
24. 10.1038/s41586-020-2602-410.1038/s41586-020-2602-4 ↗
25. Ferroic domains regulate photocurrent in single‐crystalline CH3NH3PbI3 films self‐grown on FTO/TiO2 substrate10.1038/s41535-018-0104-5 ↗
26. 10.1126/science.124398210.1126/science.1243982 ↗
27. 10.1021/nl400349b10.1021/nl400349b ↗
28. First‐principles study of mixed cation methylammonium‐formamidinium hybrid perovskite10.3866/PKU.WHXB201801082 ↗
29. Metal halide perovskite optoelectronic material and device
30. 10.1007/s11771-020-4353-710.1007/s11771-020-4353-7 ↗
31. 10.1038/s41563-018-0152-z10.1038/s41563-018-0152-z ↗
32. Ovchinnikova. Reply to: on the ferroelectricity of CH3NH3PbI3 perovskites10.1038/s41563-019-0481-6 ↗
33. Ferroelectricity‐free lead halide perovskites10.1039/C9EE00884E ↗
34. 10.1007/s12598-020-01703-y10.1007/s12598-020-01703-y ↗
35. 10.1007/s12598-020-01579-y10.1007/s12598-020-01579-y ↗
36. https://www.nrel.gov/pv/cell-efficiency.html(Accessed: July 03 2021).
37. On the ferroelectricity of CH3NH3PbI3 perovskites10.1038/s41563-019-0480-7 ↗
38. Antiferroelectric‐to‐ferroelectric switching in CH3NH3PbI3 perovskite and its potential role in effective charge separation in perovskite solar cells10.1103/PhysRevApplied.6.024007 ↗
39. Tuning the ferroelectric polarization in a multiferroic metal‐organic framework10.1021/ja408283a ↗
40. 10.1002/anie.20110140510.1002/anie.201101405 ↗
41. 10.1002/adma.20120473810.1002/adma.201204738 ↗
42. Equilibrium structure of epitaxial layers10.1002/pssa.2210370141 ↗
43. 10.1016/S1359-6454(96)00058-410.1016/S1359-6454(96)00058-4 ↗
44. 10.1016/S1359-6454(96)00059-610.1016/S1359-6454(96)00059-6 ↗
45. 10.1063/1.489163210.1063/1.4891632 ↗
46. 10.1039/C4EE02465F10.1039/C4EE02465F ↗
47. 10.1021/jz502429u10.1021/jz502429u ↗
48. 10.1021/jz502111u10.1021/jz502111u ↗
49. Semiconducting tin and lead iodide perovskites with organic cations: phase transitions, high mobilities, and near‐infrared photoluminescent properties. Inorg
50. Non‐ferroelectric nature of the conductance hysteresis in CH3NH3PbI3 perovskite‐based photovoltaic devices10.1063/1.4919109 ↗
51. 10.1039/C4CE02106A10.1039/C4CE02106A ↗
52. 10.1039/c3ta10518k10.1039/c3ta10518k ↗
53. 10.1073/pnas.170242911410.1073/pnas.1702429114 ↗
54. 10.1021/jz501697b10.1021/jz501697b ↗
55. 10.1039/C7EE00420F10.1039/C7EE00420F ↗
56. On the importance of ferroelectric domains for the performance of perovskite solar cells10.1016/j.nanoen.2018.02.049 ↗
57. Nanoscale ferroelectric characterization with heterodyne megasonic piezoresponse force microscopy10.1002/advs.202003993 ↗
58. 10.1021/nl500390f10.1021/nl500390f ↗
59. 10.1021/cm503204610.1021/cm5032046 ↗
60. 10.1021/acs.jpclett.5b0054210.1021/acs.jpclett.5b00542 ↗
61. 10.1021/jz502109e10.1021/jz502109e ↗
62. 10.1063/1.45346710.1063/1.453467 ↗
63. 10.1038/nmat415010.1038/nmat4150 ↗
64. Tunable ferroelectric polarization and its interplay with spin–orbit coupling in tin iodide perovskites10.1038/ncomms6900 ↗
65. 10.1126/sciadv.160216510.1126/sciadv.1602165 ↗
66. 10.1002/adma.20190287010.1002/adma.201902870 ↗
67. 10.1021/jp404865910.1021/jp4048659 ↗
68. 10.1021/acs.jpcc.7b0592910.1021/acs.jpcc.7b05929 ↗
69. 10.1021/acs.jpclett.5b0038910.1021/acs.jpclett.5b00389 ↗
70. Is CH3NH3PbI3 polar?10.1021/acs.jpclett.6b00803 ↗
71. 10.1063/1.489024610.1063/1.4890246 ↗
72. Ferroelectric domain wall induced band gap reduction and charge separation in organometal halide perovskites10.1021/jz502666j ↗
73. Entropy‐suppressed ferroelectricity in hybrid lead‐iodide perovskites10.1021/acs.jpclett.5b02117 ↗
74. Antiferroelectric nature of CH3NH3PbI3‐xClx perovskite and its implication for charge separation in perovskite solar cells10.1038/srep30680 ↗
75. 10.1002/adfm.20160028410.1002/adfm.201600284 ↗
76. 10.1002/aenm.20190283010.1002/aenm.201902830 ↗
77. Polar or nonpolar? That is not the question for perovskite solar cells10.1093/nsr/nwab094 ↗
78. Tailoring properties of hybrid perovskites by domain‐width engineering with charged walls10.1038/s41524-018-0134-3 ↗
79. 10.1038/srep3568510.1038/srep35685 ↗
80. 10.1002/adfm.20170180410.1002/adfm.201701804 ↗
81. Phase transitions in the perovskite methylammonium lead bromide, CH3ND3PbBr310.1016/S0022-4596(03)00352-9 ↗
82. 10.1016/j.jssc.2004.12.03710.1016/j.jssc.2004.12.037 ↗
83. 10.1039/C4CC09944C10.1039/C4CC09944C ↗
84. Cation rotation in methylammoniumlead halides10.1016/0038-1098(85)90959-7 ↗
85. Dielectric study of CH3NH3PbX3(X = cl, Br, I)10.1016/0022-3697(92)90121-S ↗
86. 10.1021/nl403514x10.1021/nl403514x ↗
87. 10.1039/C5NR06386H10.1039/C5NR06386H ↗
88. 10.1103/PhysRevB.94.21411410.1103/PhysRevB.94.214114 ↗
89. 10.1002/anie.20191059910.1002/anie.201910599 ↗
90. 10.3390/cryst806023210.3390/cryst8060232 ↗
91. 10.1021/acsaem.7b0033010.1021/acsaem.7b00330 ↗
92. 10.1002/ente.20180098910.1002/ente.201800989 ↗
93. 10.1002/adma.20180666110.1002/adma.201806661 ↗
94. 10.1063/1.507963310.1063/1.5079633 ↗
95. 10.1021/acs.jpcc.5b1146910.1021/acs.jpcc.5b11469 ↗
96. 10.1039/C5TA01325A10.1039/C5TA01325A ↗
97. 10.1021/acs.jpclett.6b0021510.1021/acs.jpclett.6b00215 ↗
98. 10.1021/acs.nanolett.5b0454510.1021/acs.nanolett.5b04545 ↗
99. The physical properties of bismuth replacement in lead halogen perovskite solar cells: CH3NH3Pb1−xBixI3 compounds by ab‐initio calculations10.1016/j.rinp.2019.102278 ↗
100. Thermal expansion of SrZrO3 and BaZrO3 perovskites10.1007/BF00200187 ↗