A comparative review of the adsorption efficiency and performance variances of metal oxide nanoparticles and pristine carbon nanotubes for Pb2+ sequestration
Source abstract
Abstract
Lead (Pb²⁺) contamination in aquatic systems poses a major threat to human health and environmental safety. Conventional remediation techniques such as chemical precipitation and ion exchange are often constrained by high operational costs, poor efficiency at trace concentrations, and secondary pollution. Nanotechnology has introduced materials like carbon nanotubes (CNTs) and metal oxide nanoparticles (MONPs) with superior physicochemical reactivity for Pb²⁺ removal. This review highlights recent advances (2002-2025) in adsorption-desorption behaviour of Pb²⁺ on MONPs and pristine CNTs, focusing on synthesis, surface properties, adsorption mechanisms, reusability, and toxicity. Reported findings reveal that MONPs, including Fe₃O₄, ZnO, MgO, and CuO, exhibit outstanding adsorption capacities (up to 1980 mg g⁻¹ for MgONPs), surpassing those of CNTs which usually range between 10 and 250 mg g-1 under comparable conditions. This performance is linked to the abundance of chemically active surface sites and electrostatic interactions, which dominate adsorption on MONPs. Desorption studies confirm both materials are reusable over multiple cycles, though MONPs demonstrate higher regeneration efficiency and lower toxicity. Overall, MONPs present more scalable and eco-friendly alternatives for Pb²⁺ remediation. Future research should refine regeneration strategies, assess environmental safety, and develop hybrid systems for sustainable water treatment.
Source: europepmc · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Adsorption and biosorption for pollutant removal · Chemical Synthesis and Characterization · Layered Double Hydroxides Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Abd El fatah M, Ossman ME. Removal of Heavy Metal by Nickel Oxide Nano Powder. Int J Environ Res. 2014;8(3):741–50. https://doi.org/10.22059/ijer.2014.768.10.22059/ijer.2014.768 ↗
2. Abdel Salam ET, El-Nour A, Awad KM, A. A., Orabi AS. Carbon nanotubes modified with 5,7-dinitro-8-quinolinol as potentially applicable tool for efficient removal of industrial wastewater pollutants. Arabian Journal of Chemistry. 2017;13. https://doi.org/10.1016/j.arabjc.2017.02.005.10.1016/j.arabjc.2017.02.005 ↗
3. Abdel Salam M. Removal of heavy metal ions from aqueous solutions with multi-walled carbon nanotubes: Kinetic and thermodynamic studies. Int J Environ Sci Technol. 2013;10(4):677–88. https://doi.org/10.1007/s13762-012-0127-6.10.1007/s13762-012-0127-6 ↗
4. Abdelrahman MS, Nassar SH, Mashaly H, Mahmoud S, Maamoun D, El-Sakhawy M, Khattab TA, Kamel S. (2020). Studies of Polylactic Acid and Metal Oxide Nanoparticles-Based Composites for Multifunctional Textile Prints. In Coatings (Vol. 10, Issue 1, p. 58). https://doi.org/10.3390/coatings10010058.10.3390/coatings10010058 ↗
5. Agasti N. Decontamination of heavy metal ions from water by composites prepared from waste. Curr Res Green Sustainable Chem. 2021;4:100088. https://doi.org/10.1016/j.crgsc.2021.100088.10.1016/j.crgsc.2021.100088 ↗
6. Ahmadi A, Heidarzadeh S, Mokhtari AR, Darezereshki E, Harouni HA. Optimization of heavy metal removal from aqueous solutions by maghemite (γ-Fe2O3) nanoparticles using response surface methodology. J Geochem Explor. 2014;147:151–8. https://doi.org/10.1016/j.gexplo.2014.10.005.10.1016/j.gexplo.2014.10.005 ↗
7. Ahmed B, Rizvi A, Ali K, Lee J, Zaidi A, Khan MS, Musarrat J. Nanoparticles in the soil–plant system: a review. In Environmental Chemistry Letters. 2021;19(2). https://doi.org/10.1007/s10311-020-01138-y.10.1007/s10311-020-01138-y ↗
8. Ahmed MA, Ali SM, El-Dek SI, Galal A. Magnetite–hematite nanoparticles prepared by green methods for heavy metal ions removal from water. Mater Sci Engineering: B. 2013;178(10):744–51. https://doi.org/10.1016/j.mseb.2013.03.011.10.1016/j.mseb.2013.03.011 ↗
9. Aigbe UO, Osibote OA. Green synthesis of metal oxide nanoparticles, and their various applications. J Hazard Mater Adv. 2024;13:100401. https://doi.org/10.1016/j.hazadv.2024.100401.10.1016/j.hazadv.2024.100401 ↗
10. Akpomie KG, Conradie J, Adegoke KA, Oyedotun KO, Ighalo JO, Amaku JF, Olisah C, Adeola AO, Iwuozor KO. Adsorption mechanism and modeling of radionuclides and heavy metals onto ZnO nanoparticles: a review. Appl Water Sci. 2023;13(1):1–24. https://doi.org/10.1007/s13201-022-01827-9.10.1007/s13201-022-01827-9 ↗
11. Al Yaqoob K, Bououdina M, Akhter MS, Najar A, B., Vijaya JJ. Selectivity and efficient Pb and Cd ions removal by magnetic MFe2O4 (M = Co, Ni, Cu and Zn) nanoparticles. Mater Chem Phys. 2019;232:254–64. https://doi.org/10.1016/j.matchemphys.2019.04.077.10.1016/j.matchemphys.2019.04.077 ↗
12. Alaqarbeh M. RHAZES: Green and Applied Chemistry Adsorption Types : Short Review. RHAZES: Green Appl Chem. 2021;13:43–51.
13. Ali AA, Ahmed IS, Elfiky EM. Auto-combustion Synthesis and Characterization of Iron Oxide Nanoparticles (α-Fe2O3) for Removal of Lead Ions from Aqueous Solution. J Inorg Organomet Polym Mater. 2021;31(1):384–96. https://doi.org/10.1007/s10904-020-01695-3.10.1007/s10904-020-01695-3 ↗
14. Ali Z, Ullah R, Tuzen M, Ullah S, Rahim A, Saleh TA. Colorimetric sensing of heavy metals on metal doped metal oxide nanocomposites: A review. Trends Environ Anal Chem. 2023;37:e00187. https://doi.org/10.1016/j.teac.2022.e00187.10.1016/j.teac.2022.e00187 ↗
15. Aliasghar R, Aliakbar B, Shakeri A, Khashayar S, Allahkaram L. Thermodynamic Investigation of Pb2 + and Cd2 + Ions Absorption from Aqueous Solutions Using Multi-Walled Carbon Nanotubes. Curr J Appl Sci Technol. 2014;4(10):1497–508. https://doi.org/10.9734/BJAST/2014/8384.10.9734/BJAST/2014/8384 ↗
16. Arora G, Sabran NS, Ng CY, Low FW, Jun HK. Applications of carbon quantum dots in electrochemical energy storage devices. Heliyon. 2024;10(15):e35543. https://doi.org/10.1016/j.heliyon.2024.e35543.10.1016/j.heliyon.2024.e35543 ↗
17. Awasthi S, Srivastava A, Kumar D, Pandey SK, Mubarak NM, Dehghani MH, Ansari K. An insight into the toxicological impacts of carbon nanotubes (CNTs) on human health: A review. Environ Adv. 2024;18:100601. https://doi.org/10.1016/j.envadv.2024.100601.10.1016/j.envadv.2024.100601 ↗
18. Azizi S, Mahdavi Shahri M, Mohamad R. (2017). Green Synthesis of Zinc Oxide Nanoparticles for Enhanced Adsorption of Lead Ions from Aqueous Solutions: Equilibrium, Kinetic and Thermodynamic Studies. In Molecules (Vol. 22, Issue 6, p. 831). https://doi.org/10.3390/molecules22060831.10.3390/molecules22060831 ↗
19. Baby R, Saifullah B, Hussein MZ. Carbon Nanomaterials for the Treatment of Heavy Metal-Contaminated Water and Environmental Remediation. Nanoscale Res Lett. 2019;14(1):341. https://doi.org/10.1186/s11671-019-3167-8.10.1186/s11671-019-3167-8 ↗
20. Bagbi Y, Sarswat A, Mohan D, Pandey A, Solanki PR. (2016). Lead (Pb2+) adsorption by monodispersed magnetite nanoparticles: Surface analysis and effects of solution chemistry. Journal of Environmental Chemical Engineering, 4(4, Part A), 4237–4247. https://doi.org/10.1016/j.jece.2016.09.026.10.1016/j.jece.2016.09.026 ↗
21. Cao C-Y, Qu J, Wei F, Liu H, Song W-G. Superb Adsorption Capacity and Mechanism of Flowerlike Magnesium Oxide Nanostructures for Lead and Cadmium Ions. ACS Appl Mater Interfaces. 2012;4(8):4283–7. https://doi.org/10.1021/am300972z.10.1021/am300972z ↗
22. Chatterjee A, Deopura BL. Carbon nanotubes and nanofibre: An overview. Fibers Polym. 2002;3(4):134–9. https://doi.org/10.1007/BF02912657.10.1007/BF02912657 ↗
23. Chawla J, Kumar R, Kaur I. Carbon nanotubes and graphenes as adsorbents for adsorption of lead ions from water: a review. J Water Supply: Res Technology-Aqua. 2015;64(6):641–59. https://doi.org/10.2166/aqua.2015.102.10.2166/aqua.2015.102 ↗
24. Chen J, He F, Zhang H, Zhang X, Zhang G, Yuan G. Novel Core–Shell Structured Mn–Fe/MnO2 Magnetic Nanoparticles for Enhanced Pb(II) Removal from Aqueous Solution. Ind Eng Chem Res. 2014;53(48):18481–8. https://doi.org/10.1021/ie502967a.10.1021/ie502967a ↗
25. Chen Q, Wang H, Tang X, Ba Z, Zhao X, Wang Y, Deng H. One-step synthesis of carbon quantum dot-carbon nanotube composites on waste eggshell-derived catalysts for enhanced adsorption of methylene blue. J Environ Chem Eng. 2021;9(5):106222. https://doi.org/10.1016/j.jece.2021.106222.10.1016/j.jece.2021.106222 ↗
26. Cho G, Azzouzi S, Zucchi G, Lebental B. (2022). Electrical and Electrochemical Sensors Based on Carbon Nanotubes for the Monitoring of Chemicals in Water—A Review. In Sensors (Vol. 22, Issue 1, p. 218). https://doi.org/10.3390/s22010218.10.3390/s22010218 ↗
27. Culita DC, Simonescu CM, Dragne M, Stanica N, Munteanu C, Preda S, Oprea O. (2015). Effect of surfactant concentration on textural, morphological and magnetic properties of CoFe2O4 nanoparticles and evaluation of their adsorptive capacity for Pb(II) ions. Ceramics International, 41(10, Part A), 13553–13560. https://doi.org/10.1016/j.ceramint.2015.07.150.10.1016/j.ceramint.2015.07.150 ↗
28. Dargahi A, Gholestanifar H, Darvishi P, Karami A, Hasan SH, Poormohammadi A, Behzadnia A. An Investigation and Comparison of Removing Heavy Metals (Lead and Chromium) from Aqueous Solutions Using Magnesium Oxide Nanoparticles. Pol J Environ Stud. 2016;25(2):557–62. https://doi.org/10.15244/pjoes/60281.10.15244/pjoes/60281 ↗
29. Dehghani MH, Ahmadi S, Ghosh S, Othmani A, Osagie C, Meskini M, AlKafaas SS, Malloum A, Khanday WA, Jacob AO, Gökkuş Ö, Oroke A, Chineme M, Karri O, R. R., Lima EC. Recent advances on sustainable adsorbents for the remediation of noxious pollutants from water and wastewater: A critical review. Arab J Chem. 2023;16(12):105303. https://doi.org/10.1016/j.arabjc.2023.105303.10.1016/j.arabjc.2023.105303 ↗
30. Dehghani MH, Yetilmezsoy K, Salari M, Heidarinejad Z, Yousefi M, Sillanpää M. Adsorptive removal of cobalt(II) from aqueous solutions using multi-walled carbon nanotubes and γ-alumina as novel adsorbents: Modelling and optimization based on response surface methodology and artificial neural network. J Mol Liq. 2020;299:112154. https://doi.org/10.1016/j.molliq.2019.112154.10.1016/j.molliq.2019.112154 ↗
31. Dinh V-P, Le N-C, Tuyen LA, Hung NQ, Nguyen V-D, Nguyen N-T. Insight into adsorption mechanism of lead(II) from aqueous solution by chitosan loaded MnO2 nanoparticles. Mater Chem Phys. 2018;207:294–302. https://doi.org/10.1016/j.matchemphys.2017.12.071.10.1016/j.matchemphys.2017.12.071 ↗
32. Donaldson K, Poland CA, Murphy FA, MacFarlane M, Chernova T, Schinwald A. Pulmonary toxicity of carbon nanotubes and asbestos - similarities and differences. Adv Drug Deliv Rev. 2013;65(15):2078–86. https://doi.org/10.1016/j.addr.2013.07.014.10.1016/j.addr.2013.07.014 ↗
33. Egbosiuba TC, Egwunyenga MC, Tijani JO, Mustapha S, Abdulkareem AS, Kovo AS, Krikstolaityte V, Veksha A, Wagner M, Lisak G. Activated multi-walled carbon nanotubes decorated with zero valent nickel nanoparticles for arsenic, cadmium and lead adsorption from wastewater in a batch and continuous flow modes. J Hazard Mater. 2022;423:126993. https://doi.org/10.1016/j.jhazmat.2021.126993.10.1016/j.jhazmat.2021.126993 ↗
34. El-Kassas HY, Aly-Eldeen MA, Gharib SM. Green synthesis of iron oxide (Fe3O4) nanoparticles using two selected brown seaweeds: Characterization and application for lead bioremediation. Acta Oceanol Sin. 2016;35(8):89–98. https://doi.org/10.1007/s13131-016-0880-3.10.1007/s13131-016-0880-3 ↗
35. Engates KE, Shipley HJ. Adsorption of Pb, Cd, Cu, Zn, and Ni to titanium dioxide nanoparticles: effect of particle size, solid concentration, and exhaustion. Environ Sci Pollut Res. 2011;18(3):386–95. https://doi.org/10.1007/s11356-010-0382-3.10.1007/s11356-010-0382-3 ↗
36. Farghali AA, Bahgat M, Allah E, A., Khedr MH. Adsorption of Pb(II) ions from aqueous solutions using copper oxide nanostructures. Beni-Suef Univ J Basic Appl Sci. 2013;2(2):61–71. https://doi.org/10.1016/j.bjbas.2013.01.001.10.1016/j.bjbas.2013.01.001 ↗
37. Farooq U, Kozinski JA, Khan MA, Athar M. Biosorption of heavy metal ions using wheat based biosorbents – A review of the recent literature. Bioresour Technol. 2010;101(14):5043–53. https://doi.org/10.1016/j.biortech.2010.02.030.10.1016/j.biortech.2010.02.030 ↗
38. Fiyadh SS, AlSaadi MA, AlOmar MK, Fayaed SS, Hama AR, Bee S, El-Shafie A. The modelling of lead removal from water by deep eutectic solvents functionalized CNTs: Artificial neural network (ANN) approach. Water Sci Technol. 2017;76(9):2413–26. https://doi.org/10.2166/wst.2017.393.10.2166/wst.2017.393 ↗
39. Francis AP, Devasena T. Toxicity of carbon nanotubes: A review. Toxicol Ind Health. 2018;34(3). https://doi.org/10.1177/0748233717747472.10.1177/0748233717747472 ↗
40. Fu L, Hamzeh M, Dodard S, Zhao YH, Sunahara GI. Effects of TiO2 nanoparticles on ROS production and growth inhibition using freshwater green algae pre-exposed to UV irradiation. Environ Toxicol Pharmacol. 2015;39(3):1074–80. https://doi.org/10.1016/j.etap.2015.03.015.10.1016/j.etap.2015.03.015 ↗
41. Ghorbani M, Seyedin O, Aghamohammadhassan M. Adsorptive removal of lead (II) ion from water and wastewater media using carbon-based nanomaterials as unique sorbents: A review. Journal of Environmental Management. 2020;254. https://doi.org/10.1016/j.jenvman.2019.109814.10.1016/j.jenvman.2019.109814 ↗
42. Ghosh N, Das S, Biswas G, Haldar PK. Review on some metal oxide nanoparticles as effective adsorbent in wastewater treatment. Water Sci Technol. 2022;85(12):3370–95. https://doi.org/10.2166/wst.2022.153.10.2166/wst.2022.153 ↗
43. Gouda AA. Solid-phase extraction using multiwalled carbon nanotubes and quinalizarin for preconcentration and determination of trace amounts of some heavy metals in food, water and environmental samples. Int J Environ Anal Chem. 2014;94(12):1210–22. https://doi.org/10.1080/03067319.2014.930846.10.1080/03067319.2014.930846 ↗
44. Hang Y, Si Y, Zhou Q, Yin H, Wang A, Cao A. Morphology-controlled synthesis of calcium titanate particles and adsorption kinetics, isotherms, and thermodynamics of Cd(II), Pb(II), and Cu(II) cations. J Hazard Mater. 2019;380:120789. https://doi.org/10.1016/j.jhazmat.2019.120789.10.1016/j.jhazmat.2019.120789 ↗
45. Hassan KH, Mahdi ER. Synthesis and Characterization of Copper,Iron Oxide Nanoparticles used to Remove Lead from Aqueous Solution. Asian J Appl Sci. 2016;4(3). https://ajouronline.com/index.php/AJAS/article/view/3896
46. Hua M, Zhang S, Pan B, Zhang W, Lv L, Zhang Q. Heavy metal removal from water/wastewater by nanosized metal oxides: A review. J Hazard Mater. 2012;211–212:317–31. https://doi.org/10.1016/j.jhazmat.2011.10.016.10.1016/j.jhazmat.2011.10.016 ↗
47. Ifthikar J, Shahib II, Sellaoui L, Jawad A, Zhao M, Chen Z, Chen Z. pH tunable anionic and cationic heavy metal reduction coupled adsorption by thiol cross-linked composite: Physicochemical interpretations and fixed-bed column mathematical model study. Chem Eng J. 2020;401(126041). https://doi.org/10.1016/j.cej.2020.126041.10.1016/j.cej.2020.126041 ↗
48. Ihsanullah, Abbas A, Al-Amer AM, Laoui T, Al-Marri MJ, Nasser MS, Khraisheh M, Atieh MA. Heavy metal removal from aqueous solution by advanced carbon nanotubes: Critical review of adsorption applications. Sep Purif Technol. 2016;157:141–61. https://doi.org/10.1016/j.seppur.2015.11.039.10.1016/j.seppur.2015.11.039 ↗
49. Jaddo A, Ameen M. Materials Advances Enhanced adsorption of an organic dye by phyto- synthesized CuO nanoparticles derived from Malva sylvestris for sustainable environmental remediation. RSC Mater Adv. 2025;6:8139–56. https://doi.org/10.1039/d5ma00697j.10.1039/d5ma00697j ↗
50. Jain AK, Singh D, Dubey K, Maurya R, Pandey AK. Zinc oxide nanoparticles induced gene mutation at the HGPRT locus and cell cycle arrest associated with apoptosis in V-79 cells. J Appl Toxicol. 2019;39(5):735–50. https://doi.org/10.1002/jat.3763.10.1002/jat.3763 ↗
51. Jalu RG, Chamada TA, Kasirajan DR. Calcium oxide nanoparticles synthesis from hen eggshells for removal of lead (Pb(II)) from aqueous solution. Environ Challenges. 2021;4:100193. https://doi.org/10.1016/j.envc.2021.100193.10.1016/j.envc.2021.100193 ↗
52. Kabbashi NA, Atieh MA, Al-Mamun A, Mirghami MES, Alam MDZ, Yahya N. Kinetic adsorption of application of carbon nanotubes for Pb(II) removal from aqueous solution. J Environ Sci. 2009;21(4):539–44. https://doi.org/10.1016/S1001-0742(08)62305-0.10.1016/S1001-0742(08)62305-0 ↗
53. Kamal Z, Ebnalwaled AA, Al-Amgad Z, Saied AA, Metwally AA, Said AH. Immunomodulatory and antioxidant effect of green synthesized titanium dioxide nanoparticles on pregnant female albino rats and their fetuses. Environ Sci Pollut Res. 2023;30(19):55455–70. https://doi.org/10.1007/s11356-023-26264-2.10.1007/s11356-023-26264-2 ↗
54. Karami H. Heavy metal removal from water by magnetite nanorods. Chem Eng J. 2013;219:209–16. https://doi.org/10.1016/j.cej.2013.01.022.10.1016/j.cej.2013.01.022 ↗
55. Kerin H, Nagaraj K, Kamalesu S. Review on aquatic toxicity of metal oxide nanoparticles. Mater Today: Proc. 2023. https://doi.org/10.1016/j.matpr.2023.02.183.10.1016/j.matpr.2023.02.183 ↗
56. Khodakovskaya M, Dervishi E, Mahmood M, Xu Y, Li Z, Watanabe F, Biris AS. Carbon nanotubes are able to penetrate plant seed coat and dramatically affect seed germination and plant growth. ACS Nano. 2009;3(10):3221–7. https://doi.org/10.1021/nn900887m.10.1021/nn900887m ↗
57. Krishna RH, Chandraprabha MN, Samrat K, Murthy K, Manjunatha TP, C., Kumar SG. Carbon nanotubes and graphene-based materials for adsorptive removal of metal ions – A review on surface functionalization and related adsorption mechanism. Appl Surf Sci Adv. 2023;16:100431. https://doi.org/10.1016/j.apsadv.2023.100431.10.1016/j.apsadv.2023.100431 ↗
58. Kucherova AE, Romantsova IV, Burakov AE, Babkin AV, Neskoromnaya EA, Krasnyansky MN. Kinetic Study on Pb(II) Adsorption from Aqueous Solutions on Carbon Materials. Nano Hybrids Compos. 2017;13:334–40. https://doi.org/10.4028/www.scientific.net/NHC.13.334.10.4028/www.scientific.net/NHC.13.334 ↗
59. Kumar S, Nair RR, Pillai PB, Gupta SN, Iyengar MAR, Sood AK. Graphene Oxide–MnFe2O4 Magnetic Nanohybrids for Efficient Removal of Lead and Arsenic from Water. ACS Appl Mater Interfaces. 2014;6(20):17426–36. https://doi.org/10.1021/am504826q.10.1021/am504826q ↗
60. Kumari M, Pittman CU, Mohan D. Heavy metals [chromium (VI) and lead (II)] removal from water using mesoporous magnetite (Fe3O4) nanospheres. J Colloid Interface Sci. 2015;442:120–32. https://doi.org/10.1016/j.jcis.2014.09.012.10.1016/j.jcis.2014.09.012 ↗
61. Li H, Qiu Y. Dispersion, sedimentation and aggregation of multi-walled carbon nanotubes as affected by single and binary mixed surfactants. Royal Soc Open Sci. 2019;6(7):190241. https://doi.org/10.1098/rsos.190241.10.1098/rsos.190241 ↗
62. Li L, Haziq MA, Ullah S, Stanikzai AG, Bibi SD, Haq TU, Tayyeb M, Yang Z. Remediation of Lead-Contaminated Water Using Green Synthesized Iron-Oxide Nanoparticles: Performance and Mechanism. Air Soil Water Res. 2024;17(1). https://doi.org/10.1177/11786221241278517.10.1177/11786221241278517 ↗
63. Li Z, Chen J, Ge Y. Removal of lead ion and oil droplet from aqueous solution by lignin-grafted carbon nanotubes. Chem Eng J. 2017;308:809–17. https://doi.org/10.1016/j.cej.2016.09.126.10.1016/j.cej.2016.09.126 ↗
64. Lingamdinne LP, Koduru JR, Rao Karri R. Green Synthesis of Iron Oxide Nanoparticles for Lead Removal from Aqueous Solutions. Key Eng Mater. 2019;805:122–7. https://doi.org/https://doi.org/10.4028/www.scientific.net/kem.805.122.10.4028/www.scientific.net/KEM.805.122 ↗
65. Liosis C, Papadopoulou A, Karvelas E, Karakasidis TE, Sarris IE. (2021). Heavy Metal Adsorption Using Magnetic Nanoparticles for Water Purification: A Critical Review. In Materials (Vol. 14, Issue 24). https://doi.org/10.3390/ma14247500.10.3390/ma14247500 ↗
66. Liu W-X, Song S, Ye M-L, Zhu Y, Zhao Y-G, Lu Y. Nanomaterials with Excellent Adsorption Characteristics for Sample Pretreatment: A Review. Nanomaterials. 2022;12(11). https://doi.org/10.3390/nano12111845.10.3390/nano12111845 ↗
67. Liu Z, Li B, Shi X, Li L, Feng Y, Jia D, Zhou Y. Target-oriented synthesis of high synthetic yield carbon dots with tailored surface functional groups for bioimaging of zebrafish, flocculation of heavy metal ions and ethanol detection. Appl Surf Sci. 2021;538. https://doi.org/10.1016/j.apsusc.2020.148118.10.1016/j.apsusc.2020.148118 ↗
68. Lung I, Stan M, Opris O, Soran M-L, Senila M, Stefan M. Removal of Lead(II), Cadmium(II), and Arsenic(III) from Aqueous Solution Using Magnetite Nanoparticles Prepared by Green Synthesis with Box–Behnken Design. Anal Lett. 2018;51(16):2519–31. https://doi.org/10.1080/00032719.2018.1446974.10.1080/00032719.2018.1446974 ↗
69. Madji S, Mekatel E, Belmedani M, Cosme J, Zouaoui S, Vieillard J. Synthesis of an original Bi12CoO20/ZnO nanocomposites for lead adsorption. Mater Sci Engineering: B. 2025;319:118345. https://doi.org/10.1016/j.mseb.2025.118345.10.1016/j.mseb.2025.118345 ↗
70. Mahanty S, Chatterjee S, Ghosh S, Tudu P, Gaine T, Bakshi M, Das S, Das P, Bhattacharyya S, Bandyopadhyay S, Chaudhuri P. Synergistic approach towards the sustainable management of heavy metals in wastewater using mycosynthesized iron oxide nanoparticles: Biofabrication, adsorptive dynamics and chemometric modeling study. J Water Process Eng. 2020;37:101426. https://doi.org/10.1016/j.jwpe.2020.101426.10.1016/j.jwpe.2020.101426 ↗
71. Mahmoud AED, Al-Qahtani KM, Alflaij SO, Al-Qahtani SF, Alsamhan FA. Green copper oxide nanoparticles for lead, nickel, and cadmium removal from contaminated water. Sci Rep. 2021;11(1):12547. https://doi.org/10.1038/s41598-021-91093-7.10.1038/s41598-021-91093-7 ↗
72. Mahmoud AM, Ibrahim FA, Shaban SA, Youssef NA. Adsorption of heavy metal ion from aqueous solution by nickel oxide nano catalyst prepared by different methods. Egyptian J Petroleum. 2015;24(1):27–35. https://doi.org/10.1016/j.ejpe.2015.02.003.10.1016/j.ejpe.2015.02.003 ↗
73. Mahmoud ME, Ibrahim GAA, Abdelwahab MS. Manganese dioxide nanoparticles decorated with chitosan for effective removal of lead and lanthanum ions from water by microwave sorption technique. Mater Sci Engineering: B. 2021;267:115091. https://doi.org/10.1016/j.mseb.2021.115091.10.1016/j.mseb.2021.115091 ↗
74. Mahmoud ME, Saleh MM, Zaki MM, Nabil GM. A sustainable nanocomposite for removal of heavy metals from water based on crosslinked sodium alginate with iron oxide waste material from steel industry. J Environ Chem Eng. 2020;8(4):104015. https://doi.org/10.1016/j.jece.2020.104015.10.1016/j.jece.2020.104015 ↗
75. Mangalampalli B, Dumala N, Grover P. RETRACTED: Acute oral toxicity study of magnesium oxide nanoparticles and microparticles in female albino Wistar rats. Regul Toxicol Pharmacol. 2017;90:170–84. https://doi.org/10.1016/j.yrtph.2017.09.005.10.1016/j.yrtph.2017.09.005 ↗
76. Mashentseva AA, Seitzhapar N, Barsbay M, Aimanova NA, Alimkhanova AN, Zheltov DA, Zhumabayev AM, Temirgaziev BS, Almanov AA, Sadyrbekov DT. Adsorption isotherms and kinetics for Pb(ii) ion removal from aqueous solutions with biogenic metal oxide nanoparticles. RSC Adv. 2023;13(38):26839–50. https://doi.org/10.1039/d3ra05347d.10.1039/d3ra05347d ↗
77. Miri A, Najafzadeh H, Darroudi M, Miri J. Iron Oxide Nanoparticles: Biosynthesis, Magnetic Behavior, Cytotoxic Effect. ChemistryOpen. 2021;327–333. https://doi.org/10.1002/open.202000186.10.1002/open.202000186 ↗
78. Moradi O, Zare K. Adsorption of Pb(II), Cd(II) and Cu(II) Ions in Aqueous Solution on SWCNTs and SWCNT -COOH Surfaces: Kinetics Studies. Fullerenes Nanotubes Carbon Nanostruct. 2011;19(7):628–52. https://doi.org/10.1080/1536383X.2010.504955.10.1080/1536383X.2010.504955 ↗
79. Mostafa D, Shehata N, Alqahtani MD, Jumah B, Alotaibi MN, Alenazi NM, Rudayni NA, Allam HA, Zoubi AAA, W., Abukhadra MR. Steric and energetic studies on adsorption of toxic arsenic ions by hematite nano-rods from laterite highlighting the impact of modification periods. Sci Rep. 2025;15(1):16429. https://doi.org/10.1038/s41598-025-94802-8.10.1038/s41598-025-94802-8 ↗
80. Mu SR, Lorena N, Ponce C, Lichtfouse E. Metal, Metal-Oxides and Metal-Organic Frameworks for Environmental Remediation. Environmental Chemistry for a Sustainable World; 2021. https://www.springerprofessional.de/en/metal-metal-oxides-and-metal-organic-frameworks-for-environmenta/19136814
81. Muataz AA, Fettouhi M, Mammum AA, Yahya N. Lead removal by using carbon nanotubes. Int J Nanopart. 2009;2(6):329. https://doi.org/10.1504/IJNP.2009.028767.10.1504/IJNP.2009.028767 ↗
82. Mubarak NM, Sahu JN, Abdullah EC, Jayakumar NS. Rapid adsorption of toxic Pb(II) ions from aqueous solution using multiwall carbon nanotubes synthesized by microwave chemical vapor deposition technique. J Environ Sci. 2016;45:143–55. https://doi.org/10.1016/j.jes.2015.12.025.10.1016/j.jes.2015.12.025 ↗
83. Mudassar H, Hina K, Ghani U, Afzaal Q, Shah AA, Shaffique S, Elansary HO. Adsorptive removal of Pb2 + from wastewater using ZnO-Biochar nanocomposite. Sci Rep. 2025;15(1):29517. https://doi.org/10.1038/s41598-025-13228-4.10.1038/s41598-025-13228-4 ↗
84. Muñoz J, Gallego M, Valcárcel M. Speciation of Organometallic Compounds in Environmetal Samples by Gas Chromatography after Flow Preconcentration on Fullerenes and Nanotubes. Anal Chem. 2005;77(16):5389–95. https://doi.org/10.1021/ac050600m.10.1021/ac050600m ↗
85. Nitodas SF, Karachalios TK. Low-cost production and applications of high purity carbon nanotubes. Int J Nanomanuf. 2010;6(1–4):111–24. https://doi.org/10.1504/IJNM.2010.034777.10.1504/IJNM.2010.034777 ↗
86. Nwoke SU, Ekere NR, Abugu H, Odum PU, Ezike CC, Ihedioha JN, Eze SI. Potential Toxic Elements (PTEs) and the Health Risk Impact of Some Dairy Products Marketed in Nigeria. Eurasian J Anal Chem. 2021;16(2):1–9.
87. Nwoke SU, Ucheana IA, Divine C, Obi RG, Oluwasola HO, Ezeofor CC, Akpomie KG. Sequestration of aqueous-bound cadmium ions using ZnO nanoparticles synthesized from Ocimum gratissimum leaf extract: kinetics, isotherm, and thermodynamics studies. Int J Phytoremediation. 2025;1–15. https://doi.org/10.1080/15226514.2025.2577147.10.1080/15226514.2025.2577147 ↗
88. Odum PU, Ekere NR, Abugu HO, Ihedioha JN, Nwoke SU, Ezike CC, Eze SI. Potential toxic elements load and their health risk assessment in vegetables grown in nsukka area of South-Eastern Nigeria. Toxicol Int. 2021;28(2):103–14. https://doi.org/10.18311/ti/2021/v28i2/26074.10.18311/ti/2021/v28i2/26074 ↗
89. Olaleye AM, Nwoke SU, Okongwu DJ, Amaraegbulam N, Ezeh CC, Ucheana IA. Evaluation and health risk analysis of potential toxic elements in select foods vended within a university campus in southeastern Nigeria. J Trace Elem Minerals. 2025;12(4):100247. https://doi.org/10.1016/j.jtemin.2025.100247.10.1016/j.jtemin.2025.100247 ↗
90. Orsi M, Al Hatem C, Leinardi R, Huaux F. (2020). Carbon Nanotubes under Scrutiny: Their Toxicity and Utility in Mesothelioma Research. In Applied Sciences (Vol. 10, Issue 13, p. 4513). https://doi.org/10.3390/app10134513.10.3390/app10134513 ↗
91. Prosposito P, Burratti L, Venditti I. Silver Nanoparticles as Colorimetric Sensors for Water Pollutants. Chemosensors. 2020;8(2):26. https://doi.org/10.3390/chemosensors8020026.10.3390/chemosensors8020026 ↗
92. Pyrzynska K. (2023). Recent Applications of Carbon Nanotubes for Separation and Enrichment of Lead Ions. In Separations (Vol. 10, Issue 3, p. 152). https://doi.org/10.3390/separations10030152.10.3390/separations10030152 ↗
93. Qumar U, Hassan JZ, Bhatti RA, Raza A, Nazir G, Nabgan W, Ikram M. Photocatalysis vs adsorption by metal oxide nanoparticles. J Mater Sci Technol. 2022;131:122–66. https://doi.org/10.1016/j.jmst.2022.05.020.10.1016/j.jmst.2022.05.020 ↗
94. Rahimi S, Moattari RM, Rajabi L, Derakhshan AA, Keyhani M. Iron oxide/hydroxide (α,γ-FeOOH) nanoparticles as high potential adsorbents for lead removal from polluted aquatic media. J Ind Eng Chem. 2015;23:33–43. https://doi.org/10.1016/j.jiec.2014.07.039.10.1016/j.jiec.2014.07.039 ↗
95. Rahmani A, Mousavi HZ, Fazli M. Effect of nanostructure alumina on adsorption of heavy metals. Desalination. 2010;253(1):94–100. https://doi.org/10.1016/j.desal.2009.11.027.10.1016/j.desal.2009.11.027 ↗
96. Rajput S, Pittman CU, Mohan D. Magnetic magnetite (Fe3O4) nanoparticle synthesis and applications for lead (Pb2+) and chromium (Cr6+) removal from water. J Colloid Interface Sci. 2016;468:334–46. https://doi.org/10.1016/j.jcis.2015.12.008.10.1016/j.jcis.2015.12.008 ↗
97. Rao GP, Lu C, Su F. Sorption of divalent metal ions from aqueous solution by carbon nanotubes: A review. Sep Purif Technol. 2007;58(1):224–31. https://doi.org/10.1016/j.seppur.2006.12.006.10.1016/j.seppur.2006.12.006 ↗
98. Rasoulzadeh H, Dehghani MH, Mohammadi AS, Karri RR, Nabizadeh R, Nazmara S, Kim K-H, Sahu JN. Parametric modelling of Pb(II) adsorption onto chitosan-coated Fe3O4 particles through RSM and DE hybrid evolutionary optimization framework. J Mol Liq. 2020;297:111893. https://doi.org/10.1016/j.molliq.2019.111893.10.1016/j.molliq.2019.111893 ↗
99. Rehman M, Rehman W, Waseem M, Hussain S, Haq S, Rehman MA. Adsorption mechanism of Pb2 + ions by Fe3O4, SnO2, and TiO2 nanoparticles. Environ Sci Pollut Res. 2019;26(19):19968–81. https://doi.org/10.1007/s11356-019-05276-x.10.1007/s11356-019-05276-x ↗
100. Ren X, Shao D, Zhao G, Sheng G, Hu J, Yang S, Wang X. Plasma Induced Multiwalled Carbon Nanotube Grafted with 2-Vinylpyridine for Preconcentration of Pb(II) from Aqueous Solutions. Plasma Processes Polym. 2011;8(7):589–98. https://doi.org/10.1002/ppap.201000192.10.1002/ppap.201000192 ↗