journal article·2025-09-01

Influence of tin doping and annealing on structural and optical properties of nickel oxide thin films prepared via spray pyrolysis

Institute of Technology, Middle Technical University, Baghdad, Iraq, G. D. Salman, K. I. Hassoon, Department of Laser Science and Technology, College of Applied Sciences,University of Technology, Baghdad, Iraq, M. A. Hassan, Department of Medical and Industrial Materials Science, College of Applied Sciences,University of Technology, Baghdad, Iraq

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Abstract

Nickel oxide (NiO) is a p-type semiconductor with applications in optoelectronics, such as solar cells and photo detectors. This study explores the effects of Sn doping and annealing on NiO thin films, prepared using a cost-effective spray pyrolysis method. Doping concentrations of 3%, 6%, and 9% Sn were tested, and annealing at 500°C improved structural properties. XRD confirmed crystallinity, and the bandgap increased with doping, enhancing electronic properties. Urbach energy values indicated improved optoelectronic potential, contributing insights for optimizing NiO-based devices, particularly in solar cell applications. The findings emphasize NiO's viability for advanced optoelectronic technologies.
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