Effect of iron doping on PbTiO3 perovskites to enhance material properties for technological applications
Source abstract
Abstract
Iron-doped titanate (PbTi₁₋ₓFeₓO₃) was successfully synthesized using the sol-gel autocombustion method, with varying iron concentrations (x = 0.00, 0.02, 0.04, 0.06, 0.08, and 0.1). Elemental composition was determined by EDS, morphology was analyzed using SEM, and ferroelectric properties were evaluated through the P-E loop and PUND methods. EDS confirmed the successful incorporation of Fe into the structure. SEM images showed a reduction in the particle size of PbTiO₃, from 100 nm to 20 nm, suggesting that the presence of Fe ions contributed to the decrease in particle size. Ferroelectric analysis indicated a reduction in polarization, enhanced coercivity, and minimal leakage current at an iron concentration of x = 0.02, making it suitable for energy storage applications.
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Research context
OpenAlex topics: Ferroelectric and Piezoelectric Materials · Multiferroics and related materials · Microwave Dielectric Ceramics Synthesis
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References (44)
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1. [1] Slimani, Y., Shirsath, S. E., Erdemi, H., Meena, S. S., Batoo, K. M., Almessiere, M. A., Shariq, M. (2024), Ceramics International, 50(13), 22583-22598; https://doi.org/10.1016/j.ceramint.2024.03.36010.1016/j.ceramint.2024.03.360 ↗
2. [2] Slimani, Y., Almessiere, M. A., Shirsath, S. E., Hannachi, E., Baykal, A., Alwadai, N., Ercan, I. (2023), Inorganic Chemistry Communications, 153, 110753; https://doi.org/10.1016/j.inoche.2023.11075310.1016/j.inoche.2023.110753 ↗
3. [3] Das, S. K., Mishra, R. N., Roul, B. K. (2014), Solid state communications, 191, 19-24; https://doi.org/10.1016/j.ssc.2014.04.00110.1016/j.ssc.2014.04.001 ↗
4. [4] Craciun, F., Cordero, F., Cernea, M., Fruth, V., Atkinson, I., Stanica, N., Galassi, C. (2019), Ceramics International, 45(7), 9390-9396; https://doi.org/10.1016/j.ceramint.2018.08.14710.1016/j.ceramint.2018.08.147 ↗
5. [5] Pilch, M., Molak, A. (2014), Journal of alloys and compounds, 586, 488-498; https://doi.org/10.1016/j.jallcom.2013.10.10310.1016/j.jallcom.2013.10.103 ↗
6. [6]Lin, F., Li, Z., Sun, B., Peng, W., Cao, Z., Gao, K., Ren, F. (2024), Materials Today Advances, 22, 100506; https://doi.org/10.1016/j.mtadv.2024.10050610.1016/j.mtadv.2024.100506 ↗
7. [7]Zheng, T., Deng, H., Zhou, W., Zhai, X., Cao, H., Yu, L., Chu, J. (2016), Ceramics International, 42(5), 6033-6038; https://doi.org/10.1016/j.ceramint.2015.12.15710.1016/j.ceramint.2015.12.157 ↗
8. [8]Nayak, A., Patri, S. K.,Behera, B. (2024), Materials Science and Engineering: B, 309, 117633; https://doi.org/10.1016/j.mseb.2024.11763310.1016/j.mseb.2024.117633 ↗
9. [9] Wang, L., Yuan, P., Wang, F., Liang, E., Sun, Q., Guo, Z., Jia, Y. (2014), Materials Research Bulletin, 49, 509-513; https://doi.org/10.1016/j.materresbull.2013.08.07510.1016/j.materresbull.2013.08.075 ↗
10. [10] Gumiel, C., Calatayud, D. G. (2022), Boletín de la Sociedad Española de Cerámica y Vidrio, 61(6), 708-732; https://doi.org/10.1016/j.bsecv.2021.08.00210.1016/j.bsecv.2021.08.002 ↗
11. [11]Varignon, J., Bristowe, N. C., Bousquet, E., Ghosez, P. (2020), Physical Sciences Reviews, 5(2), 20190069; https://doi.org/10.1515/psr-2019-006910.1515/psr-2019-0069 ↗
12. [12]Ramesh, R., Spaldin, N. A. (2007), Nature materials, 6(1), 21-29; https://doi.org/10.1038/nmat180510.1038/nmat1805 ↗
13. [13] Liao, J., Dai, S., Peng, R. C., Yang, J., Zeng, B., Liao, M., Zhou, Y. (2023), Fundamental Research, 3(3), 332-345; https://doi.org/10.1016/j.fmre.2023.02.01010.1016/j.fmre.2023.02.010 ↗
14. [14] Kumar, M., Shankar, S., Kumar, A., Anshul, A., Jayasimhadri, M., Thakur, O. P. (2020), Journal of Materials Science: Materials in Electronics, 31, 19487-19510; https://doi.org/10.1007/s10854-020-04574-210.1007/s10854-020-04574-2 ↗
15. [15]Gupta, R., Kotnala, R. K. (2022), Journal of Materials Science, 57(27), 12710-12737; https://doi.org/10.1007/s10853-022-07377-4 79110.1007/s10853-022-07377-4 ↗
16. [16] Gautam, C., Madheshiya, A. (2020), Journal of Materials Science: Materials in Electronics, 31(15), 12004-12025; https://doi.org/10.1007/s10854-020-03831-810.1007/s10854-020-03831-8 ↗
17. [17]Xiong, J., Wang, Z., Yang, X., Long, X., He, C. (2021), IEEE Transactions on Ultrasonics, Ferroelectrics, and Frequency Control, 68(8), 2775-2780; https://doi.org/10.1109/TUFFC.2021.307940110.1109/TUFFC.2021.3079401 ↗
18. [18] Nougaret, L., Kassa, H. G., Cai, R., Patois, T., Nysten, B., van Breemen, A. J., Jonas, A. M. (2014), ACS nano, 8(4), 3498-3505; https://doi.org/10.1021/nn406503g10.1021/nn406503g ↗
19. [19] Mitra, R., Prusty, A., Manju, U. (2023), Perovskite Metal Oxides (pp. 617-643). Elsevier; https://doi.org/10.1016/B978-0-323-99529-0.00022-910.1016/B978-0-323-99529-0.00022-9 ↗
20. [20] Guo, J., Chen, W., Chen, H., Zhao, Y., Dong, F., Liu, W., Zhang, Y. (2021), Advanced Optical Materials, 9(23), 2002146; https://doi.org/10.1002/adom.20200214610.1002/adom.202002146 ↗
21. [21] Shi, P. P., Tang, Y. Y., Li, P. F., Liao, W. Q., Wang, Z. X., Ye, Q.,Xiong, R. G. (2016), Chemical Society Reviews, 45(14), 3811-3827; https://doi.org/10.1039/C5CS00308C10.1039/C5CS00308C ↗
22. [22] Muhammad, Z., Ishafaq, M. U. U., Zhang, X., Ullah, S., Adam, M. L., Moses, O. A., Zhao, W. (2023) Journal of Alloys and Compounds, 956, 170337; https://doi.org/10.1016/j.jallcom.2023.17033710.1016/j.jallcom.2023.170337 ↗
23. [23] Ivanov, S. A., Stash, A. I., Riekehr, L., Chen, Y. S., Ye, Z. G. (2020), Scientific Reports, 10(1), 14567; https://doi.org/10.1038/s41598-020-71438-410.1038/s41598-020-71438-4 ↗
24. [24]Bormanis, K., Kalvane, A., Burkhanov, A. I., Serezhkin, A. M. (2011), Lithuanian Journal of Physics, 51(4); https://doi.org/10.3952/lithjphys.5141610.3952/lithjphys.51416 ↗
25. [25] Evans, D. M., Alexe, M., Schilling, A., Kumar, A., Sanchez, D., Ortega, N., Gregg, J. M. (2015), The nature of magnetoelectric coupling in Pb (Zr, Ti) O3Pb (Fe, ta) O3; https://doi.org/10.1002/adma.20150174910.1002/adma.201501749 ↗
26. [26]Muhammad, Z., Ishafaq, M. U. U., Zhang, X., Ullah, S., Adam, M. L., Moses, O. A., Zhao, W. (2023), Journal of Alloys and Compounds, 956, 170337; https://doi.org/10.1016/j.jallcom.2023.17033710.1016/j.jallcom.2023.170337 ↗
27. [27]Turjo, R. M. (2014). Structure-property relationship of Ba2+ and Ti4+ doped multiferroic bismuth ferrite.
28. [28] Ganegoda, H., Mukherjee, S., Ma, B., Olive, D. T., McNeely, J. H., Kaduk, J. A., Segre, C. U. (2021), The Journal of Physical Chemistry C, 125(22), 12342-12354; https://doi.org/10.1021/acs.jpcc.1c0229710.1021/acs.jpcc.1c02297 ↗
29. [29] Muhammad, Z., Ishafaq, M. U. U., Zhang, X., Ullah, S., Adam, M. L., Moses, O. A., Zhao, W. (2023), Journal of Alloys and Compounds, 956, 170337; https://doi.org/10.1016/j.jallcom.2023.17033710.1016/j.jallcom.2023.170337 ↗
30. [30]Sakout, Y., El Ghadraoui, O., Lahrar, E. H., Zouhairi, M., Tijani, N., Harrach, A., El Yamni, K. (2024), Journal of Electronic Materials, 53(1), 141-156; https://doi.org/10.1007/s11664-023-10741-y10.1007/s11664-023-10741-y ↗
31. [31]Nayak, A., Patri, S. K., Behera, B. (2024), Materials Science and Engineering: B, 309, 117633; https://doi.org/10.1016/j.mseb.2024.11763310.1016/j.mseb.2024.117633 ↗
32. [32] M. S. Hasan, M. I. Khan, S. Kanwal, M. I. Irfan, Tahani, I. Al-Muhimeed, S. Mumtaz. (2022), Digest Journal of Nanomaterials and Biostructures. 17(4), 1527-1533; https://doi.org/10.15251/DJNB.2022.174.152710.15251/DJNB.2022.174.1527 ↗
33. [33] Murtaza, G., Ahmad, R., Rashid, M. S., Hassan, M., Hussnain, A., Khan, M. A., Riaz, S. (2014), Current Applied Physics, 14(2), 176-181; https://doi.org/10.1016/j.cap.2013.11.00210.1016/j.cap.2013.11.002 ↗
34. [34] Redhu, P., Punia, R., Hooda, A., Malik, B. P., Sharma, G., & Sharma, P. (2020), Ceramics International, 46(11), 17495-17507; https://doi.org/10.1016/j.ceramint.2020.04.04510.1016/j.ceramint.2020.04.045 ↗
35. [35] Keswani, B. C., Devan, R. S., Kambale, R. C., James, A. R., Manandhar, S., Kolekar, Y. D., & Ramana, C. V. (2017), Journal of Alloys and Compounds, 712, 320-333; https://doi.org/10.1016/j.jallcom.2017.03.301 79210.1016/j.jallcom.2017.03.301 ↗
36. [36]Nayak, A., Patri, S. K., & Behera, B. (2024), Materials Science and Engineering: B, 309, 117633; https://doi.org/10.1016/j.mseb.2024.11763310.1016/j.mseb.2024.117633 ↗
37. [37]Ullah, M. B., Ahamed, J. U., Rubel, R. R., Rahman, M. A., Hasan, Z., Alam, M. K., Khan, M. N. I. (2024), Ceramics International, 50(6), 9604-9616; https://doi.org/10.1016/j.ceramint.2023.12.27910.1016/j.ceramint.2023.12.279 ↗
38. [38] Keswani, B. C., Devan, R. S., Kambale, R. C., James, A. R., Manandhar, S., Kolekar, Y. D., Ramana, C. V. (2017), Journal of Alloys and Compounds, 712, 320-333; https://doi.org/10.1016/j.jallcom.2017.03.30110.1016/j.jallcom.2017.03.301 ↗
39. [39] Sharma, P., Berwal, N., Ahlawat, N., Maan, A. S., Punia, R. (2019), Ceramics International, 45(16), 20368-20378; https://doi.org/10.1016/j.ceramint.2019.07.01310.1016/j.ceramint.2019.07.013 ↗
40. [40] Li, C. X., Yang, B., Zhang, S. T., Zhang, R., Sun, Y., Wang, J. J., Cao, W. W. (2013), Ceramics International, 39(8), 8701-8708; https://doi.org/10.1016/j.ceramint.2013.04.05210.1016/j.ceramint.2013.04.052 ↗
41. [41]Chaudhuri, A. R., Krupanidhi, S. B. (2010), Solid state communications, 150(13-14), 660- 662; https://doi.org/10.1016/j.ssc.2009.12.02310.1016/j.ssc.2009.12.023 ↗
42. [42] http://www.ferrodevices.com/applicationnotes.html
43. [43] Mahmoud, A. E. R., & Parashar, S. K. S. (2019), Materials Science and Engineering: B, 246, 13-20; https://doi.org/10.1016/j.mseb.2019.05.02210.1016/j.mseb.2019.05.022 ↗
44. [44]Dawber, M., Rabe, K. M., & Scott, J. F. (2005), Reviews of modern physics, 77(4), 1083- 1130; https://doi.org/10.1103/RevModPhys.77.108310.1103/RevModPhys.77.1083 ↗