Novel Approach for Alternating Current (AC)‐Driven Organic Light‐Emitting Devices

Abstract A novel approach for alternating current (AC)‐driven organic light‐emitting devices is reported, which uses the concept of molecular doping in organic semiconductors. Doped organic charge‐transport layers are used to generate charge carriers within the device, hence eliminating the need for injecting charge carriers from external electrodes. Bright luminance of up to 1000 cd m⁻² is observed when the device is driven with an AC bias. The luminance observed is attributed to charge‐carrier generation and recombination, leading to the formation of excitons within the device, without injection of charge carriers through external electrodes. A mechanism for internal charge‐carrier generation and the device operation is proposed.