Light‐Induced Virtual Electrodes for Microfluidic Droplet Electro‐Coalescence

Abstract Electro‐coalescence is the fusion phenomenon between a pair or more microfluidic droplets that are immersed in an immiscible medium under an electric field. This technique is frequently used to merge confined droplets in surfactant‐stabilized microfluidic emulsions using local electric fields. Despite the necessity of miniaturized electrodes, this method has proven highly successful in microfluidics and lab‐on‐a‐chip applications. Miniaturized electrodes severely curtail the spatial and temporal flexibility of the electric potential, thus hindering real‐time and flexible operation and leading to high production costs. The current study addresses this problem with reconfigurable electric field potential by light‐driven functional virtual electrodes. These electrodes are light‐induced on a non‐centrosymmetric ferroelectric photovoltaic crystal placed below a microfluidic droplet channel. The photovoltaic effect in the crystal is responsible for the space charge distributions that act as virtual electrodes, whose evanescent field is screened by free charges into the two liquids inside the channel. A numerical model is developed to describe the evolution of the evanescent electric field causing electro‐coalescence. Based on this prediction, two coalescence processes occur at two different timescales and with different numbers of droplets involved. Controlled exposure time modulation allows either rapid on‐demand coalescence of droplet pairs or breakup of the entire emulsion.