journal article·2024-12

Effect of bromine on the formation of δ-CsPbI3 in Cs0.22FA0.78Pb(I1-xBrx)3 perovskite solar cells

Muntae Hwang, Il-Wook Cho, Jaewon Oh, Hyunbok Lee, Mee-Yi Ryu

Publisher page

Abstract

Applying Cs xFA 1-xPbI 3 perovskite is a useful strategy for synthesizing high-efficiency organic-inorganic lead halide perovskite solar cells because it improves the stability of the perovskite structure. High concentration of cesium (Cs) in CsFAPbI 3 synthesized under ambient conditions typically lead to phase separation due to δ-CsPbI 3 formation and moisture, thereby reducing light absorption and increasing non-radiative recombination. To counter this, we fabricated the mixed halide Cs 0.22FA 0.78Pb(I 1-xBr x) 3 perovskite films. Introducing bromine (Br) content effectively reduced the δ-CsPbI 3 formation and grain boundaries, thus suppressing the non-radiative recombination between perovskite and charge transport layers. Employing this approach, our perovskite solar cells with a 10 % Br concentration achieved a power conversion efficiency of 15.81 %. This demonstrates the potential of Br incorporation in enhancing the stability and efficiency of perovskite solar cells.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Perovskite Materials and Applications · Solid-state spectroscopy and crystallography · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (32)

Show source-provided references
1. Halide perovskite light‐emitting diode technologies10.1002/adom.202002128 ↗
2. Review on efficiency improvement effort of perovskite solar cell10.1016/j.solener.2022.01.060 ↗
3. TiO2 thin film deposition by RF reactive sputtering for n-i-p planar structured perovskite solar cells10.5757/ASCT.2022.31.5.116 ↗
4. Enhancement of light-harvesting ability on perovskite films via preheated substrates10.5757/ASCT.2023.32.5.110 ↗
5. Enhancement in device performance of perovskite solar cells via annealing of PCBM electron transport layer10.5757/ASCT.2022.31.6.167 ↗
6. Guanidinium cation substitution effects on perovskite solar cells10.5757/ASCT.2022.31.6.161 ↗
7. Controlled growth of perovskite layers with volatile alkylammonium chlorides10.1038/s41586-023-05825-y ↗
8. Humidity‐induced degradation via grain boundaries of HC(NH2)2PbI3 planar perovskite solar cells10.1002/adfm.201705363 ↗
9. Understanding degradation mechanisms and improving stability of perovskite photovoltaics10.1021/acs.chemrev.8b00336 ↗
10. Controlled humidity study on the formation of higher efficiency formamidinium lead triiodide-based solar cells10.1021/acs.chemmater.5b01691 ↗
11. Organic cation‐dependent degradation mechanism of organotin halide perovskites10.1002/adfm.201505127 ↗
12. Fabrication of efficient formamidinium perovskite solar cells under ambient air via intermediate-modulated crystallization10.1016/j.solener.2019.05.033 ↗
13. Formamidinium and cesium hybridization for photo- and moisture-stable perovskite solar cell10.1002/aenm.201501310 ↗
14. Air-processed mixed-cation Cs0.15FA0.85PbI3 planar perovskite solar cells derived from a PbI2–CsI–FAI intermediate complex10.1039/C8TA01049H ↗
15. Entropic stabilization of mixed A-cation ABX3 metal halide perovskites for high performance perovskite solar cells10.1039/C5EE03255E ↗
16. Insights into operational stability and processing of halide perovskite active layers10.1039/C8EE03051K ↗
17. Impact of cesium concentration on optoelectronic properties of metal halide perovskites10.3390/ma15051936 ↗
18. Effect of δ-CsPbI3 phase separation in CsxFA1−xPbI3 under ambient conditions10.5757/ASCT.2024.33.1.23 ↗
19. Humidity resistant fabrication of CH3NH3PbI3 perovskite solar cells and modules10.1016/j.nanoen.2017.06.039 ↗
20. Exploring the formation of formamidinium-based hybrid perovskites by antisolvent methods: in situ GIWAXS measurements during spin coating10.1039/C9SE00306A ↗
21. Manipulating the mixed‐perovskite crystallization pathway unveiled by in situ GIWAXS10.1002/adma.201901284 ↗
22. Unraveling the impact of bromine incorporation on the hybrid perovskite film phase evolution mechanism by in situ characterization
23. How lead halide complex chemistry dictates the composition of mixed halide perovskites10.1021/acs.jpclett.6b00433 ↗
24. Effect of antisolvent application rate on film formation and photovoltaic performance of methylammonium‐free perovskite solar cells, Advanced Energy and sustainability research10.1002/aesr.202100061 ↗
25. Rethinking the role of excess/residual lead iodide in perovskite solar cells
26. Revealing phase evolution mechanism for stabilizing formamidinium-based lead halide perovskites by a key intermediate phase10.1016/j.chempr.2021.07.011 ↗
27. High-efficiency perovskite solar cells10.1021/acs.chemrev.0c00107 ↗
28. Effects of HAT-CN layer thickness on molecular orientation and energy-level alignment with ZnPc10.3390/molecules28093821 ↗
29. Electromodulation and transient absorption spectroscopy suggest conduction band electron lifetime, electron trapping parameters, and CH3NH3PbI3 solar cell fill factor are correlated10.1021/acs.jpcc.9b02748 ↗
30. Bromine incorporation and suppressed cation rotation in mixed-halide perovskites10.1021/acsnano.0c05179 ↗
31. A victim of halide ion segregation. How light soaking affects solar cell performance of mixed halide lead perovskites10.1021/acsenergylett.7b00589 ↗
32. A comparison of charge carrier dynamics in organic and perovskite solar cells