journal article·2022-06

Electrochemical Thin‐Film Transistors using Covalent Organic Framework Channel

Mrinal K. Hota, Suman Chandra, Yongjiu Lei, Xiangming Xu, Mohamed N. Hedhili, Abdul‐Hamid Emwas, Osama Shekhah, Mohamed Eddaoudi, Husam N. Alshareef

Advanced Functional Materials· Volume 32· Issue 23
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Abstract

Abstract Covalent organic framework (COF) thin films have been successfully prepared and utilized as a channel material in electrical double‐layer (EDL) electrochemical transistors. 4,4′‐azodianiline (Azo) and 1,3,5‐triformylphloroglucinol(Tp) precursors are introduced to prepare azo (NN) functionalized ß‐keto‐enamine COF (Tp‐Azo) thin films. The EDL transistor exhibits a switching ratio of 103 times, a low threshold voltage of 0.6 V, and a field‐effect mobility of 0.53 cm2 V−1 s−1. The dynamic behavior of the transistor under different input signals shows responses, which are very similar to the biological synaptic behavior, indicating that the COF devices can be used as artificial synapses. This report opens a new direction in covalent–organic framework development in iontronic applications.
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Research context

OpenAlex topics: Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Materials Science and Engineering King Abdullah University of Science and Technology (KAUST) Thuwal 23955‐6900 Saudi Arabia

Physical Science and Engineering Division Advanced Membranes and Porous Materials Center King Abdullah University of Science and Technology (KAUST) Thuwal 23955‐6900 Saudi Arabia

Technische Universität Berlin Straße des 17. Juni 135 10623 Berlin Germany

Core Labs King Abdullah University of Science & Technology (KAUST) Thuwal 23955‐6900 Saudi Arabia

Funding

King Abdullah University of Science and Technology

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