journal article·2022-01-24Open access

Review on Y6-Based Semiconductor Materials and Their Future Development via Machine Learning

Sijing Zhong, Boon Kar Yap, Zhiming Zhong, Lei Ying

Crystals· Volume 12· Issue 2

Abstract

Non-fullerene acceptors are promising to achieve high efficiency in organic solar cells (OSCs). Y6-based acceptors, one group of new n-type semiconductors, have triggered tremendous attention when they reported a power-conversion efficiency (PCE) of 15.7% in 2019. After that, scientists are trying to improve the efficiency in different aspects including choosing new donors, tuning Y6 structures, and device engineering. In this review, we first summarize the properties of Y6 materials and the seven critical methods modifying the Y6 structure to improve the PCEs developed in the latest three years as well as the basic principles and parameters of OSCs. Finally, the authors would share perspectives on possibilities, necessities, challenges, and potential applications for designing multifunctional organic device with desired performances via machine learning.
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Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Machine Learning in Materials Science

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou 510640, China

Institute of Sustainable Energy, Universiti Tenaga Nasional, Jalan Ikram-Uniten, Kajang 43000, Malaysia

Electronics and Communication Department, College of Engineering, Universiti Tenaga Nasional, Jalan Ikram-Uniten, Kajang 43000, Malaysia

South China Institute of Collaborative Innovation, Dongguan 523808, China

Funding

Program for Science and Technology Development of Dongguan · Dongguan Innovative Research Team Program · Uniten bold grant · Natural Science Foundation of China · China Postdoctoral Science Foundation · Science and Technology Program of Guangdong · Guangdong Provincial Training Program of Innovation and Entrepreneurship for Undergraduates

References (100+)

Show source-provided references
1. The sun’s total and spectral irradiance for solar energy applications and solar radiation models10.1016/j.solener.2003.08.039 ↗
2. Thin-film CdS/CdTe solar cell with 15.8% efficiency10.1063/1.109629 ↗
3. Photovoltaic materials, history, status and outlook10.1016/S0927-796X(02)00092-X ↗
4. Heat-Insulating Multifunctional Semitransparent Polymer Solar Cells10.1016/j.joule.2018.06.006 ↗
5. Spectral Engineering of Semitransparent Polymer Solar Cells for Greenhouse Applications10.1002/aenm.201803438 ↗
6. Evaporation-Free Nonfullerene Flexible Organic Solar Cell Modules Manufactured by An All-Solution Process10.1002/aenm.201902065 ↗
7. Single-Component Non-halogen Solvent-Processed High-Performance Organic Solar Cell Module with Efficiency over 14%10.1016/j.joule.2020.07.028 ↗
8. Bulk heterojunction solar cells with internal quantum efficiency approaching 100%10.1038/nphoton.2009.69 ↗
9. Photoinduced electron transfer from a conducting polymer to buckminsterfullerene10.1126/science.258.5087.1474 ↗
10. Device Physics of Polymer:Fullerene Bulk Heterojunction Solar Cells10.1002/adma.200601093 ↗
11. Polymer-Fullerene Bulk-Heterojunction Solar Cells10.1002/adma.200801283 ↗
12. Photoinduced Degradation of Polymer and Polymer-Fullerene Active Layers: Experiment and Theory10.1002/adfm.201001079 ↗
13. A polymer tandem solar cell with 10.6% power conversion efficiency10.1038/ncomms2411 ↗
14. What Makes Fullerene Acceptors Special as Electron Acceptors in Organic Solar Cells and How to Replace Them10.1002/adma.201203486 ↗
15. Efficient organic solar cells processed from hydrocarbon solvents10.1038/nenergy.2015.27 ↗
16. A High-Mobility Electron-Transport Polymer with Broad Absorption and Its Use in Field-Effect Transistors and All-Polymer Solar Cells10.1021/ja071760d ↗
17. Next-generation organic photovoltaics based on non-fullerene acceptors10.1038/s41566-018-0104-9 ↗
18. Stability of Polymer Solar Cells10.1002/adma.201104187 ↗
19. An Electron Acceptor Challenging Fullerenes for Efficient Polymer Solar Cells10.1002/adma.201404317 ↗
20. Single-Junction Organic Solar Cell with over 15% Efficiency Using Fused-Ring Acceptor with Electron-Deficient Core10.1016/j.joule.2019.01.004 ↗
21. Over 16% efficiency organic photovoltaic cells enabled by a chlorinated acceptor with increased open-circuit voltages10.1038/s41467-019-10351-5 ↗
22. Non-fullerene acceptors with branched side chains and improved molecular packing to exceed 18% efficiency in organic solar cells10.1038/s41560-021-00820-x ↗
23. Delocalization of exciton and electron wavefunction in non-fullerene acceptor molecules enables efficient organic solar cells10.1038/s41467-020-17867-1 ↗
24. High-Performance Semi-Transparent Organic Photovoltaic Devices via Improving Absorbing Selectivity10.1002/aenm.202003408 ↗
25. Wide Bandgap Polymer with Narrow Photon Harvesting in Visible Light Range Enables Efficient Semitransparent Organic Photovoltaics10.1002/adfm.202107934 ↗
26. Flexible-spacer incorporated polymer donors enable superior blend miscibility for high-performance and mechanically-robust polymer solar cells10.1039/D1EE01062J ↗
27. Progress in Upscaling Organic Photovoltaic Devices10.1002/aenm.202100342 ↗
28. Material Strategies to Accelerate OPV Technology Toward a GW Technology10.1002/aenm.202001864 ↗
29. Organic photovoltaic cells with high efficiencies for both indoor and outdoor applications10.1039/D0QM00633E ↗
30. Interfacial Materials for Organic Solar Cells: Recent Advances and Perspectives10.1002/advs.201500362 ↗
31. Tyagi, H., Chakraborty, P.R., Powar, S., and Agarwal, A.K. (2020). Interfacial Materials for Organic Solar Cells. Solar Energy: Systems, Challenges, and Opportunities, Springer.10.1007/978-981-15-0675-8 ↗
32. Fused-Thiophene Based Materials for Organic Photovoltaics and Dye-Sensitized Solar Cells10.3390/polym6102645 ↗
33. 25th Anniversary Article: Bulk Heterojunction Solar Cells: Understanding the Mechanism of Operation10.1002/adma.201304373 ↗
34. Fill factor in organic solar cells10.1016/j.solmat.2008.06.001 ↗
35. Computer-Aided Screening of Conjugated Polymers for Organic Solar Cell: Classification by Random Forest10.1021/acs.jpclett.8b00635 ↗
36. Analyzing the efficiency, stability and cost potential for fullerene-free organic photovoltaics in one figure of merit10.1039/C8EE00151K ↗
37. Quantifying Losses in Open-Circuit Voltage in Solution-Processable Solar Cells10.1103/PhysRevApplied.4.014020 ↗
38. Recent Progress in Reducing Voltage Loss in Organic Photovoltaic Cells10.1039/D0QM00581A ↗
39. Eco-Compatible Solvent-Processed Organic Photovoltaic Cells with Over 16% Efficiency10.1002/adma.201903441 ↗
40. Achieving over 16% efficiency for single-junction organic solar cells10.1007/s11426-019-9457-5 ↗
41. A High-Efficiency Organic Solar Cell Enabled by the Strong Intramolecular Electron Push–Pull Effect of the Nonfullerene Acceptor10.1002/adma.201707170 ↗
42. Fused Benzothiadiazole: A Building Block for n-Type Organic Acceptor to Achieve High-Performance Organic Solar Cells10.1002/adma.201807577 ↗
43. Enabling low voltage losses and high photocurrent in fullerene-free organic photovoltaics10.1038/s41467-019-08386-9 ↗
44. Narrowing the Band Gap: The Key to High-Performance Organic Photovoltaics10.1021/acs.accounts.0c00157 ↗
45. Thieno[3,2-b]pyrrolo-Fused Pentacyclic Benzotriazole-Based Acceptor for Efficient Organic Photovoltaics10.1021/acsami.7b10995 ↗
46. Thieno[3,2-b]pyrrolo Donor Fused with Benzothiadiazolo, Benzoselenadiazolo and Quinoxalino Acceptors: Synthesis, Characterization, and Molecular Properties10.1021/ol202199v ↗
47. Recent progress in thick-film organic photovoltaic devices: Materials, devices, and processing10.1002/sus2.10 ↗
48. Low Band-Gap Conjugated Polymers with Strong Interchain Aggregation and Very High Hole Mobility Towards Highly Efficient Thick-Film Polymer Solar Cells10.1002/adma.201305092 ↗
49. “Conformation Locked” Strong Electron-Deficient Poly(p-Phenylene Vinylene) Derivatives for Ambient-Stable n-Type Field-Effect Transistors: Synthesis, Properties, and Effects of Fluorine Substitution Position10.1021/ja412533d ↗
50. Organic and Polymeric Semiconductors Enhanced by Noncovalent Conformational Locks10.1021/acs.chemrev.7b00084 ↗
51. PBDB-T and its derivatives: A family of polymer donors enables over 17% efficiency in organic photovoltaics10.1016/j.mattod.2019.10.023 ↗
52. Rational Tuning of Molecular Interaction and Energy Level Alignment Enables High-Performance Organic Photovoltaics10.1002/adma.201904215 ↗
53. Fused-Ring Electron Acceptors for Photovoltaics and Beyond10.1021/acs.accounts.0c00575 ↗
54. Over 17% Efficiency of Ternary Organic Photovoltaics Employing Two Acceptors with an Acceptor–Donor–Acceptor Configuration10.1021/acsami.1c15896 ↗
55. Enhanced power-conversion efficiency in polymer solar cells using an inverted device structure10.1038/nphoton.2012.190 ↗
56. Comparison of conventional and inverted structures in fullerene-free organic solar cells10.1016/j.jechem.2015.10.002 ↗
57. Tailoring Regioisomeric Structures of π-Conjugated Polymers Containing Monofluorinated π-Bridges for Highly Efficient Polymer Solar Cells10.1021/acsenergylett.0c00939 ↗
58. Improving open-circuit voltage by a chlorinated polymer donor endows binary organic solar cells efficiencies over 17%10.1007/s11426-019-9669-3 ↗
59. 18% Efficiency organic solar cells10.1016/j.scib.2020.01.001 ↗
60. 16.67% Rigid and 14.06% Flexible Organic Solar Cells Enabled by Ternary Heterojunction Strategy10.1002/adma.201902210 ↗
61. Improved Charge Transport and Reduced Nonradiative Energy Loss Enable Over 16% Efficiency in Ternary Polymer Solar Cells10.1002/adma.201902302 ↗
62. Ternary Blended Fullerene-Free Polymer Solar Cells with 16.5% Efficiency Enabled with a Higher-LUMO-Level Acceptor to Improve Film Morphology10.1002/aenm.201901728 ↗
63. Wang, X., Sun, Q., Gao, J., Wang, J., Xu, C., Ma, X., and Zhang, F. (2021). Recent Progress of Organic Photovoltaics with Efficiency over 17%. Energies, 14.10.3390/en14144200 ↗
64. Xu, W., Ma, X., Son, J.H., Jeong, S.Y., Niu, L., Xu, C., Zhang, S., Zhou, Z., Gao, J., and Woo, H.Y. (2021). Smart Ternary Strategy in Promoting the Performance of Polymer Solar Cells Based on Bulk-Heterojunction or Layer-By-Layer Structure. Small, 2104215.10.1002/smll.202104215 ↗
65. A-DA′D-A-Type Non-fullerene Acceptors Containing a Fused Heptacyclic Ring for Poly(3-hexylthiophene)-Based Polymer Solar Cells10.1021/acs.jpcc.0c07162 ↗
66. Molecular design of a non-fullerene acceptor enables a P3HT-based organic solar cell with 9.46% efficiency10.1039/D0EE01763A ↗
67. Selenium Heterocyclic Electron Acceptor with Small Urbach Energy for As-Cast High-Performance Organic Solar Cells10.1021/jacs.0c08557 ↗
68. Design and synthesis of non-fullerene acceptors based on a quinoxalineimide moiety as the central building block for organic solar cells10.1039/D0CC00896F ↗
69. Large-Area Organic Solar Cells: Material Requirements, Modular Designs, and Printing Methods10.1002/adma.201805089 ↗
70. Over 14% Efficiency in Organic Solar Cells Enabled by Chlorinated Nonfullerene Small-Molecule Acceptors10.1002/adma.201800613 ↗
71. Fluorination vs. chlorination: A case study on high performance organic photovoltaic materials10.1007/s11426-018-9260-2 ↗
72. Efficient organic solar cells based on a new “Y-series” non-fullerene acceptor with an asymmetric electron-deficient-core10.1039/C9CC10076H ↗
73. Asymmetric Acceptors Enabling Organic Solar Cells to Achieve an over 17% Efficiency: Conformation Effects on Regulating Molecular Properties and Suppressing Nonradiative Energy Loss10.1002/aenm.202003177 ↗
74. Asymmetric Isomer Effects in Benzo[c][1,2,5]thiadiazole-Fused Nonacyclic Acceptors: Dielectric Constant and Molecular Crystallinity Control for Significant Photovoltaic Performance Enhancement10.1002/adfm.202104369 ↗
75. Fine-tuning of side-chain orientations on nonfullerene acceptors enables organic solar cells with 17.7% efficiency10.1039/D0EE03506H ↗
76. An intermediate neglect of differential overlap technique for spectroscopy: Pyrrole and the azines10.1007/BF00528484 ↗
77. Near infrared electron acceptors with a photoresponse beyond 1000 nm for highly efficient organic solar cells10.1039/D0TA06907H ↗
78. Vinylene π-bridge: A simple building block for ultra-narrow bandgap nonfullerene acceptors enable 14.2% efficiency in binary organic solar cells10.1016/j.dyepig.2021.109171 ↗
79. Alkyl Chain Tuning of Small Molecule Acceptors for Efficient Organic Solar Cells10.1016/j.joule.2019.09.010 ↗
80. Organic photovoltaic cell with 17% efficiency and superior processability10.1093/nsr/nwz200 ↗
81. Polymer Photovoltaic Cells: Enhanced Efficiencies via a Network of Internal Donor-Acceptor Heterojunctions10.1126/science.270.5243.1789 ↗
82. Efficient photodiodes from interpenetrating polymer networks10.1038/376498a0 ↗
83. Polymer Blend Solar Cells Based on a High-Mobility Naphthalenediimide-Based Polymer Acceptor: Device Physics, Photophysics and Morphology10.1002/aenm.201000035 ↗
84. All-Polymer Solar Cells Based on a Conjugated Polymer Containing Siloxane-Functionalized Side Chains with Efficiency over 10%10.1002/adma.201703906 ↗
85. 14.4% efficiency all-polymer solar cell with broad absorption and low energy loss enabled by a novel polymer acceptor10.1016/j.nanoen.2020.104718 ↗
86. Controlling Molecular Mass of Low-Band-Gap Polymer Acceptors for High-Performance All-Polymer Solar Cells10.1016/j.joule.2020.03.019 ↗
87. Fluorinated End Group Enables High-Performance All-Polymer Solar Cells with Near-Infrared Absorption and Enhanced Device Efficiency over 14%10.1002/aenm.202003171 ↗
88. A Universal Fluorinated Polymer Acceptor Enables All-Polymer Solar Cells with >15% Efficiency10.1021/acsenergylett.0c02053 ↗
89. Regio-Regular Polymer Acceptors Enabled by Determined Fluorination on End Groups for All-Polymer Solar Cells with 15.2% Efficiency10.1002/ange.202016284 ↗
90. A Difluoro-Monobromo End Group Enables High-Performance Polymer Acceptor and Efficient All-Polymer Solar Cells Processable with Green Solvent under Ambient Condition10.1002/adfm.202100791 ↗
91. Achieving over 17% efficiency of ternary all-polymer solar cells with two well-compatible polymer acceptors10.1016/j.joule.2021.04.007 ↗
92. Machine learning for molecular and materials science10.1038/s41586-018-0337-2 ↗
93. Rectification, space-charge-limited current, photovoltaic and photoconductive properties of Al/tetracene/Au sandwich cell10.1063/1.1662650 ↗
94. Machine learning-assisted molecular design and efficiency prediction for high-performance organic photovoltaic materials10.1126/sciadv.aay4275 ↗
95. The Harvard Clean Energy Project: Large-Scale Computational Screening and Design of Organic Photovoltaics on the World Community Grid10.1021/jz200866s ↗
96. Learning from the Harvard Clean Energy Project: The Use of Neural Networks to Accelerate Materials Discovery10.1002/adfm.201501919 ↗
97. The Harvard organic photovoltaic dataset10.1038/sdata.2016.86 ↗
98. Toward Predicting Efficiency of Organic Solar Cells via Machine Learning and Improved Descriptors10.1002/aenm.201801032 ↗
99. Machine learning-based screening of complex molecules for polymer solar cells10.1063/1.5023563 ↗
100. Combining electronic and structural features in machine learning models to predict organic solar cells properties10.1039/C8MH01135D ↗