journal article·2006-06-01

Crystal Growth and Single-Crystal Structures of RERhO3 (RE = La, Pr, Nd, Sm, Eu, Tb) Orthorhodites from a K2CO3 Flux

René B. Macquart, Mark D. Smith, Hans-Conrad zur Loye

Crystal Growth & Design· Volume 6· Issue 6
Publisher page

Abstract

Single crystals of LaRhO 3, PrRhO 3, NdRhO 3, SmRhO 3, EuRhO 3, and TbRhO 3 have been grown for the first time using a K 2 CO 3 flux. All the compounds were found to crystallize in the orthorhombic space group Pbnm (No. 62) and adopt the GdFeO 3 distorted perovskite structure type. Transition toward a pseudo-cubic cell is noted as the rare earth cation size increases.
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Research context

OpenAlex topics: Advanced Condensed Matter Physics · Magnetic and transport properties of perovskites and related materials · Crystal Structures and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina 29208

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