journal article·2009-02-04

Correlation between Morphology and Defect Luminescence in Precipitated ZnO Nanorod Powders

Marko Bitenc, Peter Podbršček, Zorica Crnjak Orel, Michael A. Cleveland, J. Antonio Paramo, Raul M. Peters, Yuri M. Strzhemechny

Crystal Growth & Design· Volume 9· Issue 2
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Abstract

ZnO nanorods were prepared at relatively low temperatures by homogeneous precipitation from zinc nitrate and urea in a water/ethylene glycol mixture. Crystal size and morphology are controlled by growth time and solvent composition. We observed a strong correlation between nanocrystals’ size/morphology and their optoelectronic defect-related properties. Smaller crystallites exhibited intense deep-defect luminescence and enhanced emission related to near-surface excitonic recombination. Longer growth times lead to formation of well-defined nanorods with hexagonal symmetry exhibiting reduced defect emission.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: ZnO doping and properties · Copper-based nanomaterials and applications · Ga2O3 and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

National Institute of Chemistry, 1000 Ljubljana, Slovenia, Physics Department, Austin College, Sherman, Texas 75090-4400, and Department of Physics and Astronomy, Texas Christian University, Fort Worth, Texas 76129

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