journal article·2017-12-06Open access

Effect of Growth Temperature on the Structural and Morphological Properties of MgCdO Thin Films Grown by Metal Organic Chemical Vapor Deposition

Lluís M. Guia, Vincent Sallet, Said Hassani, M. Carmen Martínez-Tomás, Vicente Muñoz-Sanjosé

Crystal Growth & Design· Volume 17· Issue 12

Abstract

II–VI oxides ternary alloys have attracted considerable interest of the scientific community due to the possibility of modulating their interesting optoelectronic properties. Despite this interest, MgCdO has been poorly studied. In this work, by using the metal organic chemical vapor deposition method at low pressure, we have analyzed the synthesis of thin films of this alloy. Thus, for a fixed metal–organic precursors content, a change from Mg 1– x Cd x O (Mg-rich phase) to Cd 1– x Mg x O (Cd-rich phase) has been induced when decreasing the growth temperature. The temperature range where both phases coexist has been particularly analyzed. Using X-ray diffraction analysis and scanning electron microscopy, a structural and morphological study of the samples has been carried out. In addition, the composition of the alloy has been measured by using energy dispersive X-ray analysis, and the behavior of the lattice parameter as a function of Cd content has been studied.
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Research context

OpenAlex topics: ZnO doping and properties · Copper-based nanomaterials and applications · Semiconductor materials and devices

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Affiliations

Departamento de Física Aplicada i Electromagnetisme, Universitat de València, Burjassot, Spain

Groupe d’Étude de la Matière Concensée, CNRS-Université de Versailles St. Quentin en Yvelines, Université Paris-Saclay, Versailles, France

Funding

Generalitat Valenciana · Ministerio de Econom?a y Competitividad · Ministerio de Educaci?n, Cultura y Deporte

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