journal article·2019-09Open access

Perovskite Photovoltaic Devices: Enhancing the Open‐Circuit Voltage of Perovskite Solar Cells by up to 120 mV Using π‐Extended Phosphoniumfluorene Electrolytes as Hole Blocking Layers (Adv. Energy Mater. 33/2019)

Qingzhi An, Qing Sun, Andreas Weu, David Becker‐Koch, Fabian Paulus, Sebastian Arndt, Fabian Stuck, A. Stephen K. Hashmi, Nir Tessler, Yana Vaynzof

Advanced Energy Materials· Volume 9· Issue 33

Abstract

In article number 1901257, Yana Vaynzof and co-workers introduce π-extended phosphoniumfluorene electrolytes as hole-blocking layers in planar perovskite solar cells. The electrolytes drastically alter the energetic landscape of the device, introducing a strong dipole between the fullerene electron extraction layer and the silver electrode. This results in a substantial enhancement in the built-in potential of the device, increasing its open-circuit voltage by up to 120 meV.
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Research context

OpenAlex topics: Perovskite Materials and Applications · Conducting polymers and applications

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Affiliations

Kirchhoff Institute for Physics Im Neuenheimer Feld 227 Heidelberg University 69120 Heidelberg Germany

Centre for Advanced Materials Im Neuenheimer Feld 225 Heidelberg University 69120 Heidelberg Germany

Institute for Organic Chemistry Im Neuenheimer Feld 270 Heidelberg University 69120 Heidelberg Germany

Chemistry Department Faculty of Science King Abdulaziz University (KAU) 21589 Jeddah Saudi Arabia

Sara and Moshe Zisapel Nano‐Electronic Center Department of Electrical Engineering Technion‐Israel Institute of Technology Haifa 32000 Israel

References

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