Open‐Cage Fullerenes as n‐Type Materials in Organic Photovoltaics: Relevance of Frontier Energy Levels, Carrier Mobility and Morphology of Different Sizable Open‐Cage Fullerenes with Power Conversion Efficiency in Devices
Source abstract
Abstract
Organic bulk heterojunction (OBHJ) photovoltaics, incorporating open-cage fullerenes with orifice-size of 8, 12, 13, 16 and 20-membered-rings as n-type materials, display power conversion efficiency (PCE) up to 2.9% by the 8-membered-ring fullerene under AM 1.5G irradiation; their PCEs decrease as the orifice-size of open-cage fullerene increases, primarily due to electron-mobility descends as the cage is ruptured to larger holes.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Fullerene Chemistry and Applications · Organic Electronics and Photovoltaics · Carbon Nanotubes in Composites
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (58)
Show source-provided references
1. 10.1039/B913168J10.1039/B913168J ↗
2. 10.1039/b823001c10.1039/b823001c ↗
3. 10.1016/j.solmat.2008.12.01210.1016/j.solmat.2008.12.012 ↗
4. 10.1016/j.solmat.2008.12.01310.1016/j.solmat.2008.12.013 ↗
5. Diederich F. · Chimia · 1998 · 52 · 55110.2533/chimia.1998.551 ↗
6. 10.1039/a804248i10.1039/a804248i ↗
7. 10.1002/352760349210.1002/3527603492 ↗
8. 10.1021/cr050537110.1021/cr0505371 ↗
9. 10.1021/jo00108a01210.1021/jo00108a012 ↗
10. 10.1126/science.258.5087.147410.1126/science.258.5087.1474 ↗
11. 10.1126/science.270.5243.178910.1126/science.270.5243.1789 ↗
12. 10.1063/1.134583410.1063/1.1345834 ↗
13. 10.1002/1616-3028(200102)11:1<15::AID-ADFM15>3.0.CO;2-A10.1002/1616-3028(200102)11:1<15::AID-ADFM15>3.0.CO;2-A ↗
14. 10.1002/1521-4095(20021203)14:23<1735::AID-ADMA1735>3.0.CO;2-O10.1002/1521-4095(20021203)14:23<1735::AID-ADMA1735>3.0.CO;2-O ↗
15. 10.1063/1.152124410.1063/1.1521244 ↗
16. 10.1002/anie.20035164710.1002/anie.200351647 ↗
17. 10.1002/adfm.20039001110.1002/adfm.200390011 ↗
18. Zhang F. L. · Synth. Met. · 2003 · 137
19. 10.1039/b402661f10.1039/b402661f ↗
20. 10.1038/nmat150010.1038/nmat1500 ↗
21. 10.1126/science.114171110.1126/science.1141711 ↗
22. 10.1039/c0cc01087a10.1039/c0cc01087a ↗
23. 10.1038/nphoton.2009.6910.1038/nphoton.2009.69 ↗
24. 10.1038/nphoton.2009.19210.1038/nphoton.2009.192 ↗
25. 10.1002/adma.20050171710.1002/adma.200501717 ↗
26. 10.1063/1.239700310.1063/1.2397003 ↗
27. 10.1021/jp048890i10.1021/jp048890i ↗
28. 10.1021/cm070893v10.1021/cm070893v ↗
29. 10.1021/ol062666p10.1021/ol062666p ↗
30. 10.1021/ja710621j10.1021/ja710621j ↗
31. 10.1002/adfm.20080118910.1002/adfm.200801189 ↗
32. 10.1021/cm052783z10.1021/cm052783z ↗
33. 10.1039/b904485j10.1039/b904485j ↗
34. 10.1021/ja807627u10.1021/ja807627u ↗
35. 10.1021/ja101780s10.1021/ja101780s ↗
36. 10.1002/adma.20100133910.1002/adma.201001339 ↗
37. 10.1002/adma.20070243810.1002/adma.200702438 ↗
38. 10.1002/adfm.20090045910.1002/adfm.200900459 ↗
39. 10.1038/nmat237910.1038/nmat2379 ↗
40. 10.1002/adfm.20100180710.1002/adfm.201001807 ↗
41. D. W.Laird R.Stegamat H.Richter V.Vejins L.Scott T. A.Lada Patent WO 2008/018931 A2.
42. 10.1021/ja981387x10.1021/ja981387x ↗
43. 10.1016/j.solmat.2004.09.00210.1016/j.solmat.2004.09.002 ↗
44. 10.1002/adfm.20030515610.1002/adfm.200305156 ↗
45. 10.1002/adfm.20050042010.1002/adfm.200500420 ↗
46. 10.1039/c0cc04246c10.1039/c0cc04246c ↗
47. Compound8aand8beach encapsulates a water molecule inside the cage in 79% and 54% ratio by1H NMR analyses in which encapsulated H2O appear at –11.28 and –11.34 ppm respectively.
48. Compound5a b 6a b 7a band8a bare isolated as isomeric mixtures since they are difficult to be separated by flash column chromatography in low polarity solvents (toluene/hexanes = 1:1). Later we find that their solubilities are even lower upon separated from their isomeric mixtures with Buckyprep column by HPLC; mixtures of separated isomers/P3HT do not form better films as isomeric mixtures in devices.
49. 10.1002/chem.20039018410.1002/chem.200390184 ↗
50. Iwamatsu S.‐I. · Chem. Commun. · 2003 · 1269
51. 10.1021/ja038537a10.1021/ja038537a ↗
52. 10.1002/adma.20090370510.1002/adma.200903705 ↗
53. 10.1039/C0CP01178A10.1039/C0CP01178A ↗
54. 10.1002/anie.20035164710.1002/anie.200351647 ↗
55. 10.1021/ja801877k10.1021/ja801877k ↗
56. 10.1021/cm900779810.1021/cm9007798 ↗
57. 10.1021/ma100015710.1021/ma1000157 ↗
58. 10.1002/adma.20070151910.1002/adma.200701519 ↗