Aluminum‐Based Chalcopyrite Thin Films and Solar Cells

Abstract Aluminum‐based chalcopyrite materials have attracted attention because of the wide controllability range of their material properties and potential for use in energy‐conversion devices. Herein, CuAlSe₂‐based thin‐film growth and solar cell device properties are discussed. Ternary CuAlSe₂ thin films are relatively unstable and decompose weeks after film growth, even when preserved in a dry box. However, alloying with elemental In led to significant improvements in stability. Cu(In,Al)Se₂ (CIAS) solar cells yield better photovoltaic performance than CuInSe₂ cells, although the effective range of Al concentration that can improve device performance is narrower than that of elemental Ga in Cu(In,Ga)Se₂ (CIGS). A decrease in the alkali metal concentration in CIAS films with increasing Al concentration is observed, indicating that the formation energy of alkali‐metal substitutional defects on the Cu site is high, and/or Al‐related complex defects formed are kinetically stable and difficult to replace with alkali metals once they form. Although the direct observation of alkali metals in the bulk (grain interior) of chalcopyrite CuInSe₂ and CIGS films has been difficult to date, this result can serve as indirect evidence of the presence of alkali metals in the bulk of CuInSe₂ films.