Lifetime of Organic Salt Photovoltaics

Abstract Solar energy deployment can be augmented with the use of wavelength‐selective transparent photovoltaics (PVs). Moving forward, operating lifetime is arguably among the most important challenge that must be addressed to increase commercial viability of these emerging technologies. In this work, the lifetimes of PVs with organic near‐infrared selective small molecules and molecular salts are investigated. This is the first comprehensive lifetime study on devices featuring organic salts with varied counterions. Based on the tunability afforded by anion exchange, an extrapolated lifetime of 7 ± 2 years from continuous illumination measurements on organic salt devices held at the maximum power point is demonstrated. These lifetimes are compared with changes in external quantum efficiency, hydrophobicity, molecular orbital levels, and optical absorption to determine the limiting characteristics and failure mechanisms of PV devices utilizing each donor. A key correlation between the lifetime and the hydrophobicity of the donor layer is uncovered. This could provide a targeted parameter for designing organic molecules and salts with exceptional lifetime and enhanced commercial viability.