DataVXAdvanced Energy MaterialsPaper
journal article·2018-09Open access

Tetrathienoanthracene and Tetrathienylbenzene Derivatives as Hole‐Transporting Materials for Perovskite Solar Cell

Diana Elizabeth Meza Rojas, Kyung Taek Cho, Yi Zhang, Maxence Urbani, Nouar Tabet, Gema de la Torre, Mohammad Khaja Nazeeruddin, Tomás Torres

Advanced Energy Materials· Volume 8· Issue 25
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Source abstract

Abstract

Abstract The synthesis and characterization of two related families of star‐shaped thiophene‐containing hole‐transporting materials (HTMs) based on fused tetrathienoanthracene and nonfused tetrathienylbenzene cores are reported. All of them are endowed with four terminal (4,4′‐dimethoxy)diphenylamino groups that are either linked directly to the core or showed a different type of bridges (i.e., thiophene‐phenyl or phenyl rings). The novel HTMs are tested in mixed‐ion perovskite (Cs0.1FA0.74MA0.13PbI2.48Br0.39) solar cells, and power conversion efficiencies of up to 18.8% are measured under 1 sun irradiation, comparable with the efficiency obtained for the reference cell using 2,2′,7,7′‐tetrakis(N,N′‐di‐p‐methoxyphenylamine)‐9,9′‐spirobifluorene as an HTM.
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Research context

Electronic materials

OpenAlex topics: Perovskite Materials and Applications · Conducting polymers and applications · Organic Light-Emitting Diodes Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Departamento de Química Orgánica Universidad Autónoma de Madrid Cantoblanco 28049 Madrid Spain

Group for Molecular Engineering of Functional Materials Institute of Chemical Sciences and Engineering EPFL, Valais Wallis, Rue de l'Industrie 17 1950 Sion Switzerland

IMDEA‐Nanociencia Campus de Cantoblanco 28049 Madrid Spain

Qatar Environment and Energy Research Institute Hamad Bin Khalifa University (HBKU) Qatar Foundation Doha 5825 Qatar

Institute for Advanced Research in Chemical Sciences (IAdChem) Universidad Autónoma de Madrid 28049 Madrid Spain

Funding

Ministerio de Economía y Competitividad · Comunidad de Madrid · Horizon 2020 · Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

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