Antimony (V) Complex Halides: Lead‐Free Perovskite‐Like Materials for Hybrid Solar Cells
Source abstract
Abstract
Abstract Using bromoantimonate (V) (N‐EtPy)[SbBr6] as an example, it is demonstrated that ABX6 compounds can form perovskite‐like 3D crystalline frameworks with short interhalide contacts, enabling advanced optoelectronic characteristics of these materials. The designed compound shows an impressive performance in planar junction solar cells delivering external quantum efficiency of ≈80% and power conversion efficiency of ≈4%, thus being comparable with the conventional perovskite material MAPbBr3. The discovery of the first perovskite‐like compound ABX6 exhibiting good photovoltaic performance opens wide opportunities for rational design of novel perovskite‐like semiconductor materials for advanced electronic and photovoltaic applications.
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Research context
OpenAlex topics: Perovskite Materials and Applications · Solid-state spectroscopy and crystallography · Conducting polymers and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Nikolaev Institute of Inorganic Chemistry SB RAS Lavrentieva St. 3 Novosibirsk 630090 Russia
Faculty of Natural Sciences Novosibirsk State University Pirogova St. 2 Novosibirsk 630090 Russia
Skolkovo Institute of Science and Technology Center for Electrochemical Energy Storage Nobel St. 3 Moscow 143026 Russia
Institute for Problems of Chemical Physics RAS Acad. Semenov St. 1 Chernogolovka 142432 Russia
Funding
Russian Foundation for Basic Research
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