A Highly Efficient Nonenzymatic Hydrogen Peroxide Electrochemical Sensor Using Mesoporous Carbon Doped ZnO Nanocomposite
Source abstract
Abstract
Carbon nanomaterial coupled with inorganic semiconductor based metal oxide is a facile route to develop effective electrochemical sensors. Herein, an electrochemical investigation was carried out for selective and sensitive detection of hydrogen peroxide (H2O2) using 5% mesoporous carbon doped ZnO (Meso-C/ZnO) nanocomposite modified glassy carbon electrode (GCE). The ZnO nanomaterial was synthesized by a F127 structural template agent in a modified sol-gel procedure. Then, a simple ultra-sonication technique was employed to synthesize Meso-C/ZnO nanocomposite. XRD, TEM, FTIR, Raman, and XPS techniques were successfully applied to characterize the as-fabricated nanocomposite. CV and EIS measurements were used to evaluate the electrocatalytic activity of the modified electrode compared to pure ZnO modified GCE and unmodified GCE. The sensing efficiency of the active modified electrode was examined with square wave voltammetry (SWV) technique and the sensor exhibits excellent performance towards the detection of H2O2 in a wide linear concentration range (from 50 μM to 981 μM), with high sensitivity (0.04648 μMμA−1 cm−2), and low limit of detection (6.25 μM). Additionally, the selectivity test using several common interfering species demonstrated excellent anti-interfering ability. Furthermore, the fabricated electrode showed excellent reproducibility and operational stability as well as suitability for the real sample analysis. Thus, this new sensor is considered as very auspicious candidate in several fields of science and industry.
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Research context
OpenAlex topics: Electrochemical sensors and biosensors · Electrochemical Analysis and Applications · Analytical Chemistry and Sensors
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (85)
Show source-provided references
1. Highly sensitive graphene–Pt nanocomposites amperometric biosensor and its application in living cell H2O2 detection10.1021/ac5009699 ↗
2. Recent advances in electrochemical sensing for hydrogen peroxide: a review10.1039/C1AN15738H ↗
3. A thin-film direct hydrogen peroxide/borohydride micro fuel cell10.1002/aenm.201200975 ↗
4. PtW/MoS2 hybrid nanocomposite for electrochemical sensing of H2O2 released from living cells10.1016/j.bios.2016.02.019 ↗
5. Active site environment of Heme-Bound Amyloid β Peptide associated with Alzheimer’s disease10.1021/ja1084578 ↗
6. A novel profluorescent probe for detecting oxidative stress induced by metal and H2O2 in living cells10.1039/c000254b ↗
7. H2O2 determination by the I3- Method and by KMnO4 titration10.1021/ac00090a020 ↗
8. Simultaneous HPLC determination of peroxyacetic acid and hydrogen peroxide10.1021/ac9701750 ↗
9. A fast responsive two-photon fluorescent probe for imaging H2O2 in lysosomes with a large turn-on fluorescence signal10.1016/j.bios.2015.12.046 ↗
10. A modified FOX-1 method for Micro-determination of hydrogen peroxide in honey samples10.1016/j.foodchem.2017.05.065 ↗
11. In situ growth of FeOOH nanoparticles on physically-exfoliated graphene nanosheets as high performance H2O2 electrochemical sensor10.1016/j.snb.2020.128038 ↗
12. Sensing based on the motion of enzyme-modified nanorods10.1016/j.bios.2014.05.062 ↗
13. MoS2 nanosheet-Au nanorod hybrids for highly sensitive amperometric detection of H2O2 in living cells10.1039/C6TB02886A ↗
14. Atomic-thick PtNi nanowires assembled on graphene for high-sensitivity extracellular hydrogen peroxide sensors10.1021/acsami.7b11758 ↗
15. Fabrication of hollow CuO/PANI hybrid nanofibers for non-enzymatic electrochemical detection of H2O2 and glucose10.1016/j.snb.2019.02.006 ↗
16. Electrochemical detection of hydrogen peroxide on a new microporous Ni–metal organic framework material-carbon paste electrode10.1016/j.snb.2017.08.002 ↗
17. Non-enzymatic electrochemical hydrogen peroxide detection using MoS2- Interconnected porous carbon heterostructure10.1016/j.jelechem.2018.06.038 ↗
18. Solubilization of carbon nanotubes by Nafion toward the preparation of amperometric biosensors10.1021/ja028951v ↗
19. Electrochemical biosensing platforms using platinum nanoparticles and carbon nanotubes10.1021/ac035143t ↗
20. A novel H2O2 electrochemical sensor based on NiCo2S4 functionalized reduced graphene oxide10.1016/j.jallcom.2019.01.043 ↗
21. Advanced carbon electrode materials for molecular electrochemistry10.1021/cr068076m ↗
22. Silver nanoparticle assemblies supported on glassy-carbon electrodes for the electro-analytical detection of hydrogen peroxide10.1007/s00216-005-3205-5 ↗
23. Novel dendritic palladium nanostructure and its application in biosensing10.1021/jp072898l ↗
24. Electrochemical detection of hydrogen peroxide on platinum-containing tetrahedral amorphous carbon sensors and evaluation of their biofouling properties10.1016/j.msec.2015.05.060 ↗
25. A simple sonochemical assisted synthesis of nanocomposite (ZnO/MWCNTs) for electrochemical sensing of Epinephrine in human serum and pharmaceutical formulation10.1016/j.colsurfa.2019.124038 ↗
26. rGO/ZnO/Nafion nanocomposite as highly sensitive and selective amperometric sensor for detecting nitrite ions (NO2−)10.1016/j.jtice.2020.05.015 ↗
27. Activated carbon -ZnO nanocomposite for electrochemical sensing of acetaminophen10.20964/2016.10.51 ↗
28. TiO2-graphene nanocomposite for electrochemical sensing of adenine and guanine10.1016/j.electacta.2011.02.114 ↗
29. Synthesis of cobalt doped ZnO/reduced graphene oxide nanorods as active material for heavy metal ions sensor and antibacterial activity10.1016/j.jallcom.2017.04.298 ↗
30. Sensing characteristics of nanostructured SnO2 thin films as glucose sensor10.1016/j.egypro.2017.07.056 ↗
31. Redox preparation of mixed-valence cobalt manganese oxide nanostructured materials: highly efficient noble metal-free electrocatalysts for sensing hydrogen peroxide10.1039/C3NR03791F ↗
32. Electrodeposition of TiO2 nanoparticles on multiwalled carbon nanotube arrays for hydrogen peroxide sensing10.1002/elan.200804502 ↗
33. Non-enzymatic hydrogen peroxide electrochemical sensor based on a three-dimensional MnO2 nanosheets/carbon foam composite10.1039/C4RA09007A ↗
34. Fabrication of non-enzymatic sensor using Co doped ZnO nanoparticles as a marker of H2O210.1016/j.physe.2014.04.007 ↗
35. A novel hydrogen peroxide sensor based on Ag/SnO2 composite nanotubes by electrospinning10.1016/j.electacta.2013.03.063 ↗
36. Room temperature electrochemical synthesis of CuO flower-like microspheres and their electrooxidative activity towards hydrogen peroxide10.1007/s00604-011-0663-7 ↗
37. A Fe3O4-based chemical sensor for cathodic determination of hydrogen peroxide10.1002/elan.200503335 ↗
38. Highly electroactive Ce-ZnO/rGO nanocomposite: ultra-sensitive electrochemical sensing platform for carbamazepine determination10.1016/j.jelechem.2018.08.036 ↗
39. Hydrothermal synthesis of zinc oxide-reduced graphene oxide nanocomposites for an electrochemical hydrazine sensor10.1039/C5RA00884K ↗
40. Free-Standing 3D electrodes for electrochemical detection of hydrogen peroxide10.1002/cctc.201900913 ↗
41. A sensitive and selective amperometric hydrazine sensor based on mesoporous Au/ZnO nanocomposites10.1016/j.matdes.2016.07.107 ↗
42. Selenium-functionalized carbon as a support for platinum nanoparticles with improved electrochemical properties for the oxygen reduction reaction and CO tolerance10.1149/2.014306jes ↗
43. Beef-derived mesoporous carbon as highly efficient support for PtRuIr electrocatalysts and their high activity for CO and methanol oxidation
44. A facile synthesis of mesoporous PdZnO nanocomposites as efficient chemical sensor10.1016/j.spmi.2016.04.042 ↗
45. Photoluminescence and Raman scattering in Ag-doped ZnO nanoparticles10.1063/1.3530631 ↗
46. Investigating the possible origin of Raman bands in defective sp2/sp3 carbons below 900 cm−1: phonon density of states or double resonance mechanism at play?10.3390/c5040079 ↗
47. Dual Raman features of double coaxial carbon nanotubes with N-Doped and B-Doped multiwalls10.1021/nl051779j ↗
48. Efficient synthesis of heteroatom (N or S)-doped graphene based on ultrathin graphene oxide-porous silica sheets for oxygen reduction reactions10.1002/adfm.201200186 ↗
49. Synthesis of ZnO/Au and ZnO/Ag nanoparticles and their photocatalytic application using UV and visible light10.1039/C4RA03158J ↗
50. Beneficial role of zinc oxide nanoparticles on green crop production Introduction : Nanotechnology is the term given to those areas of science and
51. FT-IR and FT-Raman spectroscopic analyzes of indeno quinoxaline derivative crystal10.3923/ajaps.2018.83.91 ↗
52. Synthesis and characterization of polypyrrole-zinc oxide core–shell hybrid polymer nanocomposites
53. Synthesis of nitrogen doped mesoporous carbons for carbon dioxide capture10.1039/C5RA05684E ↗
54. Surface transfer p-Type doping of epitaxial graphene10.1021/ja071658g ↗
55. Gold Schottky contacts on oxygen plasma-treated, n-type ZnO(0001̄)10.1063/1.1536264 ↗
56. Blue luminescent centers and microstructural evaluation by XPS and Raman in ZnO thin films annealed in vacuum, N2 and O210.1016/j.physb.2006.05.346 ↗
57. Facile fabrication of heterostructured Bi2O3–ZnO photocatalyst and its enhanced photocatalytic activity10.1021/jp306874z ↗
58. Antioxidant potential and antibacterial efficiency of caffeic acid-functionalized ZnO nanoparticles10.3390/nano7060148 ↗
59. Optical and microstructural properties of ZnO/ TiO2 nanolaminates prepared by atomic layer deposition10.1186/1556-276X-8-107 ↗
60. Ahydrogel biosensor for high selective and sensitive detection of amyloid-beta oligomers10.2147/IJN.S152163 ↗
61. Electrochemistry of ZnO@reduced graphene oxides10.1016/j.carbon.2018.01.018 ↗
62. Development of non-enzymatic and highly selective hydrogen peroxide sensor based on nanoporous gold prepared by a simple unusual electrochemical approach10.1016/j.microc.2017.03.023 ↗
63. Electrospun CuO-ZnO nanohybrid: tuning the nanostructure for improved amperometric detection of hydrogen peroxide as a non-enzymatic sensor10.1016/j.jcis.2019.04.091 ↗
64. Electrochemically reduced graphene oxide-Nafion/Au nanoparticle modified electrode for hydrogen peroxide sensing10.5772/63519 ↗
65. Study of electrochemical reduction of selenium (+4) using square wave voltammetry10.1002/elan.1140020607 ↗
66. Princeton applied research10.1021/ac60366a732 ↗
67. Comparison of voltammetric techniques for ammonia sensing in ionic liquids10.1002/elan.201700555 ↗
68. Electrochemical sensing and biosensing based on square wave voltammetry10.1039/c3ay40155c ↗
69. Fabrication of selective and sensitive chemical sensor development based on flower-flake La2ZnO4 nanocomposite for effective non-enzymatic sensing of hydrogen peroxide by electrochemical method10.1016/j.microc.2020.105536 ↗
70. Potentiometric determination of hydrogen peroxide at MnO2-doped carbon paste electrode10.1016/S0039-9140(99)00223-4 ↗
71. Hydrogen peroxide sensor based on glassy carbon electrode modified with β-manganese dioxide nanorods10.1007/s00604-011-0650-z ↗
72. Enhanced nonenzymatic hydrogen peroxide sensing with reduced graphene oxide/ferroferric oxide nanocomposites10.1016/j.talanta.2011.12.054 ↗
73. Graphene wrapped Cu2O nanocubes: non-enzymatic electrochemical sensors for the detection of glucose and hydrogen peroxide with enhanced stability10.1016/j.bios.2013.02.010 ↗
74. Electrochemical behavior of cuprous oxide-reduced graphene oxide nanocomposites and their application in nonenzymatic hydrogen peroxide sensing10.1016/j.electacta.2012.10.070 ↗
75. A novel nonenzymatic hydrogen peroxide sensor based on MnO2/graphene oxide nanocomposite10.1016/j.talanta.2010.07.020 ↗
76. A non-enzymatic sensor for hydrogen peroxide based on the use of α-Fe2O3 nanoparticles deposited on the surface of NiO nanosheets10.1007/s00604-017-2335-8 ↗
77. Self-assembled Pt screen printed electrodes with a novel peroxidase Panicum maximum and zinc oxide nanoparticles for H2O2 detection10.1016/j.colsurfa.2018.10.051 ↗
78. Counterintuitive sensing mechanism of ZnO nanoparticle based gas sensors10.1016/j.snb.2010.07.009 ↗
79. Hydrogen peroxide reduction in the oxygen vacancies of ZnO nanotubes10.1016/j.tsf.2014.01.084 ↗
80. Carbon-doped ZnO nanostructures: facile synthesis and visible light photocatalytic applications10.1021/acs.jpcc.5b07116 ↗
81. The Hydroxyl radical is a critical intermediate in the voltammetric detection of hydrogen peroxide10.1021/jacs.5b13376 ↗
82. Electrochemical co-preparation of cobalt sulfide/reduced graphene oxide composite for electrocatalytic activity and determination of H 2O 2 in biological samples10.1016/j.jcis.2017.08.087 ↗
83. Hydrogen peroxide electrochemistry on platinum: towards understanding the oxygen reduction reaction mechanism10.1039/c2cp40616k ↗
84. Mechanism of electrochemical reduction of hydrogen peroxide on copper in acidic sulfate solutions10.1021/la7013557 ↗
85. Influence of calcium on glucose biosensor response and on hydrogen peroxide detection10.1016/S0956-5663(97)00084-5 ↗