journal article·2021-09

Enhancement of magnetoresistance and near room-temperature temperature coefficient of resistivity in polycrystalline La0.7Ca0.24Na0.06MnO3 by silver doping

Yunrui Yang, Ling Li, Sheng’an Yang, Fuxin Ling, Yan Gao, Longfei Qi, Dingzhang Wu, Yingjuan Li, Hui Zhang, Qingming Chen

Publisher page

Abstract

We reported the synthesis, characterization, electrical transport, and magnetic properties of polycrystalline La0.7Ca0.24Na0.06MnO3:Agy (LCNMO:Agy) with y = 0.0, 0.1, 0.2, 0.3, and 0.4. The combination of EDS and XPS proved that Ag not only entered the perovskite phase structure but there would also be a small amount of Ag enrichment at the grain boundaries. The magnetoresistance (MR) and temperature coefficient of resistivity (TCR) improved significantly with the addition of Ag as a dopant. At y = 0.2, a multi-functional perovskite material with high TCR (30.57% K−1) near room temperature and large MR (72.28%) at the low magnetic field (1 T) was obtained. This enhancement of MR and TCR near room temperature was attributed to the good connectivity between the grains and the decrease in electron scattering at the grain boundaries. Overall, these findings look promising for future applications in infrared detection bolometers.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Advanced Condensed Matter Physics · Rare-earth and actinide compounds

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (36)

Show source-provided references
1. Daughton JM (1999) GMR applications. J Magn Magn Mater 192:334–34210.1016/S0304-8853(98)00376-X ↗
2. Dagotto E, Hotta T, Moreo A (2001) Colossal magnetoresistant materials: the key role of phase separation. Phys Rep 344:1–15310.1016/S0370-1573(00)00121-6 ↗
3. Smari M, Walha I, Dhahri E, Hlil EK (2013) Structural, magnetic and magnetocaloric properties of Ag-doped La0.5Ca0.5-Ag MnO3 compounds with 0 ≤ x ≤ 0.4. J Alloy Compd 579:564–57110.1016/j.jallcom.2013.07.104 ↗
4. Yang XS, Yang LQ, Lv L, Cheng CH, Zhao Y (2012) Magnetic phase transition in La0.7Sr0.3MnO3/Ta2O5 ceramic composites. Ceram Int 38:2575–257810.1016/j.ceramint.2011.10.014 ↗
5. Haghiri-Gosnet AM, Renard JP (2003) CMR manganites: physics, thin films and devices. J Phys D Appl Phys 36:R127–R15010.1088/0022-3727/36/8/201 ↗
6. Fan J, Xie Y, Zhu Y, Qian F, Ji Y, Hu D, Tong W, Zhang L, Ling L, Wang C, Ma C, Yang H (2019) Emergent phenomena of magnetic skyrmion and large DM interaction in perovskite manganite La0.8Sr0.2MnO3. J Magn Magn Mater 483:42–4710.1016/j.jmmm.2019.03.086 ↗
7. Awana VPS, Tripathi R, Kumar N, Kishan H, Bhalla GL, Zeng R, Chandra LS, Ganesan V, Habermeier HU (2010) Magnetotransport of La0.70Ca0.3−xSrxMnO3(Ag): a potential room temperature bolometer and magnetic sensor. J Appl Phys 107(9):723–725
8. Awana VPS, Tripathi R, Balamurugan S, Kishan H, Takayama-muromachi E (2006) Magnetotransport of high TCR (temperature coefficient of resistance) La2/3Ca1/3MnO3:Ag polycrystalline composites. Solid State Commun 140:410–41510.1016/j.ssc.2006.09.021 ↗
9. Goodenough JB (1955) Theory of the role of covalence in the perovskite-type manganites [La, M (II)] MnO3. Phys Rev 100(2):564–57310.1103/PhysRev.100.564 ↗
10. Kanamori J (1959) Superexchange interaction and symmetry properties of electron orbitals. J Phys Chem Solids 10(2-3):87–9810.1016/0022-3697(59)90061-7 ↗
11. Zener C, Clarence (1951) Interaction between the d-shells in the transition metals. II. FerRomagnetic Compounds Of Manganese With Perovskite Structure. Phys Rev 82(3):403–40510.1103/PhysRev.82.403 ↗
12. Mavani KR, Paulose PL (2005) Effects of cation size disorder and lattice distortion on metamagnetism in phase-separated manganites. Solid State Commun 135(3):183–18810.1016/j.ssc.2005.04.023 ↗
13. Wang ZM, Ni G, Sang H, Du YW (2001) The effect of average A-site cation radius on TC in perovskite manganites. J Magn Magn Mater 234(2):213–21710.1016/S0304-8853(01)00314-6 ↗
14. Singh D, Mahajan A (2015) Effect of A-site cation size on the structural, magnetic, and electrical properties of La1−xNdxMn0.5Cr0.5O3 perovskites. J Appl Phys 644:172–179
15. Ouyang R (2019) Exploiting ionic radii for rational design of halide perovskites. Chem Mater 32:595–60410.1021/acs.chemmater.9b04472 ↗
16. Zhang S, Dong G, Liu Y, Li HJ, Chu KL, Pu XR, Yu XH, Liu X (2020) Effect of Na-doping on structural, electrical, and magnetoresistive properties of La0.7(Ag0.3−xNax)0.3MnO3 polycrystalline ceramics. Ceram Int 46:584–59110.1016/j.ceramint.2019.09.006 ↗
17. Wali M, Skini R, Khlifi M, Bekri M, Dhahri E, Hlil EK (2016) Double metal–insulator transitions and magnetoresistance properties in La0.8Na0.2−xMnO3 oxides. Ceram Int 42:5699–570610.1016/j.ceramint.2015.12.100 ↗
18. Ji FQ, Sun T, Li ZD (2019) Impact of Ag doping on the structural, surface morphologic and electrical properties of La0.625(Ca0.285Sr0.09)MnO3 polycrystalline ceramics. J Alloy Compd 811:152018–15202810.1016/j.jallcom.2019.152018 ↗
19. Huang YH (2003) Enhanced ferromagnetic transition and magnetoresistance in granular Ag-added L0.7Ca0.3MnO3. J Solid State Chem 174:257–26310.1016/S0022-4596(03)00212-3 ↗
20. Lakshmi YK, Reddy PV (2010) Influence of silver doping on the electrical and magnetic behavior of La0.7Ca0.3MnO3 manganites. Solid State Sci 12(10):1731–174010.1016/j.solidstatesciences.2010.07.022 ↗
21. Khiem NV, Phong PT, Dai NV, Chinh HD, Manh DH, Hong LV, Phuc NX (2009) Electrical properties of Ag-La0.7Ca0.3MnO3. Mater Lett 63(11):899–90210.1016/j.matlet.2009.01.058 ↗
22. Sun T, Liu Y, Dong G, Zhang S, Li ZD, Chu KL, Pu XR, Li HJ, Ji FQ, Zhang H, Chen QM (2019) La0.67(Ca0.24Sr0.09)MnO3:xAg2O (0 ≤ x ≤ 0.25) composites with improved room-temperature TCR and MR for advanced uncooling infrared bolometers and magnetic sensors. Appl Surf Sci 493:448–45710.1016/j.apsusc.2019.07.056 ↗
23. Yin XP, Zhan YH, Zhang H, Chen QM (2015) Effect of Ag addition on the magnetic and electrical properties of La0.67Ca0.33MnO3films. Appl Surf Sci 349:983–98710.1016/j.apsusc.2015.04.218 ↗
24. Liu Y, Sun T, Ji FQ, Dong G, Zhang S, Yu XH, Li ZD, Chen QM (2019) Influence of Ag doping on electrical and magnetic properties of La0.67Ca0.33MnO3 polycrystalline ceramics. Ceram Int 45:11006–1101210.1016/j.ceramint.2019.02.184 ↗
25. Li YL, Yang SA, Chen QH, Chen QM (2018) Improved temperature coefficient of resistance in La1−xCaxMnO3:Ag0.2 (0.25 ≤ x ≤ 0.33) ceramics prepared by sol-gel method. J Alloy Compd 800:64–7110.1016/j.jallcom.2019.06.060 ↗
26. Koubaa M, Cheikhrouhou-Koubaa W, Cheikhrouhou A (2009) Effect of Ag doping on structural, magnetic and magnetocaloric properties of La0.65Ca0.35−xAgxMnO3 manganites. J Alloy Compd 473:5–1010.1016/j.jallcom.2008.05.089 ↗
27. Ma J, Theingi M, Zhang H, Ding X, Chen QM (2013) Structural and electrical characterization of La0.72Ca0.28MnO3 ceramic and thin films. Appl Surf Sci 264:225–22810.1016/j.apsusc.2012.09.177 ↗
28. Dong G, Sun T, Liu Y, Zhang S, Liu X (2019) Structural and electrical properties of La0.67(Ca0.3Sr0.03)MnO3 composites prepared with added Ag. J Alloy Compd 794:365–37310.1016/j.jallcom.2019.04.289 ↗
29. Liu Y, Sun T, Dong G, Zhang S, Liu X (2019) Electrical conduction in La0.85Sr0.15MnO3:Agx (0 ≤ x ≤ 0.5) ceramics with large room-temperature TCR. Ceram Int 45:24070–2407710.1016/j.ceramint.2019.08.113 ↗
30. Ferrel-Álvarez ACA, Domínguez-Crespo MAA, Cong HB, Torres-Huerta AMA, Brachetti-Sibaja SBC, De La Cruzd W (2018) Synthesis and surface characterization of the La0.7−XPrXCa0.3MnO3 (LPCM) perovskite by a non-conventional microwave irradiation method. J Alloy Compd 735:1750–175810.1016/j.jallcom.2017.11.306 ↗
31. Yang SA, Ma JA, Zhai YWC, Xu RDA, Zhang HB, Chen QM (2021) La1−xCaxMnO3:Ag0.2 (0.25 ≤ x ≤ 0.31) ceramics with high-temperature coefficient of resistivity under magnetic field. Ceram Int 47:19659–1966710.1016/j.ceramint.2021.03.303 ↗
32. Li HJ, Dong G, Chu KL, Pu XR, Li ZD, Zhang H, Chen QM, Liu X (2021) Utilization of metallic Ag and Ag+ ions to optimize room-temperature TCR and MR of La0.7(Ca0.205Sr0.095)MnO3:xAg2O composites. J Mater Chem C 8:17054–1706410.1039/D0TC03991H ↗
33. Jin F, Zhang H, Chen X, Liu X, Chen QM (2017) Enhancement of temperature coefficient of resistance (TCR) and Magneto-resistance (MR) in La1−x CaxMn03:Ag0.2 polycrystalline composites. J Sol-Gel Sci Technol 82(1):193–20010.1007/s10971-016-4294-7 ↗
34. Peng Z, Wang G, Tang Y, Liu P, Niu X (2010) Enhancement of room-temperature magnetoresistance in La0.5Sm0.2Sr0.3MnO3/(Ag2O) x/2. Rare Met 29:45–4910.1007/s12598-010-0008-4 ↗
35. Sun T, Jiang J, Chen QM (2018) Improvement of room-temperature TCR and MR in polycrystalline La0.67(Ca0.27Sr0.06)MnO3 ceramics by Ag2O doping. Ceram Int 44(8):9865–987410.1016/j.ceramint.2018.02.234 ↗
36. Chu KL, Peng JB, Li HJ, Pu XR, Zhang S, Dong G, Liu Y (2020) Enhanced room-temperature TCR of La0.67Ca0.33−xSrxMnO3 (0.06 ≤ x ≤ 0.11) polycrystalline ceramics by Sr content adjustment. Ceram Int 46(6):7568–757510.1016/j.ceramint.2019.11.256 ↗