journal article·2026-06Open access

Advances and challenges in Copper–Copper bonding for 3D packaging interconnects

Yueting Zheng, Hao Cui, Anyang Yu

Abstract

The semiconductor industry faces both opportunities and challenges in the post-Moore era. As artificial intelligence and high–performance computing advance, conventional 2D interconnects have become a performance bottleneck. Three–dimensional integration has thus emerged as a vital solution. Copper is the preferred interconnect material due to its low resistivity, excellent electromigration resistance, and cost–effectiveness. However, conventional thermocompression bonding requires high temperatures, posing thermal damage risks to sensitive devices. This has spurred the development of low–temperature hybrid bonding, which enables direct Cu–Cu and oxide–oxide connections without micro-bumps, permitting closer chip stacking and denser interconnects. This review outlines advancements in Cu–Cu bonding for 3D packaging. It subsequently presents various techniques–including surface pretreatment (e.g., plasma treatment, Chemical Mechanical Polishing (CMP) Process Optimization), hybrid bonding methods (e.g., surface activated bonding), and microstructure control (e.g., preferential (1 1 1) orientation)—that enhance low-temperature bonding performance. Key challenges and corresponding solutions are examined. Finally, the paper summarizes the critical technologies and processes essential for achieving high–quality, low-temperature hybrid bonding. • A comprehensive analysis is presented on surface pretreatment, microstructural control, and multi-process integration for hybrid bonding. • Emphasis is placed on (1 1 1)-oriented nanotwinned copper,which enables high- strength bonding at low temperatures while enhancing interfacial reliability. • This work provides critical technical support for cutting-edge applications such as HBM and AI chips.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: 3D IC and TSV technologies · Electronic Packaging and Soldering Technologies · Copper Interconnects and Reliability

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (89)

Show source-provided references
1. Current advances and outlooks in hybrid bonding
2. Recent advances and trends in Cu–Cu hybrid bonding10.1109/TCPMT.2023.3265529 ↗
3. Defect localization approach for wafer-to-wafer hybrid bonding interconnects10.1109/TSM.2023.3311452 ↗
4. Development of wafer bonding system for high precision bonding alignment10.1007/s12541-024-01088-3 ↗
5. Research progress of hybrid bonding technology for three-dimensional integration10.1016/j.microrel.2024.115372 ↗
6. Integration solution for thin D2w hybrid bonding for yield and reliability
7. Characterization and benchmarking of the low intertier thermal resistance of three-dimensional hybrid Cu/dielectric wafer-to-wafer bonding10.1115/1.4035597 ↗
8. D2W hybrid bonding system achieving high-accuracy and high-throughput with minimal configurations
9. Annealing effects in sub-8 μm pitch die-to-wafer hybrid bonding
10. Navigating complex process and design challenges in hybrid bonding for advanced semiconductor integration: A comprehensive analysis10.1149/2162-8777/ad7d3b ↗
11. Minimizing recess of Cu pad on hybrid bonding with SiCN via non-selective chemical mechanical polishing and post-cleaning steps10.1149/2162-8777/ad5fb7 ↗
12. State of the art of Cu–Cu hybrid bonding10.1109/TCPMT.2024.3367985 ↗
13. Two-step plasma treatment on copper surface for low-temperature Cu thermo-compression bonding10.1109/TCPMT.2019.2928323 ↗
14. Effect of plasma treatments on the interface chemistry and adhesion strength between Cu metallization and SiCN etch stop layer10.1149/1.2437050 ↗
15. Activation of electroplated-Cu surface via plasma pretreatment for low temperature Cu-Sn bonding in 3D interconnection10.1016/j.apsusc.2016.05.023 ↗
16. Investigation of the SiC surface after nitrogen plasma treatment
17. Effects of two-step plasma treatment on Cu and SiO 2 surfaces for 3D bonding applications
18. In-depth parametric study of Ar or N2 plasma activated Cu surfaces for Cu-Cu direct bonding
19. Two-step Ar/N2 plasma treatment on SiO2 surface for Cu/SiO2 hybrid bonding10.1109/TCPMT.2024.3379117 ↗
20. Low-temperature Cu/SiO2 hybrid bonding based on Ar/H2 plasma and citric acid cooperative activation for multi-functional chip integration10.1016/j.apsusc.2023.159074 ↗
21. Contamination-free Cu/SiCN hybrid bonding process development for sub-μm pitch devices with enhanced bonding characteristics
22. C2H4 reductive plasma treatment on copper surface for copper bonding10.1088/2053-1591/addc3c ↗
23. Surface modification of nanotwinned copper and SiCN using N2 and Ar plasma activation10.1016/j.apsusc.2024.161832 ↗
24. Potassium hydroxide surface modification for low temperature Cu/SiO2 hybrid bonding10.1016/j.surfin.2023.103076 ↗
25. Assessment of the risk of crack formation at a hybrid bonding interface using numerical analysis10.3390/mi15111332 ↗
26. A study on D2W hybrid Cu bonding technology for HBM multi-die stacking
27. CMP: Scaling down and stacking up: How the trends in semiconductors are affecting chemical-mechanical planarization
28. Effects of dishing and annealing temperature on wafer to wafer hybrid bonding
29. Process technology enablers for aggressive scaling of hybrid bonding temperature and pitch
30. Cu-Cu wiring: the novel structure of Cu-Cu hybrid bonding
31. Study of ultra-fine 0.4 μm pitch wafer-to-wafer hybrid bonding and impact of bonding misalignment
32. 0.5 1/4M pitch wafer-to-wafer hybrid bonding with SiCN bonding interface for advanced memory
33. Low-temperature epoxy-based Cu/Polymer hybrid bonding for 3D IC packaging with optimized CMP
34. Process development and integration of hybrid bonding for wafers with multi-type bonding pads10.1016/j.mee.2025.112420 ↗
35. Influence of deposition conditions on ALD based Ru passivation for Cu-Cu hybrid bonding10.1038/s41598-025-20296-z ↗
36. Effects of Au passivation thickness on improving low-temperature Cu-to-Cu bonding interface10.1109/TCPMT.2025.3526663 ↗
37. Unraveling diffusion behavior in Cu-to-Cu direct bonding with metal passivation layers10.1038/s41598-024-57379-2 ↗
38. First demonstration of enhanced Cu-Cu bonding at low temperature with ruthenium passivation layer10.1109/ACCESS.2024.3409622 ↗
39. Synergistic plasma activation-enabled low-temperature Cobalt/SiO2 hybrid bonding without oxide interfaces10.1021/acsami.4c21182 ↗
40. Feasibility of surface activated bonding for ultra-fine pitch interconnection-a new concept of bump-less direct bonding for system level packaging
41. Bumpless interconnect through ultrafine Cu electrodes by means of surface-activated bonding (SAB) method10.1109/TADVP.2006.873138 ↗
42. Recent progress in surface activated bonding for 3D and heterogeneous integration10.35848/1347-4065/adcfab ↗
43. Wafer bonding of SiC-SiC and SiC-Si by modified suface activated bonding method
44. Combined surface activation bonding for Cu/SiO 2 hybrid bonding for 3D integration
45. Development of low temperature CuCu bonding and hybrid bonding for three-dimensional integrated circuits (3D IC)10.1016/j.microrel.2021.114412 ↗
46. Investigation of low temperature Cu/Cu wafer bonding for hybrid bonding applications
47. Surface activated bonding for hybrid and all-metal 3D (AM3D) interconnect
48. Hybrid Pt nanostructures by metallization of organic films10.1021/jp406370c ↗
49. Dual interfacial modification with 1D perovskite for self-assembled monolayer based inverted perovskite solar cells10.1016/j.nanoen.2024.109811 ↗
50. Selective self-assembled monolayer for copper surface protection during plasma activation of hybrid-bonded wafers
51. Multi-functional self-assembled monolayer for chip-to-chip and chip-to-wafer hybrid bonding
52. Dielectric bonding method for 3D integration packaging using self-assembled monolayer10.1007/s13391-025-00547-x ↗
53. The high-adhesion die-cleaning tape with dual-functional groups for die to wafer (D2W) hybrid bonding10.1021/acsaelm.4c00308 ↗
54. Tailored microstructure and enhanced bonding strength of in-situ surface modified Cu flakes via oxidation–reduction bonding
55. Robustness and reliability achievements for direct hybrid bonding integration: a review
56. Impacts of misalignment on 1μm pitch Cu-Cu hybrid bonding
57. Cu–SiO2 hybrid bonding
58. Low-temperature Cu/SiO 2 hybrid bonding using a novel two-step cooperative surface activation
59. Non-TCB process Cu/SiO 2 hybrid bonding using plasma-free hydrophilicity enhancement with NaOH for Chip-to-wafer bonding
60. Towards standardization of hybrid bonding interface: In-depth study of dielectrics on direct bonding
61. Impact of dielectric types on surface topography for wafer-level hybrid bonding
62. Investigation on the performance of phenyl-rich silicon oxycarbide (SiCO) ceramics as electrode material for voltammetric detection of carbendazim10.1007/s10008-024-06052-9 ↗
63. Investigation of paramagnetic defects in SiCN and SiCO-based wafer bonding
64. Characterization of die-to-wafer hybrid bonding using heterogeneous dielectrics
65. Reliability challenges in advanced 3D technologies: The case of through silicon vias and SiCN–SiCN wafer-to-wafer hybrid-bonding technologies10.1109/TDMR.2023.3327664 ↗
66. Evaluation of PVD SiCN for Cu/SiCN hybrid bonding
67. 0.5 μM pitch wafer-to-wafer hybrid bonding at low temperatures with SiCN bond layer
68. Characteristics of PVD SiCN for application in hybrid Cu bonding10.5573/JSTS.2025.25.1.102 ↗
69. Hybrid bonding of nanotwinned copper/organic dielectrics with low thermal budget
70. Demonstration of low temperature Cu-Cu hybrid bonding using a novel thin polymer
71. Development of polymer base hybrid bonding process
72. A study on multi-chip stacking process by novel dielectric polymer adhesive for Cu-Cu hybrid bonding
73. Chemical mechanical planarization of nanotwinned copper/polyimide for low temperature hybrid bonding10.1016/j.jelechem.2024.118544 ↗
74. Hybrid bonding with particle accommodation using polymer dielectric: Design, process and yield study
75. Effect of compressive stress on evolution and healing kinetics of artificial voids in highly (111)-oriented Cu-Cu wafer bonding at 300°C10.1149/2162-8777/abf16b ↗
76. Effect of anisotropic grain growth on improving the bonding strength of< 111>-oriented nanotwinned copper films10.1016/j.msea.2021.140754 ↗
77. Cu-SiO 2 hybrid bonding yield enhancement through Cu grain enlargement
78. Enhanced thermal expansion with nanocrystalline Cu in SiO2 vias for hybrid bonding10.1016/j.apsusc.2024.160784 ↗
79. Low temperature Cu/SiO2 hybrid bonding via< 1 1 1>-oriented nanotwinned Cu with Ar plasma surface modification10.1016/j.apsusc.2023.157854 ↗
80. Low-temperature Cu-Cu bonding using< 111>-oriented and nanocrystalline hybrid surface grains
81. Copper microstructure optimization for fine pitch low temperature Cu/SiO 2 hybrid bonding
82. Atomic study on Copper–Copper bonding using nanoparticles10.1115/1.4046164 ↗
83. Molecular dynamics simulation study of Zr interposer promoting Cu-Cu low-temperature hybrid bonding
84. Low-temperature (260°C) solderless Cu–Cu bonding for fine-pitch 3-D packaging and heterogeneous integration10.1109/TCPMT.2021.3065531 ↗
85. Modelling and characterization on wafer to wafer hybrid bonding technology for 3D IC packaging
86. Numerical simulation of Cu/polymer-dielectric hybrid bonding process using finite element analysis
87. Material innovation through atomistic modelling for hybrid bonding technology
88. Hybrid bonding for ultra-high-density interconnect10.1115/1.4064750 ↗
89. Copper bonding technology in heterogeneous integration10.1007/s13391-023-00433-4 ↗