Ferroelectric domains in pressureless-sintered barium titanate

Abstract Ferroelectric domains in pressureless-sintered BaTiO 3 ceramics have been studied using scanning and transmission electron microscopy. Both the 90°- and 180°-type exhibiting the characteristic features of herringbones, square-nets, and “water-mark”, respectively, are observed in polished sections. Most of the domains identified in thin foils are the conventional 90° a–a type. Unconventional 90° a–a domain boundaries lying on {111} are also identified from the CO 2 -laser-sintered samples, but they have vanished after several minutes of electron beam irradiation. Both the wedge-shape and overlapped “microtwin” domains exhibit the characteristic δ -fringes. The displacement vector R of 〈101〉 is thought to have derived from a small lattice translation introduced by the rotation of the polarization vector across the domain boundaries. Lattice-fringe images of the 90° domain boundaries suggest that the lattice distortion has occurred to accommodate the strain generated by the c→t-BaTiO 3 phase transition. The strain thus induced is manifested by dot contrast appearing on the 90° domain walls as revealed by transmission electron microscopy. The distribution of dots suggests that the strains are taken up inhomogeneously both along and across the domain boundaries by the crystal lattices.