journal article·2021-01-21

Energy Transfer between Anthracene-9-carboxylic Acid Ligands and CsPbBr3 and CsPbI3 Nanocrystals

Jake Hardy, Matthew W. Brett, Aurélien Rossi, Isabella Wagner, Kai Chen, Mattie S. M. Timmer, Bridget L. Stocker, Michael B. Price, Nathaniel J. L. K. Davis

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Abstract

Cesium lead halide perovskite nanocrystals show great promise for optoelectronic applications due to their thermal stability, wide absorption range, and intense photoluminescence. These properties make CsPbX 3 (X = Cl, Br, or I) nanocrystals great potential candidates for incorporation into light harvesting antenna complexes and photon multipliers via the coordination of organic chromophores as surface-bound ligands. In this paper, we demonstrate the synthesis of CsPbBr 3 and CsPbI 3 NCs and direct in situ attachment of anthracene-9-carboxylic acid ligands to their surface. Using steady-state and time-resolved fluorescence measurements, we show that CsPbX 3 –anthracene systems demonstrate energy transfer from the anthracene ligands via FRET with efficiencies as high as 40%.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Perovskite Materials and Applications · Quantum Dots Synthesis And Properties · Organic Light-Emitting Diodes Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemical and Physical Sciences, Victoria University of Wellington, Wellington 6140, New Zealand

Wellington UniVentures, Victoria University of Wellington, Wellington 6140, New Zealand

Robinson Research Institute, Faculty of Engineering, Victoria University of Wellington, Wellington 6140, New Zealand

The MacDiarmid Institute for Advanced Materials and Nanotechnology, Victoria University of Wellington, Wellington 6140, New Zealand

The Dodd-Walls Centre for Photonic and Quantum Technologies, University of Otago, Dunedin 9056, New Zealand

Funding

Royal Society · Ministry of Business, Innovation and Employment · MacDiarmid Institute for Advanced Materials and Nanotechnology · Victoria University of Wellington · Royal Society of New Zealand · Marsden Fund · Science for Technological Innovation Science Challenges · Victoria Research Trust

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