journal article·2022-11

Magnetic and magneto-optical properties of La0.8Sr0.2FeO3 crystals in alumina doped lead-bismuth-borate Faraday rotating glass matrix

Qiuling Chen, Weihao Chen

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Abstract

In this study, we reported the synthesis of perovskite La 0.8Sr 0.2FeO 3 nanocrystals in heavy metal oxide glass under the Al 2O 3 tailoring. 10 nm-nanocrystals of orthogonal La 0.8Sr 0.2FeO 3 were synthesized and well distributed in glass by melting quenching followed with subsequent crystallization process at 400 °C for 30 min for 10% Al 2O 3 content. Aluminum abnormality effect and the Sr 2+ induced multi-valence states of Fe ions and oxygen vacancies in La 0.8Sr 0.2FeO 3 lattice, resulting in polarizability and oxygen packing density change. The glass with 10%Al 2O 3 amount exhibited a large thermal stability (132 °C) and significant enhancement in Verdet constant of 105 rad/T.m at 633 nm wavelength. The obtained Verdet constant values were compared with relative literatures and the values in this study are superior than values in literatures. The obtained glass with extremely good magnetic property and magneto optical performances can be promising candidate for photonics device applications.
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Research context

OpenAlex topics: Magneto-Optical Properties and Applications · Glass properties and applications · Multiferroics and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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