journal article·2011-10

Antiferromagnetic interactions in Er-doped SnO2 DMS nanoparticles

S. Sambasivam, D. Paul Joseph, Jung Hyun Jeong, Byung Chun Choi, Kwon Taek Lim, Sang Su Kim, Tae Kwon Song

Journal of Nanoparticle Research· Volume 13· Issue 10
Publisher page

Abstract

Diluted magnetic semiconductor (DMS) nanoparticles of Sn1−x Er x O2 (x = 0.0, 0.02, 0.04, and 0.1) were prepared by sol–gel method. The X-ray diffraction patterns showed SnO2 rutile structure for all samples with no impurity peaks. The decrease in crystallite size with Er concentration was confirmed from TEM measurements (from 12 to 4 nm). The UV–Visible absorption spectra of Er-doped SnO2 nanoparticles showed blue shift in band gap compared to undoped SnO2. The electron spin resonance analysis of Er-doped SnO2 nanoparticles indicate Er3+ in a rutile lattice and also decrease in intensity with Er concentration above x = 0.02. Temperature-dependent magnetization studies and the inverse susceptibility curves indicated increased antiferromagnetic interaction with Er concentration.
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Research context

OpenAlex topics: ZnO doping and properties · Gas Sensing Nanomaterials and Sensors · Ga2O3 and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (38)

Show source-provided references
1. Abragam A, Bleany B (1970) Electron paramagnetic resonance of transition ions. Clarendon, Oxford
2. Bouloudenine M, Virat N, Colis S, Kortus J, Dinia A (2005) Antiferromagnetism in bulk Zn1−x Co x O magnetic semiconductors prepared by the coprecipitation technique. Appl Phys Lett 87:052501. doi: 10.1063/1.200173910.1063/1.2001739 ↗
3. Brovelli S, Baraldi A, Capelletti R, Chiodini N, Lauria A, Mazzera M, Monguzzi A, Paleari A (2006) Growth of SnO2 nanocrystals controlled by erbium doping in silica. Nanotechnology 17:4031–4036. doi: 10.1088/0957-4484/17/16/00610.1088/0957-4484/17/16/006 ↗
4. Coey JMD, Douvalis AP, Fitzgerald CB, Venkatesan M (2004) Ferromagnetism in Fe-doped SnO2 thin films. Appl Phys Lett 84:1332–1334. doi: 10.1063/1.165004110.1063/1.1650041 ↗
5. Coey JMD, Venkatesan M, Stamenov P, Fitzgerald CB, Dorneles LS (2005) Magnetism in hafnium dioxide. Phys Rev B 72:024450. doi: 10.1103/PhysRevB.72.02445010.1103/PhysRevB.72.024450 ↗
6. Das S, Kar S, Chaudhuri S (2006) Optical properties of SnO2 nanoparticles and nanorods synthesized by solvothermal process. J Appl Phys 99:114303(1)–114303(7). doi: 10.1063/1.2200449
7. Datta S, Das B (1990) Electronic analog of the electro-optic modulator. Appl Phys Lett 56:665–667. doi: 10.1063/1.10273010.1063/1.102730 ↗
8. Dietl T, Ohno H, Matsukura F, Cibert J, Ferrand D (2000) Zener model description of ferromagnetism in zinc-blende magnetic semiconductors. Science 287:1019–1022. doi: 10.1126/science.287.5455.101910.1126/science.287.5455.1019 ↗
9. Fiederling R, Kleim M, Reuscher G, Ossau W, Schmidt G, Waag A, Molenkamp LW (1999) Injection and detection of a spin-polarized current in a light emitting diode. Nature 402:787–790. doi: 10.1038/4550210.1038/45502 ↗
10. Fitzgerald CB, Venkatesan M, Douvalis AP, Huber S, Coey JMD, Bakas T (2004) SnO2 doped with Mn, Fe or Co:RT DMS. J Appl Phys 95:7390–7392. doi: 10.1063/1.167602610.1063/1.1676026 ↗
11. Fukano T, Ida T, Hashizume H (2005) Ionization potentials of transparent conductive indium tin oxide films covered with a single layer of fluorine-doped tin oxide nanoparticles grown by spray pyrolysis deposition. J Appl Phys 97:084314(1)–084314(6). doi: 10.1063/1.186648810.1063/1.1866488 ↗
12. Hong NH, Sakai J (2005) Ferromagnetic V-doped SnO2 thin films. Physica B 358:265–268. doi: 10.1016/j.physb.2005.01.45610.1016/j.physb.2005.01.456 ↗
13. Hong NH, Sakai J, Prellier W, Hassini A (2005) Transparent Cr-doped SnO2 thin films: ferromagnetism beyond RT with a giant magnetic moment. J Phys 17:1697–1702. doi: 10.1088/0953-8984/17/10/023
14. Hong NH, Sakai J, Poirot N, Brize V (2006) RT ferromagnetism observed in undoped semiconducting and insulating oxide thin films. Phys Rev B 73:132404(1)–132404(4). doi: 10.1103/PhysRevB.73.132404
15. Korotcenkov G (2005) Gas response control through structural and chemical modification of metal oxide films: state of the art and approaches. Sens Actuator B 107:209–232. doi: 10.1016/j.snb.2004.10.00610.1016/j.snb.2004.10.006 ↗
16. Lawes G, Risbud AS, Ramirez AP, Seshadri R (2005) Absence of ferromagnetism in Co and Mn substituted polycrystalline ZnO. Phys Rev B 71:045201. doi: 10.1103/PhysRevB.71.04520110.1103/PhysRevB.71.045201 ↗
17. Lee HM, Kim SJ, Shim I-B, Kim CS (2003) Mössbauer studies of 57Fe-doped anatase TiO2. IEEE Trans Magn 39:2788–279010.1109/TMAG.2003.815712 ↗
18. Minami T, Nanto H, Takata S (1988) Highly conducting and transparent SnO2 thin films prepared by RF magnetron sputtering on low temperature substrates. Jpn J Appl Phys 27:L287–L289. doi: 10.1143/JJAP.27.L287-L28910.1143/JJAP.27.L287 ↗
19. Mohan Kant K, Chandrasekaran K, Ogale SB, Venkatesan T, Sethupathi K, Rao MSR (2005) Magnetic and optical properties of rare earth doped Sn0.95RE0.05O2 (RE = Gd, Dy, Er). J Appl Phys 97:10A925(1)–10A925(3). doi: 10.1063/1.185570710.1063/1.1855707 ↗
20. Morais EA, Luis Scalvi VA (2007) Decay of photo-excited conductivity of Er-doped SnO2 thin films. J Mater Sci 42:2216–2221. doi: 10.1007/s10853-006-1320-010.1007/s10853-006-1320-0 ↗
21. Ogale SB, Choudhary RJ, Buban JP, Lofland SE, Shinde SR, Kale SN, Kulkarni VN, Higgins J, Lanci C, Simpson JR, Browning ND, Sarma SD, Drew HD, Greene RL, Venkatesan T (2003) High temperature ferromagnetism with a giant magnetic moment in transparent Co-doped SnO2. Phys Rev Lett 91:077205(1)–077205(4). doi: 10.1103/PhysRevLett.91.07720510.1103/PhysRevLett.91.077205 ↗
22. Ohno H (1998) Making nonmagnetic semiconductors ferromagnetic. Science 281:951–956. doi: 10.1126/science.281.5379.95110.1126/science.281.5379.951 ↗
23. Ohno H, Munekata H, Penney T, Von Molnar S, Chang LL (1992) Magnetotransport properties of p-type (In, Mn)As diluted magnetic III-V semiconductors. Phys Rev Lett 68:2664–2667. doi: 10.1103/PhysRevLett.68.266410.1103/PhysRevLett.68.2664 ↗
24. Ohno H, Shen A, Matsukura F, Oiwa A, Endo A, Katsumoto S, Iye Y (1996) (Ga, Mn)As: a new diluted magnetic semiconductor based on GaAs. Appl Phys Lett 69:363–365. doi: 10.1063/1.11806110.1063/1.118061 ↗
25. Paul Joseph D, Venkateswaran C (2010) Room temperature ferromagnetism in Cr doped chalcopyrite type Cu-Zn-Se compound. Phys Status Solidi A 207:2549–2552. doi: 10.1002/pssa.20102617910.1002/pssa.201026179 ↗
26. Paul Joseph D, Renugambal P, Saravanan M, Philip Raja S, Venkateswaran C (2009) Effect of Li doping on the structural, optical and electrical properties of spray deposited SnO2 thin films. Thin Solid Films 517:6129. doi: 10.1016/j.tsf.2009.04.04710.1016/j.tsf.2009.04.047 ↗
27. Reed ML, El-Masry NA, Stadelmaier HH, Ritums MK, Reed MJ, Parker CA, Roberts JC, Bedair SM (2001) Room temperature ferromagnetic properties of (Ga, Mn)N. Appl Phys Lett 79:3473–3475. doi: 10.1063/1.141923110.1063/1.1419231 ↗
28. Ruderman MA, Kittel C (1954) Indirect exchange coupling of nuclear magnetic moments by conduction electrons. Phys Rev 96:99–102. doi: 10.1103/PhysRev.96.9910.1103/PhysRev.96.99 ↗
29. Sambasivam S, Choi BC, Lin JG (2011) Intrinsic magnetism in Fe doped SnO2 nanoparticles. J Solid State Chem 184:199–203. doi: 10.1016/j.jssc.2010.11.01010.1016/j.jssc.2010.11.010 ↗
30. Soumahoro I, Moubah R, Schmerber G, Colis S, Ait Aouaj M, Abd-lefdil M, Hassanain N, Berrada A, Dinia A (2010) Structural, optical, and magnetic properties of Fe-doped ZnO films prepared by spray pyrolysis method. Thin Solid Films 518:4593. doi: 10.1016/j.tsf.2009.12.03910.1016/j.tsf.2009.12.039 ↗
31. Sundaresan A, Bhargavi R, Rangarajan N, Siddesh U, Rao CNR (2006) Ferromagnetism as a universal feature of nanoparticles of the otherwise nonmagnetic oxides. Phys Rev B 74:161306. doi: 10.1103/PhysRevB.74.16130610.1103/PhysRevB.74.161306 ↗
32. Tarey RD, Raju TA (1985) A method for the deposition of transparent conducting thin films of tin oxide. Thin Solid Films 128:181–18910.1016/0040-6090(85)90070-7 ↗
33. Ting C-C, Chen S-Y, Hsieh W-F, Lee H-Y (2001) Effects of yttrium codoping on photoluminescence of erbium-doped TiO2 films. J Appl Phys 90(11):5564–5569. doi: 10.1063/1.141349010.1063/1.1413490 ↗
34. Wang D, Wen S, Chen J, Zhang S, Li F (1994) Microstructure of SnO2. Phys Rev B 49:14282–14285. doi: 10.1103/PhysRevB.49.1428210.1103/PhysRevB.49.14282 ↗
35. Wang W, Wang Z, Hong Y, Tang J, Yu M (2006) Structure and magnetic properties of Cr/Fe-doped SnO2 thin films. J Appl Phys 99:08M115. doi: 10.1063/1.217194010.1063/1.2171940 ↗
36. Wu J, Coffer JL (2007) Strongly emissive erbium doped tin oxide nanofibers derived from sol gel/electrospinning methods. J Phys Chem C 111:16088–16091. doi: 10.1021/jp076338y10.1021/jp076338y ↗
37. Yang S, Evans SM, Halliburton LE, Slack GA, Schujman SB, Morgan KE, Bondokov RT, Mueller SG (2009) Electron paramagnetic resonance of Er3+ ions in aluminum nitride. J Appl Phys 105:023714. doi: 10.1063/1.306553210.1063/1.3065532 ↗
38. Yosida K (1957) Magnetic properties of Cu-Mn alloys. Phys Rev 106:893–898. doi: 10.1103/PhysRev.106.89310.1103/PhysRev.106.893 ↗