journal article·2018-01

Thermal engineering of lead-free nanostructured CH3NH3SnCl3 perovskite material for thin-film solar cell

Sk Abdul Moyez, Subhasis Roy

Journal of Nanoparticle Research· Volume 20· Issue 1
Publisher page

Abstract

Perovskite solar cell is a kind of revolutionary investigation in the field of renewable energy which is capable of mitigates the deficiencies of silicon solar cell and its uprising efficiency can bring blessing to society. The presence of lead (Pb) in perovskite solar cell can make worst and negative impact on environment and is not desirable for our society. In this paper, general plans are anticipated by replacement of Pb with tin (Sn) in open atmosphere to fabricate the CH3NH3SnCl3 photovoltaic cells in chlorine (Cl)-rich environment. Excess uses of Cl has positive influences on morphological growth of the film and it also suppresses the oxidation tendency of tin (Sn) with existing oxygen in atmosphere and maintains same chemical atmosphere as bulk. Various characterization tools like X-ray diffraction, scanning electron microscope (SEM) have been used to study the effect of annealing temperature on crystal stricture, phase formation, impurities, and morphologies of the film. Finally, photovoltaic performance was reported using the solar simulator under 1.5 sun illumination.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Perovskite Materials and Applications · Chalcogenide Semiconductor Thin Films · Solid-state spectroscopy and crystallography

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References (41)

Show source-provided references
1. Ananthajothi P, Venkatachalam P (2016) Tin chloride perovskite-sensitized core/shell photoanode solar cell with spiro-MeOTAD hole transport material for enhanced solar light harvesting. J Solid State Electrochem 20(10):2633–2642. https://doi.org/10.1007/s10008-016-3262-z10.1007/s10008-016-3262-z ↗
2. Ball JM, Lee MM, Hey A, Snaith HJ (2013) Low-temperature processed meso-superstructured to thin-film perovskite solar cells. Energy Environ Sci 6(6):1739–1743. https://doi.org/10.1039/c3ee40810h10.1039/c3ee40810h ↗
3. Borriello I, Cantele G, Ninno D (2008) Ab initio investigation of hybrid organic-inorganic perovskites based on tin halides. Phys Rev B 77(23):235214. https://doi.org/10.1103/PhysRevB.77.23521410.1103/PhysRevB.77.235214 ↗
4. Chiarella F, Zappettini A, Licci F, Borriello I, Cantele G, Ninno D, Cassinese A, Vaglio R (2008) Combined experimental and theoretical investigation of optical, structural, and electronic properties of CH3NH3SnX3 thin films. (X=Cl,Br). Phys Rev B 77:045129410.1103/PhysRevB.77.045129 ↗
5. Colella S, Mosconi E, Fedeli P, Listorti A, Gazza F, Orlandi F, Ferro P, Besagni T, Rizzo A, Calestani G (2013) MAPbI3-xClx mixed halide perovskite for hybrid solar cells: the role of chloride as dopant on the transport and structural properties. Chem Mater 25(22):4613–4618. https://doi.org/10.1021/cm402919x10.1021/cm402919x ↗
6. Dey A, Moyez A, Mandal MK, Roy S (2016) Fabrication of solar cell using extracted biomolecules from tea leaves and hybrid perovskites. Mat Today Proc 3:3498–350410.1016/j.matpr.2016.10.033 ↗
7. Dey A, Karan P, Sengupta A, Moyez SA, Sarkar P, Majumder SB, Pradhan D, Roy S (2017) Enhanced charge carrier generation by dielectric nanomaterials for quantum dots solar cells based on CdS-TiO2 photoanode. Sol Energy 158:83–88. https://doi.org/10.1016/j.solener.2017.09.03810.1016/j.solener.2017.09.038 ↗
8. Docampo P, Ball JM, Darwich M, Eperon GE, Snaith HJ (2013) Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates. Nat Commun 4:2761–276610.1038/ncomms3761 ↗
9. Dong X, Fang X, Lv M, Lin B, Zhang S, Wang Y, Yuan N, Ding J (2016) Method for improving illumination instability of organic–inorganic halide perovskite solar cells. Sci Bull 61(3):236–244. https://doi.org/10.1007/s11434-016-0994-110.1007/s11434-016-0994-1 ↗
10. Edri E, Kirmayer S, Kulbak M, Hodes G, Cahen D (2014) Chloride inclusion and hole transport material doping to improve methyl ammonium lead bromide perovskite-based high open-circuit voltage solar cells. J Phys Chem Lett 5(3):429–433. https://doi.org/10.1021/jz402706q10.1021/jz402706q ↗
11. Feng J, Xiao B (2014) Effective masses and electronic and optical properties of nontoxic MASnX3 (X=Cl, Br, and I) perovskite structures as solar cell absorber: a theoretical study using HSE06. J Phys Chem C 118(34):19655–19660. https://doi.org/10.1021/jp506498k10.1021/jp506498k ↗
12. Frost JM, Butler KT, Brivio F, Hendon CH, van Schilfgaarde M, Walsh A (2014) Atomistic origins of high-performance in hybrid halide perovskite solar cells. Nano Lett 14(5):2584–2590. https://doi.org/10.1021/nl500390f10.1021/nl500390f ↗
13. Gidlow DA (2004) Lead toxicity. Occup Med (Lond) 54(2):76–81. https://doi.org/10.1093/occmed/kqh01910.1093/occmed/kqh019 ↗
14. Grätzel M (2014) The light and shade of perovskite solar cells. Nat Mater 13(9):838–842. https://doi.org/10.1038/nmat406510.1038/nmat4065 ↗
15. Green MA, Ho-Baillie A, Snaith HJ (2014) The emergence of perovskite solar cells. Nat Photon 8(7):506–514. https://doi.org/10.1038/nphoton.2014.13410.1038/nphoton.2014.134 ↗
16. Han GS, Lee S, Kim DW, Kim DH, Noh JH, Park JH, Roy S, Ahn TK (2013) A simple method to control morphology of hydroxyapatite nano-and microcrystals by altering phase transition route. Cryst Growth Des 13(8):3414–3418. https://doi.org/10.1021/cg400308a10.1021/cg400308a ↗
17. Hao F, Stoumpos CC, Chang RPH, Kanatzidis MG (2014) Anomalous band gap behavior in mixed Sn and Pb perovskites enables broadening of absorption spectrum in solar cells. J Am Chem Soc 136(22):8094–8099. https://doi.org/10.1021/ja503325910.1021/ja5033259 ↗
18. Hao F, Stoumpos CC, Guo P, Zhou N, Marks TJ, Chang RPH, Kanatzidis MG (2015) Solvent-mediated crystallization of CH3NH3SnI3 films for heterojunction depleted perovskite solar cells. J Am Chem Soc 137(35):11445–11452. https://doi.org/10.1021/jacs.5b0665810.1021/jacs.5b06658 ↗
19. Kagan CR, Mitzi DB, Dimitrakopoulos CD (1999) Organic-inorganic hybrid materials as semiconducting channels in thin-film field-effect transistors. Science 286(5441):945–947. https://doi.org/10.1126/science.286.5441.94510.1126/science.286.5441.945 ↗
20. Kojima A, Teshima K, Shirai Y, Miyasaka T (2009) Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. J Am Chem Soc 131(17):6050–6051. https://doi.org/10.1021/ja809598r10.1021/ja809598r ↗
21. Kumar MH, Dharani S, Leong WL, Boix PP, Prabhakar RR, Baikie T, Shi C, Ding H, Ramesh R, Asta M, Graetzel M, Mhaisalkar SG, Mathews N (2015) Lead-free halide perovskite solar cells with high photocurrents realized through vacancy modulation. Adv Mater 26(41):7122–712710.1002/adma.201401991 ↗
22. Lee MM, Teuscher J, Miyasaka T, Murakami TN, Snaith HJ (2012) Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites. Science 338(6107):643–647. https://doi.org/10.1126/science.122860410.1126/science.1228604 ↗
23. Liang PW, Liao CY, Chueh CC, Zuo F, Williams ST, Xin XK, Lin J, Jen AKY (2014) Additive enhanced crystallization of solution-processed perovskite for highly efficient planar-heterojunction solar cells. Adv Mater 26(22):3748–3754. https://doi.org/10.1002/adma.20140023110.1002/adma.201400231 ↗
24. Lotsch BV (2014) New light on an old story: perovskites go solar. Angew Chem Int Ed 53(3):635–637. https://doi.org/10.1002/anie.20130936810.1002/anie.201309368 ↗
25. Lyu M, Yun JH, Cai M, Jiao Y, Bernhardt PV, Zhang M, Wang Q, Du A, Wang H, Liu G, Wang L (2016a) Organic–inorganic bismuth (III)-based material: a lead-free, air-stable and solution-processable light-absorber beyond organolead perovskites. Nano Res 9(3):692–702. https://doi.org/10.1007/s12274-015-0948-y10.1007/s12274-015-0948-y ↗
26. Lyu M, Zhang M, Cooling NA, Jiao Y, Wang Q, Yun JH, Vaughan B, Triani G, Evans P, Zhou X, Feron K, Du A, Dastoor P, Wang L (2016b) Highly compact and uniform CH3NH3Sn0.5Pb0.5I3 films for efficient panchromatic planar perovskite solar cells. Sci Bull 61(20):1558–1562. https://doi.org/10.1007/s11434-016-1147-210.1007/s11434-016-1147-2 ↗
27. Malliga P, Pandiarajan J, Prithivikumaran N, Neyvasagam K (2014) Influence of film thickness on structural and optical properties of sol–gel spin coated TiO2 thin film. IOSR-JAP 6(1):22–28. https://doi.org/10.9790/4861-0611222810.9790/4861-06112228 ↗
28. Mosca R, Ferro P, Besagni T, Calestani D, Chiarella F, Licci F (2011) Effect of humidity on the a.c. impedance of CH3NH3SnCl3 hybrid films. Appl Phys A Mater Sci Process 104(4):1181–1187. https://doi.org/10.1007/s00339-011-6407-z10.1007/s00339-011-6407-z ↗
29. Moyez A, Dhar A, Sarkar P, Jung HS, Roy S (2016) A review of the multiple exciton generation in photovoltaics. Rev Adv Sci Eng 5(1):51–64. https://doi.org/10.1166/rase.2016.110810.1166/rase.2016.1108 ↗
30. Moyez SA, Sengupta A, Biswas AB, Roy S, Dey A, Das BC (2017) Fabrication of environmental friendly perovskite solar cell by partial replacement of lead with tin. Invertis J Renew Energy 7(2):59–6310.5958/2454-7611.2017.00008.X ↗
31. Nayak PK, Cahen D (2014) Updated assessment of possibilities and limits for solar cells. Adv Mater 26(10):1622–1628. https://doi.org/10.1002/adma.20130462010.1002/adma.201304620 ↗
32. Ogomi Y, Morita A, Tsukamoto S, Saitho T, Fujikawa N, Shen Q, Toyoda T, Yoshino K, Pandey SS, Ma T, Hayase S (2014) CH3NH3SnxPb(1-x)I3 perovskite solar cells covering up to 1060 nm. J Phys Chem Lett 5(6):1004–1011. https://doi.org/10.1021/jz500211710.1021/jz5002117 ↗
33. Roiati V, Mosconi E, Listorti A, Colella S, Gigli G, De Angelis F (2014) Stark effect in perovskite/TiO2 solar cells: evidence of local interfacial order. Nano Lett 14(4):2168–2174. https://doi.org/10.1021/nl500544c10.1021/nl500544c ↗
34. Roy S, Han GS, Shin H, Lee JW, Mun J, Shin H, Jung HS (2015) Low temperature synthesis of rutile TiO2 nanocrystals and their photovoltaic and photocatalytic properties. J Nanosci Nanotechnol 15:4516–452110.1166/jnn.2015.9778 ↗
35. Sarkar P, Moyez SA, Dey A, Roy S, Das SK (2017) Experimental investigation of photocatalytic and photovoltaic activity of titania/rice husk crystalline nano-silica hybrid composite. Sol Energy Mater Sol 172:93–98. https://doi.org/10.1016/j.solmat.2017.07.02110.1016/j.solmat.2017.07.021 ↗
36. Stoumpos CC, Malliakas CD, Kanatzidis MG (2013) Semiconducting tin and lead iodide perovskites with organic cations: phase transitions, high mobilities, and near-infrared photoluminescent properties. Inorg Chem 52(15):9019–9038. https://doi.org/10.1021/ic401215x10.1021/ic401215x ↗
37. Stranks SD, Eperon GE, Grancini G, Menelaou C, Alcocer MJP, Leijtens T, Herz LM, Petrozza A, Snaith HJ (2013) Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber. Science 342(6156):341–344. https://doi.org/10.1126/science.124398210.1126/science.1243982 ↗
38. Yamamuro NO, Matsuo T, Suga H (1990) Calorimetric and IR spectroscopy studies of phase transitions in methylammonium trihalogenoplumbates (ii). J Phys Chem Solids 51(12):1383–1395. https://doi.org/10.1016/0022-3697(90)90021-710.1016/0022-3697(90)90021-7 ↗
39. Yin W, Shi T, Yan Y (2014) Unusual defect physics in CH3NH3PbI3 perovskite solar cell absorber. Appl Phys Lett 104(6):063903. https://doi.org/10.1063/1.486477810.1063/1.4864778 ↗
40. You J, Hong Z, Yang Y (2014) Low-temperature solution-processed perovskite solar cells with high efficiency and flexibility. ACS Nano 8(2):1674–1680. https://doi.org/10.1021/nn406020d10.1021/nn406020d ↗
41. Zhao K, Munir R, Yan B, Yang Y, Kim T, Amassian A (2015) Solution-processed inorganic copper(I) thiocyanate (CuSCN) hole transporting layers for efficient p–i–n perovskite solar cells. J Mater Chem A 3(41):20554–20559. https://doi.org/10.1039/C5TA04028K10.1039/C5TA04028K ↗