Enhanced energy-storage density and temperature stability of Pb0.89La0.06Sr0.05(Zr0.95Ti0.05)O3 anti-ferroelectric thin film capacitor
Source abstract
Abstract
As the fundamental energy storage components in electronic systems, dielectric capacitors with high power densities were demanded. In this work, the anti-ferroelectric Pb0.89La0.06Sr0.05(Zr0.95Ti0.05)O3 (PLSZT) ceramics and thin film capacitor were successfully fabricated by a solid-state reaction route and pulsed laser deposition method, respectively. The ferroelectric, dielectric, energy-storage properties, and temperature stability of anti-ferroelectric PLSZT capacitor were investigated in detail. By compared with the PLSZT ceramic (energy storage density is 1.29 J/cm3 with an efficiency of 78.7% under 75 kV/cm), the anti-ferroelectric PLSZT thin film capacitors exhibited the enhanced energy storage density of 52.6 J/cm3 with efficiency of 67.7% under an electric field as high as 2068.9 kV/cm, and the enhanced energy-storage temperature stabilities from room temperature (RT) to more than 200 °C were demonstrated, and the oxygen defects mechanism and size effect were discussed. Moreover, the fast charging (∼0.05 μs) and discharging (∼0.15 μs) time were certified for the anti-ferroelectric PLSZT film capacitor. These findings broaden the horizon for PLSZT anti-ferroelectrics in high energy storage properties and show promising for manufacturing pulse power capacitor.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Ferroelectric and Piezoelectric Materials · Dielectric materials and actuators · Multiferroics and related materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (57)
Show source-provided references
1. Ultrahigh-energy density lead-free dielectric films via polymorphic nanodomain design10.1126/science.aaw8109 ↗
2. Flexible high-temperature dielectric materials from polymer nanocomposites10.1038/nature14647 ↗
3. A dielectric polymer with high electric energy density and fast discharge speed10.1126/science.1127798 ↗
4. Giant energy density and high efficiency achieved in bismuth ferrite-based film capacitors via domain engineering10.1038/s41467-018-04189-6 ↗
5. Large energy storage density and high thermal stability in a highly textured (111)-oriented Pb0.8Ba0.2ZrO3 relaxor thin film with the coexistence of antiferroelectric and ferroelectric phases10.1021/acsami.5b02790 ↗
6. Ultrahigh energy-storage density in antiferroelectric ceramics with field-induced multiphase transitions10.1002/adfm.201807321 ↗
7. Multilayer hierarchical interfaces with high energy density in polymer nanocomposites composed of BaTiO3@TiO2@Al2O3 nanofibers10.1039/C7TA03846A ↗
8. Ultrahigh energy storage performance of lead-free oxide multilayer fifilm capacitors via interface engineering10.1002/adma.201604427 ↗
9. Novel BaTiO3-based lead-free ceramic capacitors featuring high energy storage density, high power density, and excellent stability10.1039/C8TC03003K ↗
10. Thickness-dependent dielectric and energy storage properties of (Pb0.96La0.04)(Zr0.98Ti0.02)O3 anti-ferroelectric thin films10.1063/1.4944802 ↗
11. Antiferroelectric thin-film capacitors with high energy-storage densities, low energy losses, and fast discharge times10.1021/acsami.5b08786 ↗
12. Novel strontium titanate-based lead-free ceramics for high-energy storage applications10.1021/acssuschemeng.7b02203 ↗
13. High energy storage density and ultrafast discharge in lead lutetium niobate based ceramics10.1039/C9TA00463G ↗
14. Large energy storage density, low energy loss and highly stable (Pb0.97La0.02)(Zr0.66Sn0.23Ti0.11)O3 antiferroelectric thin-film capacitors10.1016/j.jeurceramsoc.2018.03.004 ↗
15. Fabrication and characterization of Sol-Gel derived (100)-textured (Pb0.97La0.02)(Zr0.95Ti0.05)O3 thin films10.1111/j.1551-2916.2009.03304.x ↗
16. Large electric field-induced strain and antiferroelectric behavior in (1-x)(Na0.5Bi0.5)TiO3-xBaTiO3 ceramics10.1021/cm102719k ↗
17. Ultra-high energy-storage density and fast discharge speed of (Pb0.98-xLa0.02Srx)(Zr0.9Sn0.1)0.995O3 antiferroelectric ceramics prepared via the tape casting method10.1039/C9TA02149C ↗
18. Phase-transition induced giant negative electrocaloric effect in a lead-free relaxor ferroelectric thin film10.1039/C9EE00269C ↗
19. Improvement of the recoverable energy storage density and efficiency by utilizing the linear dielectric response in ferroelectric capacitors10.1063/1.4892454 ↗
20. B-site non-stoichiometric (Pb0.97La0.02)(Zr0.95Ti0.05)O3 antiferroelectric ceramics for energy storage10.1080/21870764.2018.1501126 ↗
21. Large electrocaloric effect inrelaxor ferroelectric and antiferroelectric lanthanum doped lead zirconate titanate ceramics10.1038/srep45335 ↗
22. Strongly enhanced dielectric and energy storage properties in lead-free perovskite titanate thin films by alloying10.1016/j.nanoen.2018.01.003 ↗
23. Ultrahigh energy storage and electrocaloric performance achieved in SrTiO3 amorphous thin films via polar cluster engineering10.1039/C9TA05446D ↗
24. Giant electric energy density in epitaxial lead-free thin films with coexistence of ferroelectrics and antiferroelectrics10.1002/aelm.201500052 ↗
25. Ultrahigh energy storage performance of lead-free oxide multilayer film capacitors via interface engineering10.1002/adma.201604427 ↗
26. High energy-storage density of lead-free BiFeO3 doped Na0.5Bi0.5TiO3-BaTiO3 thin film capacitor with good temperature stability10.1016/j.jallcom.2018.05.072 ↗
27. Enhanced dielectric and energystorage properties in BiFeO3-modified Bi0.5(Na0.8K0.2)0.5TiO3 thin films10.1016/j.ceramint.2017.07.039 ↗
28. Ni doping to enhance ferroelectric, energy-storage and dielectric properties of lead-free NBT ceramic thin film with low leakage current10.1016/j.ceramint.2018.01.177 ↗
29. Enhancement of charge and energy storage in sol-gel derived pure and La-modified PbZrO3 thin films10.1063/1.2928230 ↗
30. Improved energy storage performance and fatigue endurance of Sr-doped PbZrO3 antiferroelectric thin films10.1111/j.1551-2916.2009.03015.x ↗
31. Effects of composition and temperature on energy storage properties of (Pb,La)(Zr,Sn,Ti)O3 antiferroelectric ceramics10.1016/j.ceramint.2017.06.005 ↗
32. PLZT phases near lead zirconate: determination by X-Ray diffraction10.1111/j.1551-2916.2005.00102.x ↗
33. Effect of Sn:Ti variations on electric filed induced AFE-FE phase transition in PLZST antiferroelectric ceramics10.1016/j.ceramint.2011.04.037 ↗
34. High-energy storage density and excellent temperature stability in antiferroelectric/ferroelectric bilayer thin films10.1111/jace.14876 ↗
35. Enhanced energy-storage performance and electrocaloric effect in compositionally grade Pb(1-3x/2)LaxZr0.85Ti0.15O3 antiferroelectric thick films10.1016/j.ceramint.2015.09.122 ↗
36. Large strain and high energy storage density in orthorhombic perovskite (Pb0.97La0.02)(Zr1-x-ySnxTiy)O3 antiferroelectric thin films10.1063/1.3497193 ↗
37. Electric-field-induced transformation of incommensurate modulations in antiferroelectric Pb0.99Nb0.02[(Zr1-xSnx)1-yTiy]0.98O310.1103/PhysRevB.72.024102 ↗
38. The effects of oxygen vacancies on ferroelectric phase transition of HfO2-based thin film from first-principle10.1016/j.commatsci.2019.05.041 ↗
39. Enhancing ferroelectricity in dopant-free hafnium oxide10.1063/1.4973928 ↗
40. Effects of thickness on energy storage of (Pb,La)(Zr,Sn,Ti)O3 antiferroelectric films deposited on LaNiO3 electrodes10.1016/j.ceramint.2015.09.067 ↗
41. The electrical properties and phase transformation of PLZST2/85/13/2 antiferroelectric thin films on different bottom electrode10.1016/j.ssc.2007.03.048 ↗
42. The effect of substrate clamping on the paraelectric to antiferroelectric phase transition in Nd-doped BiFeO3 thin films10.1016/j.tsf.2016.10.004 ↗
43. Microstructure and electrical properties of (1-x)[0.82Bi0.5Na0.5TiO3-0.18Bi0.5K0.5TiO3]-xBiFeO3 lead-free piezoelectric ceramics10.1016/j.jallcom.2010.02.025 ↗
44. Effect of Zr addition on ZnSnO thin-film transistors using a solution process10.1063/1.3524514 ↗
45. Role of the defect in determining the properties of PbTi0.9Ni0.1O3 thin films10.1063/1.5000921 ↗
46. Large recoverable energy density with excellent thermal stability in Mn-modified NaNbO3-CaZrO3 lead-free thin films10.1111/jace.15528 ↗
47. Enhancement of ferroelectricity and large dielectric strength of Pb(Zr0.52Ti0.48)O3 thin films on SrTiO3 substrate with a SrRuO3 buffer10.1142/S1793604714500581 ↗
48. Pb0.94La0.04[(Zr0.70Sn0.30)0.90Ti0.10]O3 antiferroelectric bulk ceramics for pulsed capacitors with high energy and power density10.1063/1.4979833 ↗
49. Enhanced energy storage properties in sodium bismuth titanate-based ceramics for dielectric capacitor applications10.1039/C9TC01239G ↗
50. Excellent energy storage density and charge-discharge performance of a novel Bi0.2Sr0.7TiO3-BiFeO3 thin film10.1039/C9TC03032H ↗
51. Ultrahigh energy storage density and charge-discharge performance in novel sodium bismuth titanate-based ceramics
52. Superior energy storage performance and fatigue resistance in ferroelectric BCZT thin films grown in an oxygen-rich atmosphere10.1039/C9TC00569B ↗
53. Ultrahigh energy storage and electrocaloric performance achieved in SrTiO3 amorphous thin films via polar cluster engineering10.1039/C9TA05446D ↗
54. Enhancing electrical energy storage density in anti-ferroelectric ceramics using ferroelastic domain switching10.1088/2053-1591/1/4/045502 ↗
55. PLZT film capacitors for power electronics and energy storage applications10.1007/s10854-015-3025-0 ↗
56. Energy-storage properties and electrocaloric effect of Pb(1-3x/2)LaxZr0.85Ti0.15O3 antiferroelectric thick films10.1021/am502415z ↗
57. Energy storage and polarization switching kinetics of (001)-oriented Pb0.97La0.02(Zr0.95Ti0.05)O3 antiferroelectric thick films10.1063/1.4944645 ↗