journal article·2020-03-18

Nanoscale Infrared Spectroscopy and Imaging of Catalytic Reactions in Cu2O Crystals

G. X. Ni, S. Chen, S. S. Sunku, A. Sternbach, A. S. McLeod, L. Xiong, M. M. Fogler, G. Chen, D. N. Basov

ACS Photonics· Volume 7· Issue 3
Publisher page

Abstract

Many of the existing electrochemical catalysts suffer from poor selectivity, instability, and low exchange current densities. These shortcomings call for a comprehensive exploration of the catalytic processes at the fundamental nanometer length scale levels. Here we exploit infrared (IR) nanoimaging and nanospectroscopy to directly visualize catalytic reactions on the surface of Cu2O polyhedral single crystals with nanoscale spatial resolution. Nano-IR data revealed signatures of this common catalyst after electrochemical reduction of carbon dioxides (CO2). We discuss the utility of nano-IR methods for surface/facet engineering of efficient electrochemical catalysts.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: CO2 Reduction Techniques and Catalysts · Electronic and Structural Properties of Oxides · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Physics, Columbia University, New York, New York 10027, United States

Honda Research Institute USA, Inc., 70 Rio Robles, San Jose, California 95134, United States

Department of Applied Physics and Applied Mathematics, Columbia University, New York, New York 10027, United States

Department of Physics, University of California, San Diego, La Jolla, California 92093, United States

Funding

Basic Energy Sciences

References (41)

Show source-provided references
1. 10.1126/science.117798110.1126/science.1177981 ↗
2. 10.1021/ja501923g10.1021/ja501923g ↗
3. 10.1038/nchem.100010.1038/nchem.1000 ↗
4. 10.1126/science.120978610.1126/science.1209786 ↗
5. 10.1002/anie.20140432810.1002/anie.201404328 ↗
6. 10.1021/jacs.5b0004610.1021/jacs.5b00046 ↗
7. 10.1021/ja508879j10.1021/ja508879j ↗
8. 10.1021/ja500328k10.1021/ja500328k ↗
9. 10.1021/ja409445p10.1021/ja409445p ↗
10. 10.1021/jp310509z10.1021/jp310509z ↗
11. 10.1021/jacs.6b0884210.1021/jacs.6b08842 ↗
12. 10.1126/sciadv.aaw562310.1126/sciadv.aaw5623 ↗
13. 10.1038/s41467-018-02925-610.1038/s41467-018-02925-6 ↗
14. 10.1038/nature2079510.1038/nature20795 ↗
15. 10.1016/j.corsci.2016.02.03710.1016/j.corsci.2016.02.037 ↗
16. 10.1038/s41929-019-0306-710.1038/s41929-019-0306-7 ↗
17. 10.1038/s41560-019-0450-y10.1038/s41560-019-0450-y ↗
18. 10.1039/C4CP01520G10.1039/C4CP01520G ↗
19. 10.1038/s41929-017-0009-x10.1038/s41929-017-0009-x ↗
20. 10.1038/s41929-017-0018-910.1038/s41929-017-0018-9 ↗
21. 10.1038/s41929-019-0338-z10.1038/s41929-019-0338-z ↗
22. 10.1038/s41567-018-0201-110.1038/s41567-018-0201-1 ↗
23. 10.1038/nmat442510.1038/nmat4425 ↗
24. 10.1166/jnn.2003.20210.1166/jnn.2003.202 ↗
25. 10.1021/cr970080y10.1021/cr970080y ↗
26. 10.1063/1.478942810.1063/1.4789428 ↗
27. 10.1038/nphoton.2016.4510.1038/nphoton.2016.45 ↗
28. 10.1038/s41586-018-0136-910.1038/s41586-018-0136-9 ↗
29. 10.1126/science.aau514410.1126/science.aau5144 ↗
30. Querry, M. R. Optical constants. Contractor Report CRDC-CR-85034, Defense Technical Information Center, 1985.
31. 10.1021/ja030167310.1021/ja0301673 ↗
32. 10.1149/1.236483710.1149/1.2364837 ↗
33. 10.1002/anie.20150573010.1002/anie.201505730 ↗
34. 10.1038/ncomms1212310.1038/ncomms12123 ↗
35. 10.1021/acs.jpcc.8b0498310.1021/acs.jpcc.8b04983 ↗
36. 10.1126/science.aax584310.1126/science.aax5843 ↗
37. 10.1021/ar200293n10.1021/ar200293n ↗
38. 10.1002/advs.20150008510.1002/advs.201500085 ↗
39. 10.1021/nl101807g10.1021/nl101807g ↗
40. 10.3390/nano903046810.3390/nano9030468 ↗
41. 10.1021/acsnano.5b0118410.1021/acsnano.5b01184 ↗