Progress in Controllable Construction and Energy‐Related Applications of MX₂/Graphene and MX₂/MX₂ Heterostructures

Abstract Van der Waals heterostructures have attracted attention worldwide owing to their novel properties and diverse potential applications. Particularly, vertically stacked MX₂/graphene (MX₂/Gr, M=Mo, W; X=S, Se, etc.) and MX₂/MX₂ heterostructures have demonstrated their superiority in electronics, optoelectronics and some energy‐related applications. In this Focus Review, we summarize the recent progress in the controllable construction and characterization of MX₂/Gr and MX₂/MX₂ heterostructures, as well as their multiple applications in energy‐related fields. In the first part, we focus on the construction of MX₂/Gr heterostructures by the layer‐by‐layer transfer and the direct chemical vapor deposition (CVD) methods, as well as their excellent performance in electronic and optoelectronic devices. We then introduce the direct CVD syntheses, electronic properties and photocatalytic activities of MX₂/MX₂ heterostructures. Finally, the current challenges and opportunities for such systems are discussed.