Photoluminescence and Raman study of Cu2ZnSn(SexS1−x)4 monograins for photovoltaic applications

Abstract The quaternary semiconductors Cu 2 ZnSnSe 4 and Cu 2 ZnSnS 4 have attracted a lot of attention as possible absorber materials for solar cells due to their direct bandgap and high absorption coefficient (> 10 4 cm −1 ). In this study we investigate the optical properties of Cu 2 ZnSn(Se x S 1 − x ) 4 monograin powders that were synthesized from binary compounds in the liquid phase of potassium iodide (KI) flux materials in evacuated quartz ampoules. Radiative recombination processes in Cu 2 ZnSn(Se x S 1 − x ) 4 monograins were studied by using low-temperature photoluminescence (PL) spectroscopy. A continuous shift from 1.3 eV to 0.95 eV of the PL emission peak position with increasing Se concentration was observed indicating the narrowing of the bandgap of the solid solutions. Recombination mechanisms responsible for the PL emission are discussed. Vibrational properties of Cu 2 ZnSn(Se x S 1 − x ) 4 monograins were studied by using micro-Raman spectroscopy. The frequencies of the optical modes in the given materials were detected and the bimodal behaviour of the A 1 Raman modes of Cu 2 ZnSnSe 4 and Cu 2 ZnSnS 4 is established.