journal article·2013-03-26

Interfacing Quantum Dots and Graphitic Surfaces with Chlorine Atomic Ligands

Fabiola Iacono, Cristina Palencia, Leonor de la Cueva, Michaela Meyns, Luigi Terracciano, Antje Vollmer, María José de la Mata, Christian Klinke, José M. Gallego, Beatriz H. Juarez, Roberto Otero

ACS Nano· Volume 7· Issue 3
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Abstract

The performance of devices based on semiconductor nanocrystals (NCs) improves both with stronger interface interactions among NCs and between NCs and solid electrode surfaces. The combination of X-ray photoelectron spectroscopy (XPS) and solid (31)P CP/MAS NMR (cross-polarization/magic angle spinning nuclear magnetic resonance) shows that the selective substitution of long organic chains by chlorine atomic ligands during the colloidal synthesis by the hot injection method promotes the adsorption of CdSe NCs to carbon sp(2) surfaces, leading to the formation of well-ordered NC monolayers on graphitic materials.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Quantum Dots Synthesis And Properties · Chalcogenide Semiconductor Thin Films · ZnO doping and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Departamento de Física de la Materia Condensada and Instituto Nicolás Cabrera, Facultad de Ciencias, Universidad Autónoma de Madrid, UAM, Avd. Fco. Tomás y Valiente 7, 28049 Madrid, Spain

IMDEA Nanoscience, c\ Faraday 9, Campus de Cantoblanco, 28049 Madrid, Spain

Institute of Physical Chemistry, University of Hamburg, Grindelallee 117, Hamburg, Germany

Helmholtz Zentrum Berlin für Materialien und Energie GmbH, BESSY II, Albert-Einstein-Strasse 15, 12489 Berlin, Germany

Servicio Interdepartamental de Investigación. SIdI. Universidad Autónoma de Madrid UAM, Avd. Fco. Tomás y Valiente 7, 28049 Madrid, Spain

Instituto de Ciencia de Materiales de Madrid, ICMM, CSIC, Sor Ángela de la Cruz s/n, 28049 Madrid, Spain

Departamento de Química Física Aplicada, Facultad de Ciencias, Universidad Autónoma de Madrid UAM, Avd. Fco. Tomás y Valiente 7, 28049 Madrid, Spain

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