journal article·2016-07-26

Million-Fold Decrease in Polymer Moisture Permeability by a Graphene Monolayer

Sindhu Seethamraju, Shishir Kumar, Krishna Bharadwaj B, Giridhar Madras, Srinivasan Raghavan, Praveen Chandrashekarapura Ramamurthy

ACS Nano· Volume 10· Issue 7
Publisher page

Abstract

Flexible, transparent, and moisture-impermeable materials are critical for packaging applications in electronic, food, and pharmaceutical industries. Here, we report that a single graphene layer embedded in a flexible polymer reduces its water vapor transmission rate (WVTR) by up to a million-fold. Large-area, transparent, graphene-embedded polymers (GEPs) with a WVTR as low as 10(-6) g m(-2) day(-1) are demonstrated. Monolayered graphene, synthesized by chemical vapor deposition, has been transferred onto the polymer substrate directly by a very simple and scalable melt casting process to fabricate the GEPs. The performances of the encapsulated organic photovoltaic (OPV) devices do not vary even after subjecting the GEPs to cyclic bending for 1000 cycles. Accelerated aging studies of working OPV devices encapsulated in the GEPs show a 50% lifetime of equivalent to 1 000 000 min, which satisfies the requirements of organic electronics.
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Research context

OpenAlex topics: Graphene research and applications · Advanced Sensor and Energy Harvesting Materials · Nanowire Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Centre for Nanoscience and Engineering, ‡Department of Chemical Engineering, and §Department of Materials Engineering, Indian Institute of Science, Bangalore 560012, India

Funding

Basic Energy Sciences · Department of Science and Technology, Ministry of Science and Technology · Solar Energy Technologies Program

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