DataVXChalcogenide LettersPaper
journal article·2024-12-15Open access

Probing SnSO3/ZnSO3 nanocomposites by optical and magnetic perspective

Department of Physics, Gandhigram Rural Institute, Deemed To Be University, Gandhigram-624302, Dindigul District, Tamilnadu, India, R. Gayathri, S. Shanmugha Soundare, Centre for Nanoscience and Technology, Anna University, Chennai-600025, Tamilnadu, India, K. Haritha, Department of Physics, Gandhigram Rural Institute, Deemed To Be University, Gandhigram-624302, Dindigul District, Tamilnadu, India, S. Ariponnammal, Department of Physics, Gandhigram Rural Institute, Deemed To Be University, Gandhigram-624302, Dindigul District, Tamilnadu, India

Chalcogenide Letters· Volume 21· Issue 12
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Abstract

SnSO3/ZnSO3 nanocomposite has been synthesized using the hydrothermal process. The complete formation of the SnSO3/ZnSO3 nanocomposite is confirmed by XRD and EDAX. It displays a fascinating rectangular bar shape. The measured particle size is 100.4 nm. It will be a promising option for optoelectronic devices. Energy gap of the SnSO3/ZnSO3 nanocomposite is 5.85 eV. The refractive index of the nanocomposite through its energy gap is found to be 1.883. The ultraviolet (~387.2 nm) area of the PL emission spectrum exhibits the strong efficient emission, while the green (~522.1 nm) region and the red (~789.4 nm) region show weak and moderate emission, respectively. Radiative electronhole recombination is seen in the UV emission at 387.2 nm, which qualifies the contender for displays/projection-based applications. Emission peaks observed in the visible region is attributed to various defects Frenkel or Schottky defects, Tin or Zinc interstitials and oxygen vacancies. The finger print region's S-O, Zn-O, and Sn-O bands are confirmed by the accurately assigned FTIR bands. At 300K, the sample displays diamagnetic behaviour. Additionally, at 5K, it displays an intriguing super paramagnetic behaviour between -0.15 Tesla and 0.15 Tesla.
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NanomaterialsElectronic materials

OpenAlex topics: Chalcogenide Semiconductor Thin Films · Quantum Dots Synthesis And Properties · ZnO doping and properties

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