Plausible Colloidal Methods to Synthesize Semiconductor Nanowires: Deep Study From ZnSe Nanorods

Abstract When the diameter of semiconductor nanowires is below the Bohr radius, confined excitons in the radial direction can freely move along the elongated axis direction, highlighting their potential for applications in quantum information and optoelectronic devices. Controlled anisotropic growth and oriented attachment are viable strategies for producing ultra‐long semiconductor nanowires with precisely controlled lengths and diameters. Anisotropic ZnSe nanorods are used as the initial seeds for the controlled anisotropic growth and oriented attachment methods. ZnSe nanorods/nanowires with limiting lengths of tens to hundreds of nanometers are produced. The advantages and limitations of semiconductor nanowires via controlled anisotropic growth and oriented attachment are summarized. The perspective for the promotion of controlled anisotropic growth and oriented attachment is discussed, which allows to promotion of the precise synthesis of semiconductor ultra‐long nanowires to develop the fundamental research and applications of ultra‐long semiconductor nanowires.