High‐Performance Flexible Broadband Photoelectrochemical Photodetector Based on Molybdenum Telluride

Abstract Flexible broadband photodetectors are desired but challenging to be fabricated for next‐generation wearable intelligent optoelectronic devices. Considering the narrow bandgap and strong light absorption, molybdenum telluride (MoTe ₂ ) based photoelectrochemical photodetectors are successfully assembled by liquid phase exfoliation accompanied with the electrophoretic deposited method. This MoTe ₂ ‐based photodetector shows a broadband detection in ultraviolet–near‐infrared band, long‐term stability within 18000 s, and fast response in millisecond‐level (response time≈19 ms, recovery time≈26 ms). More importantly, even though the MoTe ₂ photodetector is bent and twisted at a high degree for several hundred times, it still shows excellent flexibility with stable on‐off switching characteristics. Additionally, this photodetector displays a good response for rotation angles in the range from 0° to 360°, and the extracted I _ph maintain almost the same value approximately 0.97 µA cm ⁻² , suggesting an omnidirectional detection capability. This work demonstrates the proposed flexible photoanode shows a great potential in future broadband omnidirectional detection systems.