journal article·2014-04Open access

Preparation and characterization of self-assembled percolative BaTiO3–CoFe2O4 nanocomposites via magnetron co-sputtering

Qian Yang, Wei Zhang, Meiling Yuan, Limin Kang, Junxiao Feng, Wei Pan, Jun Ouyang

Abstract

BaTiO3-CoFe2O4 composite films were prepared on (100) SrTiO3 substrates by using a radio-frequency magnetron co-sputtering method at 750 °C. These films contained highly (001)-oriented crystalline phases of perovskite BaTiO3 and spinel CoFe2O4, which can form a self-assembled nanostructure with BaTiO3 well-dispersed into CoFe2O4 under optimized sputtering conditions. A prominent dielectric percolation behavior was observed in the self-assembled nanocomposite. Compared with pure BaTiO3 films sputtered under similar conditions, the nanocomposite film showed higher dielectric constants and lower dielectric losses together with a dramatically suppressed frequency dispersion. This dielectric percolation phenomenon can be explained by the 'micro-capacitor' model, which was supported by measurement results of the electric polarization and leakage current.
Source: europepmc · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Multiferroics and related materials · Ferroelectric and Piezoelectric Materials · Microwave Dielectric Ceramics Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory for Liquid-Solid Structure Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan, 250061, China

State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, China

Suzhou Institute of Shandong University, Suzhou, 215123, China

References (36)

Show source-provided references
1. 10.1126/science.109420710.1126/science.1094207 ↗
2. 10.1088/0022-3727/38/8/R0110.1088/0022-3727/38/8/R01 ↗
3. 10.1002/adma.20090432610.1002/adma.200904326 ↗
4. 10.1016/0079-6425(93)90004-510.1016/0079-6425(93)90004-5 ↗
5. 10.1002/(SICI)1521-4095(200002)12:4%3C294::AID-ADMA294%3E3.0.CO;2-D10.1002/(SICI)1521-4095(200002)12:4%3C294::AID-ADMA294%3E3.0.CO;2-D ↗
6. 10.1103/PhysRevLett.39.122210.1103/PhysRevLett.39.1222 ↗
7. 10.1016/S0965-9773(97)00121-910.1016/S0965-9773(97)00121-9 ↗
8. 10.1002/adma.20060121510.1002/adma.200601215 ↗
9. 10.1016/j.actamat.2007.10.00410.1016/j.actamat.2007.10.004 ↗
10. SterbinskyG E 2010 PhD Dissertation Northeastern University, Evanston, IL
11. 10.1007/s10853-009-3512-x10.1007/s10853-009-3512-x ↗
12. 10.1063/1.335410410.1063/1.3354104 ↗
13. 10.1016/j.matchemphys.2008.07.13110.1016/j.matchemphys.2008.07.131 ↗
14. 10.1016/j.jmmm.2009.02.01210.1016/j.jmmm.2009.02.012 ↗
15. 10.1111/j.1551-2916.2010.03823.x10.1111/j.1551-2916.2010.03823.x ↗
16. 10.1016/j.apsusc.2011.03.14110.1016/j.apsusc.2011.03.141 ↗
17. 10.1016/j.matchemphys.2009.07.03110.1016/j.matchemphys.2009.07.031 ↗
18. 10.1016/j.physleta.2011.02.04610.1016/j.physleta.2011.02.046 ↗
19. 10.1063/1.10243610.1063/1.102436 ↗
20. 10.1088/0022-3727/40/9/03610.1088/0022-3727/40/9/036 ↗
21. 10.1016/j.actamat.2005.04.01610.1016/j.actamat.2005.04.016 ↗
22. 10.1016/j.scriptamat.2011.12.03010.1016/j.scriptamat.2011.12.030 ↗
23. 10.1002/adfm.20060082310.1002/adfm.200600823 ↗
24. 10.1063/1.36667710.1063/1.366677 ↗
25. 10.1111/j.1551-2916.2011.04582.x10.1111/j.1551-2916.2011.04582.x ↗
26. 10.1088/1468-6996/13/3/03500610.1088/1468-6996/13/3/035006 ↗
27. 10.1016/0039-6028(94)91089-810.1016/0039-6028(94)91089-8 ↗
28. 10.1116/1.58914310.1116/1.589143 ↗
29. 10.1016/j.ceramint.2008.04.03010.1016/j.ceramint.2008.04.030 ↗
30. 10.1063/1.142103310.1063/1.1421033 ↗
31. 10.1016/j.scriptamat.2007.07.02010.1016/j.scriptamat.2007.07.020 ↗
32. 10.1063/1.347801510.1063/1.3478015 ↗
33. 10.1063/1.195713010.1063/1.1957130 ↗
34. 10.1063/1.37112010.1063/1.371120 ↗
35. 10.1143/JJAP.46.703910.1143/JJAP.46.7039 ↗
36. 10.1103/PhysRevB.50.594110.1103/PhysRevB.50.5941 ↗