Hysteresis in Carbon-Based Multiporous Layered Electrode Perovskite Solar Cells with 5-AVA-MAPbI₃ and CsFAPbI₃

Ryuki Tsuji; Takaya Shioki; Naonari Izumoto; Shunsuke Oshita; Takahiro Kondo; Seigo Ito

doi:10.1021/acsenergylett.4c03133

journal article·2025-03-14

Hysteresis in Carbon-Based Multiporous Layered Electrode Perovskite Solar Cells with 5-AVA-MAPbI₃ and CsFAPbI₃

Ryuki Tsuji, Takaya Shioki, Naonari Izumoto, Shunsuke Oshita, Takahiro Kondo, Seigo Ito

ACS Energy Letters· Volume 10· Issue 3

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Abstract

Carbon-based multiporous layered electrode perovskite solar cells (MPLE-PSCs) have gained attention for their affordability and operational stability, making them promising candidates for commercialization. Various perovskite compositions have been studied as light absorbers in MPLE-PSCs. In this study, we compared the operational performance of MPLE-PSCs using 5-AVA-MAPbI 3 and CsFAPbI 3 under varying scan rates and capacitance conditions. The 5-AVA-MAPbI 3 -based devices exhibited notable ion migration and charge accumulation, particularly at high scan rates, which may negatively affect the operational performance. In contrast, CsFAPbI 3 -based devices showed stable J–V characteristics, reduced hysteresis, and consistent photocurrent generation under continuous illumination. However, while the long-term stability of 5-AVA-MAPbI 3 is well-established in the literature, long-term data for CsFAPbI 3 remain limited, emphasizing the need for further investigation. These findings highlight the importance of selecting appropriate perovskite materials and optimizing device architectures to enhance stability and accelerate the commercialization of MPLE-PSCs.

Source: openalex_inverted_index · Quality: baseline

Research context

Electronic materials

OpenAlex topics: Perovskite Materials and Applications · Conducting polymers and applications · Quantum Dots Synthesis And Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials and Synchrotron Radiation Engineering, Graduate School of Engineering, University of Hyogo, 2167 Shosha, Himeji, Hyogo 671-2280, Japan

Department of Materials Science, Institute of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573, Japan

The Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan

Tsukuba Research Center for Energy Materials Science, Institute of Pure and Applied Sciences and R&D Center for Zero CO Emission with Functional Materials

University of Tsukuba

Funding

Electrochemical Society of Japan · Strategic International Collaborative Research Program · Japan Aerospace Exploration Agency · JFE 21st Century Foundation · Japan Society for the Promotion of Science · Japan Science and Technology Agency · Kondo-Zaidan · Azbil Yamatake General Foundation · EIG CONCERT-Japan

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